Safety Data Sheet Struers Caldofix Resin 1. PRODUCT AND COMPANY IDENTIFICATION Product Name: Struers Caldofix Resin Synonyms/Generic Names: None Product Number: 5571 Product Use: Industrial, Manufacturing or Laboratory use Manufacturer: Columbus Chemical Industries, Inc. N4335 Temkin Rd. Columbus, WI. 53925 For More Information Call: 920-623-2140 (Monday-Friday 8:00-4:30) In Case of Emergency Call: CHEMTREC - 800-424-9300 or 703-527-3887 (24 Hours/Day, 7 Days/Week) 2. HAZARDS IDENTIFICATION Target Organs: Signal Word: Danger Pictograms: GHS Classification: irritation Category 2 Eye damage Category 1 sensitization Category 1 Mutagenicity Category 2 Chronic aquatic toxicity Category 2 GHS Label Elements, including precautionary statements: Hazard Statements: H315 Causes skin irritation. H317 May cause and allergic skin reaction. H318 Causes serious eye damage. H341 Suspected of causing genetic defects. H411 Toxic to aquatic life with long lasting effects. Precautionary Statements: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P261 Avoid breathing dust/fume/gas/mist/vapors/spray. P264 Wash hands thoroughly after handling. Revised on 11/05/2015 Page 1 of 6
P272 P273 P280 P280 P302+P352 P305+P351+P338 P321 P332+P313 P362+P364 P391 P405 P501 Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see first aid instruction on this label). If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Collect spillage. Store locked up. Dispose of contents/container in accordance with local regulations. Potential Health Effects May causes eye damage. Inhalation May cause respiratory tract irritation. Causes skin irritation irritation. Ingestion May be harmful if swallowed. NFPA Ratings Health 2 Flammability 1 Reactivity 0 Specific hazard HMIS Ratings Health 2 Fire 1 Reactivity 0 Personal H 3. COMPOSITION/INFORMATION ON INGREDIENTS Component Bisphenol A Diglycidyl Ether Resin Neodecanoic acid oxiranylmethylester Weight % CAS # EINECS# / ELINCS# Formula Molecular Weight 60-100 25068-38-6 500-033-5 (C 15 H 16 O 2 C 3 H 5 ClO) x N/A 15-35 26761-45-5 247-979-2 C 13 H 24 O 3 228.33 2-Propenoic acid 3-5 1245638-61-2 629-850-6 N/A N/A Hexamethylene diacrylate 1-5 13048-33-4 235-921-9 C 12 H 18 O 4 226.27 4. FIRST-AID MEASURES Inhalation Ingestion Rinse with plenty of water for at least 15 minutes and seek medical attention. Move casualty to fresh air and keep at rest. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention. Flush with plenty of water for at least 15 minutes while removing contaminated clothing and wash using soap. Get medical attention. Do Not Induce Vomiting! Never give anything by mouth to an unconscious person. If conscious, wash out mouth with water. Get medical attention. Revised on 11/05/2015 Page 2 of 6
5. FIRE-FIGHTING MEASURES Suitable (and unsuitable) extinguishing media Special protective equipment and precautions for firefighters Specific hazards arising from the chemical Use foam, carbon dioxide, dry powder or water fog on fires involving this material. Use appropriate media for adjacent fire. Cool unopened containers with water. Wear self-contained, approved breathing apparatus and full protective clothing, including eye protection and boots. Emits toxic fumes (carbon oxides) under fire conditions. (See also Stability and Reactivity section). 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up See section 8 for recommendations on the use of personal protective equipment. Prevent spillage from entering drains. Any release to the environment may be subject to federal/national or local reporting requirements. Absorb spill with noncombustible absorbent material, then place in a suitable container for disposal. Clean surfaces thoroughly with water to remove residual contamination. Dispose of all waste and cleanup materials in accordance with regulations. 7. HANDLING AND STORAGE Precautions for safe handling See section 8 for recommendations on the use of personal protective equipment. Use with adequate ventilation. Wash thoroughly after using. Keep container closed when not in use. Avoid formation of aerosols. Conditions for safe storage, including any incompatibilities Store in cool, dry well ventilated area. Keep away from incompatible materials (see section 10 for incompatibilities). 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Occupational exposure controls: Contains no substances with occupational exposure limit values. Personal Protection Wear chemical safety glasses or goggles. Inhalation Provide local exhaust, preferably mechanical. If exposure levels are excessive, use an approved respirator. Wear nitrile or rubber gloves, and apron or lab coat. Other Other Recommendations Provide eyewash stations, quick-drench showers and washing facilities accessible to areas of use and handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance (physical state, color, etc.) Odor Clear, yellowish liquid. Slight odor. Revised on 11/05/2015 Page 3 of 6
