EFFECTS OF SEED-PLACED SULFUR FORMS ON WHEAT, CANOLA AND PEA YIELDS IN SASKATCHEWAN SOILS

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EFFECTS OF SEED-PLACED SULFUR FORMS ON WHEAT, CANOLA AND PEA YIELDS IN SASKATCHEWAN SOILS Tom King 1, Jeff J. Schoenau 1, Ryan Hangs 1, S. S. Malhi 2 and Ron Urton 1 1 Dept. of Soil Science, 51 Campus Drive, University of Saskatchewan, Saskatoon, SK, CANADA S7N 5A8 2 Agriculture & Agrifood Canada (AAFC), Melfort, SK, CANADA S0E 1A0 Soils and Crops Meeting, Saskatoon, SK. March 16, 2015

Introduction Sulfur fertilizers are important for not only canola, but also sometimes recommended for cereal and pulse crops. Sulfur sources include: soluble forms (Ammonium Sulfate, Potassium Sulfate) slightly soluble forms (Calcium Sulfate [Gypsum]) insoluble forms (Elemental Sulfur) liquid forms (Ammonium Thiosulfate) Is there an advantage of using one or more of the S fertilizer forms in conjunction with phosphorus fertilizer in cereal, oilseed and legume crops in different Saskatchewan soils?

STUDY OBJECTIVE To examine the effects that different forms of sulfur fertilizers, with and without the addition of phosphorus fertilizer, have on wheat, canola and pea yield in: Brown Chernozem, Gray Luvisol and Gray-Black Chernozem soils in Saskatchewan.

STUDY LOCATIONS Saskatoon, SK Melfort, SK (Gray-Black Chernozem) Star City, SK (Gray Luvisol) Central Butte, SK (Brown Chernozem) (Henry s Handbook of Soil and Water, 2003)

STUDY METHODOLOGY Study set up as a randomized complete block design (RCBD), complete with 4 replicate blocks for each of the 3 crops at 3 sites in Saskatchewan. 3 Crops: Cereal: Hard Red Spring Wheat (Waskada HRSW) Oilseed: Canola (Liberty Link 150) Legume: Yellow Pea (Meadow) Plot Size: 3 metre X 1 metre Plots seeded & seed-row fertilizer placement using a single row seeder. Row Spacing: 25 cm Seedbed utilization (SBU) = ~ 5% Harvest samples: 1.0 metre row length

STUDY METHODOLOGY Treatments Urea Urea+Monoammonium Phosphate (MAP) Ammonium Sulfate Ammonium Sulfate + MAP Ammonium Thiosulfate Ammonium Thiosulfate + MAP Gypsum Gypsum + MAP Potassium Sulfate Potassium Sulfate + MAP Elemental Sulfur Elemental Sulfur + MAP Fertilizer Rates ---------------------------(kg ha -1 )------------------------- Sulfur Phosphorus Nitrogen 0 0 100 0 20 100 20 0 100 20 20 100 20 0 100 20 20 100 20 0 100 20 20 100 20 0 100 20 20 100 20 0 100 20 20 100 Phosphorus fertilizer added as P 2 O 5 equivalent. Phosphorus fertilizer applied as monoammonium phosphate (MAP: 12-51-0). Nitrogen fertilizer applied as urea (46-0-0). Sulfur and/or phosphorus fertilizer containing N is taken into account to maintain a 100 kg N ha -1 rate. No N fertilizer (other than the N contained in sulfur and/or phosphorus fertilizer) was added to the pea crop.

2014 STUDY RESULTS

SOIL TEST EXTRACTABLE P AND S SPRING 2014 P S -----kg ha -1 (0-15 cm)------- Central Butte (Brown Chernozem) 17 48 37 11 Star City (Gray Luvisol) 13 50 43 20 Melfort (Gray-Black Chernozem) 42 59 32 14 Sulfates present in sub-soil (30-60 cm) at Central Butte (Brown Chernozem) site. Values in red indicate spring 2013 soil extractable P and S

2014 Wheat Grain Yield Treatments Central Butte Star City Melfort Brown Chernozem Gray Luvisol Gray-Black Chernozem --------------------------------------------(kg ha -1 )------------------------------------------------ Urea 3373 2323 4130 Urea+Monoammonium Phosphate (MAP) 3494 3501 4581 Ammonium Sulfate 4659 3511 3778 Ammonium Sulfate + MAP 4304 3822 4477 Ammonium Thiosulfate 3366 3196 3720 Ammonium Thiosulfate + MAP 4188 3658 3726 Gypsum 4431 3377 3617 Gypsum + MAP 3888 3192 4201 Potassium Sulfate 3611 3088 3616 Potassium Sulfate + MAP 4175 2796 3848 Elemental Sulfur 3311 3639 4004 Elemental Sulfur + MAP 2963 3562 4229 Pr > F Pr > F Pr > F Crop 0.0005 0.1730 0.0247 Treatment <0.0001 0.1620 <0.0001 Crop*Treatment <0.0001 <0.0001 0.0001 Least significant difference at P 0.10

