CONSIDER BRUSH ALLOY 174

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Brush performance alloys

CONSIDER BRUSH ALLOY 174 Engineered to carry high current with lower temperature rise, predictable normal forces and an improved formability to strength ratio, Brush Alloy 174 is specifically designed for applications spanning the computer, electronics, automotive, appliance, electrical/ electromechanical, medical and aerospace industries. Since its introduction in 1985, Brush Alloy 174 has established itself as the preferred material in applications where the traditional copper alloys are no longer adequate. Alloy 174 Composition Brush Alloy 174 fills the performance and cost differential between the lower performance copper alloys, such as brass, and the higher performance beryllium copper alloys. Brush Performance Alloys engineering staff achieved this objective by alloying small quantities of beryllium and cobalt in a copper matrix. The patented chemical composition for Brush Alloy 174 is shown in Figure 1. Figure 1: Composition Alloy Copper Beryllium UNS Number C17410 Trade Name Be (%) Co (%) Cu Brush Alloy 174 0.15-0 0.35-0.60 Balance Alloy 174 Properties Figure 2: Physical Properties The physical and mechanical properties of Brush Alloy 174 are shown in Figures 2 and 3. Available as mill hardened strip, Brush Alloy 174 conforms to ASTM specification B768 and is manufactured within the quality system requirements of Brush Performance Alloys. Melting Point (solidus) Density* Specific Gravity Thermal Conductivity* Electrical Resistivity* Electrical Conductivity* HT 1/2 HT Modulus of Elasticity 1875 F 0.318 lb/in 3 8.80 135 BTU/(ft hr F) 23.0 ohms circ mil/ft 45% IACS 50% IACS 20 x 10 6 psi 1025 C 8.80 g/cm 3 8.80 6 cal/(cm sec C) 3.82 microhm cm 0.26 megmho/cm 0.29 megmho/cm 137,900 N/mm 2 Alloy 174 Performance As shown in Figure 4 (page 4), the performance advantages of Brush Alloy 174 over commonly used copper alloys include a superior resistance to stress relaxation at elevated temperatures, electrical conductivity that is four times greater than the bronzes, enhanced formability for a given strength, and value pricing. *Room Temperature Figure 3: Mechanical Properties Property Brush Alloy 174 HT Brush Alloy 174 1/2 HT Ultimate Tensile Strength Yield Strength (0.2% offset) Elongation in 2 (50 mm) Hardness Electrical Conductivity at 68 F (20 C) Fatigue Strength -10 7 cycles, reveresed bending one way bending 110-130 ksi 100-120 ksi 7-17% 95-102 HRB 45-60% IACS 45-50 ksi 80-85 ksi 760-895 N/mm 2 690-825 N/mm 2 7-17% 230-280 HV 26-35 m/ωmm 2 310-345 N/mm 2 550-585 N/mm 2 95-115 ksi 80-100 ksi 10-20% 89-98 HRB 50% min IACS 45-50 ksi 80-85 ksi 655-790 N/mm 2 550-690 N/mm 2 10-20% 180-230 HV 29 m/ωmm 2 310-345 N/mm 2 550-585 N/mm 2 Typical Formability (R/t) 90 Longitudinal Transverse 1.2 5.0 2

BRUSH ALLOY 174 In electrical and electronic products ranging from computers and electrical/electromechanical devices, to automobiles and appliances, current-carrying applications requiring high strength, high conductivity, and superior resistance to stress relaxation are rapidly becoming the norm. These factors, combined with the increasing demand for enhanced product reliability, have triggered changes in contact material specification - changes that have focused attention on the engineered material performance of Brush Alloy 174. Benefits Miniaturization High Temperature Applications Twice the Electrical Conductivity of Brass High Repetitive Cycle Life Easily Formed into Complex Shapes Available with Tin Coatings or Precious Metal Inlays Miniaturization The need for more circuit connections in a smaller space can be satisfied using Brush Alloy 174. The material s strength allows it to withstand higher stresses. These higher stresses occur because spring size is reduced, yet spring force is maintained to provide reliable gas-tight contact interfaces. As the number of circuit pathways increase, connector insertion and withdrawal forces must be managed. Designs using Brush Alloy 174 will have lower insertion and withdrawal forces. High Temperature Applications At high temperatures, Brush Alloy 174 maintains the highest spring force, as compared to other traditional copper alloys (Figures 5 & 6). Applications where in-service temperatures exceed 200 C are using Brush Alloy 174. Because of this long-term thermal stability, Brush Alloy 174 eliminates the need to overdesign beginning-of-life contact normal forces to compensate for stress loss common in other copper alloys. This will minimize insertion and withdrawal forces. Twice the Electrical Conductivity of Brass With a typical electrical conductivity of 52% IACS, Brush Alloy 174 can carry higher levels of electrical current without generating damaging temperature rises. Substituting Brush Alloy 174 for brass can result in less material usage and reduced heating offering longer and more reliable operating life. High Repetitive Cycle Life Brush Alloy 174 has excellent fatigue strength making it the material of choice for use in high cycle applications such as switches or relays. In the severe reversed bending mode, Brush Alloy 174 demonstrates cycle life over 100 million operations while stressed to 45 ksi (310 N/mm 2 ). Easily Formed into Complex Shapes Given the material s high strength level, Brush Alloy 174 has very good forming characteristics. By substituting Brush Alloy 174 for lower strength/performance materials, existing designs have been upgraded without modification to the stamping tool. Available with Tin Plating or Precious Metal Inlays Brush Alloy 174 is available with surface coatings such as tin plating, solder coating or precious metal inlay. The standard material finish has a stain inhibiting treatment on the surface. This provides a temporary protection against the growth of surface films such as oxides, even in industrial atmospheres (90% relative humidity, 90 F). 3 Brush Alloy 174 is a registered trademark of Materion Brush Inc.

