Moving toward Sustainability

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Nanotechnology and the Environment: Moving toward Sustainability Barbara Karn, PhD Health and Environment Organization April 17, 2012

A bit of history Nanotechnology is enabled Nanotechnology is recognized NNI formed NNI becomes official Program Component Areas Environment EHS Responsible nanotechnology First ACS symposium NNI workshops Royal Society Report

Nanotechnology research moves to sustainability

Nanotechnology Defined National Nanotechnology Initiative: Nanotechnology -- the understanding and control of matter at dimensions between approximately 1 and 100 nanometers, where unique phenomena enable novel applications. Encompassing nanoscale science, engineering, and technology, nanotechnology involves imaging, measuring, modeling, and manipulating matter at this length scale. Dimensions between approximately 1 and 100 nanometers are known as the nanoscale where unusual physical, chemical, and biological properties can emerge. These properties may differ in important ways from the properties of bulk materials and single atoms or molecules. European Commission: (October 18, 2011) Definition of a nanomaterial, a natural, incidental or manufactured material containing particles, in an unbound state or as an aggregate or as an agglomerate and where, for 50 percent or more of the particles in the number size distribution, one or more external dimensions is in the size range 1 nm 100 nm nanometers.

Nanotechnology 1-100nm Cell 30-50,000nm Nucleus 10,000nm Ribosome 20-30nm diameter DNA 2nm diameter

National Nanotechnology Initiative (NNI) Vision A future in which the ability to understand and control matter at the nanoscale leads to a revolution in technology and industry that benefits society.

Nanotech-enabled Semiconductor technologies (Organic Semiconductors, CMOS Sensors ) Memory and storage technologies (Magnetic Heads, Optical Pickup, AFM-based Memory, CNT-based Memory, Molecular Memory ) Nano s fast moving sectors Display technologies (Photonic FED, Organic Electroluminescence, Electronic Paper) Optic/photonic technologies (Photonic Crystal Fiber, Optical Waveguides, Optoelectronic IC) Energy technologies (Fuel Cells, Li-Ion Batteries, Electric Double-Layer Capacitors, Microcrystalline Thin Films, Solar Cells, Dye-sensitized Solar Cells) Bio/health technologies (Drug Delivery Systems, Immunochromatography, Regenerative Medicine, Biosensors, Nanobubble Generators, Nano-cosmetics, Nano-textiles) Materials (Composites) Research and Markets, 2007

Nanotechnology Evolution M. C. Roco 6/18/08

NNI Scientific Organization: Program Component Areas (Millions USD-2009) Fundamental Nanoscale Phenomena and Processes Nanomaterials Nanoscale Devices and Systems $116.93 $34.76 Instrumentation Research, Metrology, and Standards for Nanotechnology Nanomanufacturing Major Research Facilities and Instrumentation Acquisition Environment, Health, and Safety Education and Societal Dimensions $203.01 $101.35 $76.85 $402.03 $484.40 $342.28

Research Framework for Responsible nanotechnology for Environment health and safety Applications reactive to existing problems or proactive in preventing future problems. Implications of interactions of nanomaterials with the environment and possible risks that may be posed by the use of nanotechnology.

Applications Examples Sensors Treatment Remediation Green manufacturing Sustainable energy Environmentally benign synthesis Implications Natural nano processes Fate, transport, and transformation Lifecycle aspects Toxicology Exposure, bioavailability, and bioaccumulation

Green Nanotechnology Framework 1. Production of nanomaterials and products does not harm the environment Making NanoX greenly e.g., Green chemistry, Green engineering, DfE, Smart business practices Using NanoX to green production e.g., Nanomembranes, nanoscaled catalysts Pollution Prevention Emphasis 2. Products of nano help the environment Direct Environmental Applications Indirect Environmental Applications e.g., environmental remediation, sensors e.g., saved energy, reduced waste, Anticipating full life cycle of nanomaterials and nanoproducts NEXT STEPS: Policies that offer incentives for developing green nanoproducts and manufacturing techniques

State of Research Number of publications: nano and nano/environment 80000 70000 71485 y = 6289.8x + 1785.7 R² = 0.9909 60000 60909 Number Of Publications 50000 40000 30000 20000 19078 30937 45297 nano* nano* and environ* 10000 0-10000 12028 y = 330.31x - 393.95 368 597 982 1652 2660 3681 R² = 0.939 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 Year

Nano EHS Publications change from 2003 to 2010 12000 10539 10000 Number Of Publications 8000 6000 7922 5705 4000 2000 0 3326 2024 1316 677 4028 2094 24 217 10 2003 2010

There is a need to go beyond environmental protection to sustainability Social and economic aspects, in addition to the environment, are considered in sustainability Nanotechnology can aid in reaching sustainability

Nanotechnology can help alleviate sustainability problems Climate change Water resources Infectious disease Food production Renewable energy Toxics

No technology will lead to sustainabilty Technologies buy us time by slowing down the rate of non-sustainable practices Only a change in Human values and behavior in concert with technologies can lead to true sustainability

Charge to the research community Use your knowledge, particularly in science or engineering, to make a contribution to support responsible and sustainable development of nanotechnology Because you can

Thanks! bkarn@nsf.gov

The National Science Foundation (NSF) is the primary Federal agency supporting research at the frontiers of knowledge, across all fields of science and engineering (S&E) and all levels of S&E education. NSF Act of 1950 (Public Law 81-507). The NSF Act set forth a mission: to promote the progress of science; to advance the national health, prosperity, and welfare; to secure the national defense; and for other purposes.