The HIsarna Ironmaking Process

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Presentation title, change View >> Header & Footer The HIsarna Ironmaking Process Together we make the difference 1

Content 1. Introduction 2. The benefits of HIsarna 3. The pilot plant 4. Further development 5. Conclusions 2

1. Introduction In 2004 several European steelmakers proactively started the ULCOS project with the objective to achieve 50 % reduction of the CO 2 emissions of steelmaking HIsarna is one of the four process development that originate from the ULCOS project. Since 2007 Tata Steel, Rio Tinto and ULCOS have been active developing this coal-based smelting reduction process. The HIsarna process offers a combination of environmental and economical benefits. 3

2. The benefits of HIsarna Comparison BF route - HIsarna Iron ore Hot metal Coal Coking/Agglomeration Ironmaking Iron ore Hot metal Coal Ironmaking Direct use of fine ores and coal (no agglomeration and coking) 4

2. The benefits of HIsarna HIsarna offers a combination of environmental and economic benefits Economic benefits Ironmaking with low cost raw materials, non-coking coals and low grade ores Recycling of waste oxides, slags and galvanised scrap Higher energy efficiency Lower steelmaking costs because of low Si, P in hot metal Greenfield developments with much lower CAPEX Environmental benefits CO 2 emission reduction 20 % without CCS CO 2 emission reduction 80 % with CCS Lower emissions SO X, NO X, dioxines and fine dust Avoidance of dumping slags and dusts 5

3. HIsarna Pilot Plant Over 10 Years of Development 6

3. HIsarna pilot plant Achievements 2011 First metal tap 2012 First long operating period 2013 High energy efficiency First metal delivered to BOS plant 2014 Recycling of high Zn waste oxides Recycling of scrap 2015-2017 Major plant expansion (20 M investment) CO 2 reduction target of 35 % Long duration testing of process and equipment Financial support from EU Horizon2020 Dutch Government DEI (Demonstratie Energie Innovatie) 7

4.2 Plant modifications 8

Raw materials preparation 9

Hot metal production 10

Regular slag tap and slag sampling 11

3.1 HIsarna Campaign C & D: Raw Materials Standard Ore: Campaign C: high quality hematite (65% Fe), finer granulometry Campaign D: high quality hematite (63% Fe), coarser granulometry Alternative Ores: Ironstone: Low quality (33% Fe) Coal Types: Standard: Low-volatile 8% VM Alternative 1: Mid-volatile coal 22% VM Alternative 2: High-volatile coal 39% VM Fluxes Lime BOF sludge (high lime content) 12

Coal consumption [kg/thm] 3.2 The use Coal of HIsarna hot requirement metal in steelmaking Coal rate achieved during the 4 campaigns 2750 2500 2250 2000 1750 1500 1250 1000 750 500 250 0 Campaign B Campaign C Campaign D 0 1 2 3 4 5 6 7 8 Production rate [thm/h] Target operation for pilot scale 13

3.3 HIsarna Overall results Campaign C & D Stable operation at ~ 90 % nameplate capacity (~ 7 thm/h) Successful operation with hematite ores, low-vol, mid-vol and high-vol coals Cyclone capture efficiency and pre-reduction in line with earlier experience Coal rates reached expectation (design 750 kg/thm at pilot scale) Post Combustion Ratios > 90% achieved for long stable periods Successful tapping into torpedo ladle cars, subsequently used for steel making at BOS plant 14

4. Further development Demo plant preparation: Scale up Demo plant engineering study Further technology development at the pilot plant: CO 2 capture at the pilot plant Recycling of galvanised steel scrap Zn recovery from steel plant waste oxides Partial replacement of coal by natural gas and/or biomass 15

Technology development Plant upgrade Technology demonstration Plant upgrade System development Operational knowledge System demonstration Scale up 4. Further development 4.1. Towards the Demo plant Present TRL 9 TRL 8 Demo plant TRL 7 Campaign F TRL 6 E. TRL 5 C D TRL 4 A B TRL 3 HIsarna pilot plant campaigns (Semi-) Industrial 2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 Responsibility R&D Responsibility MLE Ironmaking

9 m 14 m 20 m 4.2 Scale up Industrial size ironmaking Small size ironmaking but industrial size recycle plant Pilot plant 2.7 m 3.5 m 6.0 m 60,000 thm/year Atmospheric 1.0 bar abs 400,000 thm/year Pressurised 1.8 bar abs 1,000,000 thm/year Pressurised 1.8 bar abs

Specific heat loss [GJ/t] Bigger plants are more efficient 5.0 4.5 Pilot plant 4.0 3.5 3.0 2.5 2.0 1.5 Industrial plant 1.0 0.5 0.0 0.0 0.5 1.0 1.5 2.0 Unit size [Mt/y] #

4.3 Industrial scale HIsmelt A HIsmelt furnace with a hearth diameter of 6.5 m operated in Kwinana, Australia and now in Molong, China. En engineering package (12,000 documents) of this facility is owned by Rio Tinto

4.4 Engineering study Study made for 1 Mt/y HIsarna plant at Tata Steel IJmuiden site

4.5 CCU or CCS The HIsarna process is very suited for a combination CCS or with CCU because: The CO 2 concentration in the HIsarna off gas is > 85 % With the HIsarna process the emissions are concentrated at a single stack 21

#

Integrated site until HRC 23

Integrated site until HRC 24

4.6 HIsarna pilot plant with CO 2 capture unit New in campaign F de-sox Existing pilot plant CO 2 capture unit 60 bar Compressor Vent gas Reducer Water 35 bar Cooler CO 2 CO 2 storage 100 kt-co 2 /y to greenhouses

4.7 By-product recycling HIsarna can use Fe rich process dusts and sludges from other process as a raw material. OEM manufacturing These include BOF sludge and BF dust, also those with a high Zn fraction. This was succesfully done for the first time in campaign D (2014) Zinc coated steel strip Zn containing process dust Zinc coated steel scrap The objective is to reach sufficient Zn rich dusts for use in Zn smelters HIsarna based steel production Metallic zinc Zinc concentrate Zinc smelting 26

5. Conclusions HIsarna is a new coal-based ironmaking process offering both economical and environmental benefits The environmental benefits include a 20 % reduction of CO 2 emissions without CCS/CCU 80 90 % CO 2 reduction with CCS/CCU Experimental results of the plant in IJmuiden have confirmed the: High energy efficiency Raw material flexibility Good start/stop abilities of the process Conceptual engineering for the first industrial scale plant, 0.5 to 1.0 M t/y, has started 27