Stress Relaxation Resistance The trend toward denser packaging, miniaturization, higher currents, and increased operating temperatures has combined to make a contact material s stress relaxation resistance a critical concern. Materials with low resistance to stress relaxation will lose contact normal force over time. This can lead to increased contact resistance, greater self heating and ultimately failure. The stress relaxation performance of Brush Alloy 174, as it compares with the traditional copper alloys, is shown in Figures 5 and 6. Conductivity For higher power applications or thermal management of denser packaging, material selection based on electrical and thermal conductivity has assumed primary importance. Since electronic component failure rates increase exponentially with temperature increases, it is important to use materials which minimize temperature rise. The electrical conductivity of Brush Alloy 174 is extremely high for a spring alloy. The alloy s corresponding thermal conductivity is three to five times greater than competitive copper alloys. Formability A comparison of Brush Alloy 174 s formability, in relation to other copper alloys, is shown in Figure 4. Brush Alloy 174 s 1/2HT temper has excellent forming characteristics in both directions (good-way and bad-way). This allows material substitutions with minimal impact on existing stamping tools. Figure 4: Comparision Property Brush Alloy 174 C510 C260 HT 1/2 HT S H S H Ultimate Tensile Strength (ksi) 0.2% Yeild Strength (ksi) Elongation (%) Hardness (HRB) Elastic Modulus (x 10 6 psi) Conductivity (% IACS) Typical formability (R/t) 90 Longitudinal Transverse Stress Relaxation Resistance Remaining Stress (%) (75% of 0.2% YS) 1000 hrs. at 150 C 110-130 100-120 7 min. 95-102 20 45-60 1.2 5.0 85 95-115 80-100 10 min. 89-98 20 50 min. 80 95-110 92-108 6 max. 88-96 11 3.0 8.0 50 76-91 74-88 11 max. 84-93 13 3.0 < 50 95 86 1 min. 91 28 1.7 3.5 < 25 76 72 10 82 28 0.9 1.7 20 Figure 5: 150 C Stress Relaxation Resistance Results Figure 6: 200 C Stress Relaxation Resistance Results 4

5 Health & Safety Handling copper beryllium in solid form poses no special health risk. Like many industrial materials, beryllium-containing materials may pose a health risk if recommended safe handling practices are not followed. Inhalation of airborne beryllium may cause a serious lung disorder in susceptible individuals. The Occupational Safety and Health Administration (OSHA) has set mandatory limits on occupational respiratory exposures. Read and follow the guidance in the Material Safety Data Sheet (MSDS) before working with this material. For additional information on safe handling practices or technical data on copper beryllium, contact Materion Brush Performance Alloys, Technical Service Department at 800.375.4205.

ABOUT MATERION MATERION BUSINESSES Materion ABOUT MATERION is the new name for Brush Advanced Chemicals Electrofusion Engineered Materion is Materials the new name Inc., its for Brush a dozen leading advanced Barr Precision materials Optics companies & Thin with Film a Coatings common Wellman ownership Inc. and subsidiary, now combined and all under of the a single brand Brush identity. Beryllium Prior & to Composites March 2011, you knew company s us as Williams businesses Advanced worldwide. Materials or Barr Associates Brush or Performance Academy Corporation. Alloys Or maybe Materion you knew is us among as Zentrix the world s Cerac premier or Thin Film Technology. Ceramics What you probably didn t know is Large Area Coatings Microelectronics & Services Natural Resources Technical Materials providers that we were of advanced all part of materials the same solutions company: Brush Engineered Materials, a billion-dollar New and York services. Stock Exchange Now under company the one that is among the world s BRUSH premier PERFORMANCE providers of ALLOYs advanced INTERNATIONAL materials LOCATIONS and brand, services. we Now are better under aligned the one Materion brand, we are better aligned to deliver a Materion China/Hong Kong REPUBLIC OF KOREA to broader deliver scope a broader of products, scope of service products, and expertise p needed + 852.2318.1907 to drive our customers growth p + 82.32.811.2171 services and profitability and expertise and become needed their to drive first choice in a brushalloyshk-info@materion.com partner. brushalloyskr-info@materion.com our customers growth and profitability and MATERION become their OPERATING first choice BUSINESSES in a partner. Microelectronics Materion & Corporation Services common stock Advanced trades Chemicals on the New York Stock CHINA/SHANGHAI p Brush + 86.21.5237.2328 Beryllium & Composites brushalloyscn-info@materion.com Brush Electrofusion SINGAPORE/ASEAN p + 65.6842.4456 brushalloyssg-info@materion.com Exchange Precision Options under the & symbol Thin Film MTRN. Coatings Brush Ceramics GERMANY TAIWAN, R.O.C. Large Area Coatings Brush High Performance Alloys p + 49.711.830.930 p + 886.2.2747.8800 ext. 121 Technical Materials brushalloysde-info@materion.com Brush Resources brushalloystw-info@materion.com INDIA/PUNE p + 91.99606.33744 brushalloysin-info@materion.com UNITED KINGDOM & IRELAND p + 44.118.930.3733 brushalloysuk-info@materion.com JAPAN p + 81.33.230.2961 brushalloysjp-info@materion.com BRUSH PERFORMANCE ALLOYs Main Office 6070 Parkland Boulevard Mayfield Heights, OH 44124 USA p 800.375.4205 +1.2.486.4200 www.materion.com/brushalloys AB0009 04.11