2014 Wheat Crop Summary At Brown Chernozem (Central Butte) ammonium sulfate and gypsum produced highest yields. Addition of MAP to S fertilizers slightly boosted wheat yields at Gray-Black Chernozem (Melfort) site. No significant response of wheat grain yield to S fertilizers at Gray Luvisol or Gray-Black Chernozem sites.

2014 Canola Grain Yield Treatments Central Butte Star City Melfort Brown Chernozem Gray Luvisol Gray-Black Chernozem --------------------------------------------(kg ha -1 )------------------------------------------------ Urea 3773 3402 5576 Urea+Monoammonium Phosphate (MAP) 5021 3308 3957 Ammonium Sulfate 4093 2646 3888 Ammonium Sulfate + MAP 5332 2714 4974 Ammonium Thiosulfate 4071 3164 4168 Ammonium Thiosulfate + MAP 2452 2258 3254 Gypsum 6192 3266 4424 Gypsum + MAP 6119 5076 5421 Potassium Sulfate 4186 3635 7819 Potassium Sulfate + MAP 5672 3154 3945 Elemental Sulfur 5298 2725 3744 Elemental Sulfur + MAP 4226 3735 4763 Pr > F Pr > F Pr > F Crop 0.0005 0.1730 0.0247 Treatment <0.0001 0.1620 <0.0001 Crop*Treatment <0.0001 <0.0001 0.0001 Least significant difference at P 0.10

2014 Canola Crop Summary In Brown Chernozem soil, calcium sulfate (gypsum)(± MAP) produced significant canola yield response. At Gray Luvisol site, addition of calcium sulfate + MAP increased canola yields. For Gray-Black Chernozem site, potassium sulfate had highest yield. Gypsum + MAP had similar high yields. Some issues with injury for seedplaced AS, ATS and MAP at Gray and Gray-Black sites.

2014 Yellow Pea Grain Yield Treatments Central Butte Star City Melfort Brown Chernozem Gray Luvisol Gray-Black Chernozem --------------------------------------------(kg ha -1 )------------------------------------------------ Control (No Urea) 3436 3278 5237 Monoammonium Phosphate (MAP) 4478 2893 7268 Ammonium Sulfate 3995 3857 3761 Ammonium Sulfate + MAP 4146 3225 3755 Ammonium Thiosulfate 3023 2665 2633 Ammonium Thiosulfate + MAP 1995 1481 1620 Gypsum 3070 2988 2569 Gypsum + MAP 3034 2002 3131 Potassium Sulfate 3815 2701 4904 Potassium Sulfate + MAP 3055 2752 5791 Elemental Sulfur 4665 3009 4937 Elemental Sulfur + MAP 2968 2019 4814 Pr > F Pr > F Pr > F Crop 0.0005 0.1730 0.0247 Treatment <0.0001 0.1620 <0.0001 Crop*Treatment <0.0001 <0.0001 0.0001 Least significant difference at P 0.10

2014 Pea Crop Summary No significant positive yield responses of pea to S fertilizer. ATS treatment (with MAP) significantly decreased pea grain yield. 20 kg P 2 O 5 /ha plus 20 kg S/ha in seed-row may have caused injury especially with the low SBU (~ %5). At Brown and Gray-Black Chernozem sites, positive yield responses to MAP.

General Conclusions Calcium sulfate (gypsum) and potassium sulfate were effective fertilizer S sources in the seed-row for crops evaluated. Suitable alternative to ammonium sulfate. Elemental S produced some positive yield responses, especially in wheat. Of the three crops, canola most consistent in response to added S. Peas showed no positive response. Addition of ATS, especially in combination with MAP placed in seed row in contact with seed impaired canola and especially pea crop germination and growth at all three Saskatchewan sites. Better response to P fertilizer application at Brown Chernozem and Gray Luvisol sites due to lower residual soil available phosphorus.

ACKNOWLEDGEMENTS Funding provided by: Saskatchewan Agriculture Development Fund Western Grains Research Foundation Sask Canola Development Commission Saskatchewan Pulse Growers The authors greatly appreciate the support and assistance provided by: Darwin Leach & Karen Strukoff (AAFC, Melfort, SK.) Team Schoenau Research Group (Univ. of Sask., Saskatoon, SK.)