Odor threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point 100 C Evaporation rate Flammability (solid, gas) Not Flammable Upper/lower flammability or explosive limit Not Explosive Vapor pressure Vapor density Density 1.13 Solubility (ies) Insoluble in water. Partition coefficient: n-octanol/water Auto-ignition temperature Decomposition temperature 10. STABILITY AND REACTIVITY Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Incompatible Materials Hazardous Decomposition Products Stable under normal temperature conditions. Will not occur. None known. Strong oxidizing agents and strong bases. Carbon oxides. 11. TOXICOLOGICAL INFORMATION Acute Toxicity Respiratory Ingestion Carcinogenicity IARC ACGIH NTP OSHA as probable, possible or confirmed human carcinogen by IARC. as a carcinogen or potential carcinogen by ACGIH. as a known or anticipated carcinogen by NTP. as a carcinogen or potential carcinogen by OSHA. Signs & Symptoms of Exposure Irritation. Irritation, redness, watering eyes. Respiratory Irritation, coughing. Ingestion Nausea, stomach pain, vomiting. Chronic Toxicity Teratogenicity Mutagenicity Embryotoxicity Specific Target Organ Toxicity Reproductive Toxicity Respiratory/ Sensitization Revised on 11/05/2015 Page 4 of 6
12. ECOLOGICAL INFORMATION Ecotoxicity Aquatic Vertebrate Aquatic Invertebrate Terrestrial Persistence and Degradability Bioaccumulative Potential Mobility in Soil PBT and vpvb Assessment Other Adverse Effects Expected to be heavily biodegradable. May accumulate in soil and water systems. 13. DISPOSAL CONSIDERATIONS Waste Residues Product Containers Users should review their operations in terms of the applicable federal/national or local regulations and consult with appropriate regulatory agencies if necessary before disposing of waste product or residues. Users should review their operations in terms of the applicable federal/national or local regulations and consult with appropriate regulatory agencies if necessary before disposing of waste product container. The information offered in section 13 is for the product as shipped. Use and/or alterations to the product may significantly change the characteristics of the material and alter the waste classification and proper disposal methods. 14. TRANSPORTATION INFORMATION US DOT UN3082, Environmentally hazardous substance, liquid, n.o.s. (epoxy resin), 9, pg III TDG UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (EPOXY RESIN), 9, PG III IMDG UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (EPOXY RESIN), 9, PG III Marine Pollutant Yes IATA/ICAO UN3082, Environmentally hazardous substance, liquid, n.o.s. (epoxy resin), 9, pg III 15. REGULATORY INFORMATION TSCA Inventory Status DSCL (EEC) California Proposition 65 SARA 302 SARA 304 SARA 311 SARA 312 SARA 313 WHMIS Canada All ingredients are listed on the TSCA inventory. All ingredients are listed on the DSCL inventory. No SARA Hazard No SARA Hazard Revised on 11/05/2015 Page 5 of 6
16. OTHER INFORMATION Revision Date Original 11/05/2015 Disclaimer: Columbus Chemical Industries, Inc. ( Columbus ) believes that the information herein is factual but is not intended to be all inclusive. The information relates only to the specific material designated and does not relate to its use in combination with other materials or its use as to any particular process. Because safety standards and regulations are subject to change and because Columbus has no continuing control over the material, those handling, storing or using the material should satisfy themselves that they have current information regarding the particular way the material is handled, stored or used and that the same is done in accordance with federal, state and local law. COLUMBUS MAKES NO WARRANTY, EXPRESS OR IMPLIED, INCLUDING (WITHOUT LIMITATION) WARRANTIES WITH RESPECT TO THE COMPLETENESS OR CONTINUING ACCURACY OF THE INFORMATION CONTAINED HEREIN OR WITH RESPECT TO FITNESS FOR ANY PARTICULAR USE. Revised on 11/05/2015 Page 6 of 6