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in cement industry

A d va n c e d refractories technology Our products have been developed for the special operating conditions required in the cement manufacturing process. Nowadays, more and more alternative fuels are burned and special refractory materials are required. To date, a refractory material suitable for all the operative conditions does not exist. Thus, each plant should be analyzed to find the best technical solutions. Our services We keep a strategic stock of monolithic and insulating castables for the cement customer s need. In addition we keep a wide stock of all complementary products such as steel and ceramic anchors, bio-soluble and ceramic fibres, and insulating bricks. With the support of our expert technicians, we supply not only top quality refractories but also technical solutions and engineering. In cooperation with selected installation companies, we are able to supply turn-key/new projects, along with all the necessary equipment for the lining maintenance of a cement plant. Our solutions Each step of the cement-making process has special requirements regarding the correct choice of refractory materials. The design of the plant, the raw materials used in the process, and the various fuel options, all have a major influence on the refractories required. Alkali infiltrations, build-ups, abrasion and the use of alternative fuels, must all be carefully evaluated. 2

1. Burner lance Kiln Burners. Seven Cast corrundum. The burner lance is a critical area with specific needs which depend on kiln and grid cooler design, raw materials used, and fuel type. Strong thermal load, abrasion, infiltration and chemical attack must be considered in the right choice for the monolithic used to line the burner lance. Brand name Type of product Operating condition Seven Cast 95 RR VK RCC Kiln Burners. Seven Cast 80. Seven Cast 80 NH LCC Hard Seven Flow 80 NH SFC Hard Seven Cast 50 RD 01 W LCC Hard Seven Plast 90 AKR PLASTIC I 2. Preheater (Cyclones and connecting ducts) II IV III V Cyclones system. Stage Process temperature I 300 C II 500 C III 650 C IV 800 C V 900 C The most important step in the efficiency of a modern cement plant is the cyclones system. Each pre-heating system design is different and unique, and each cyclone system must be analysed in order to identify the critical refractory zone. We evaluate the effects of build-up, alkali, chlorine infiltration, and all other factors which may influence the performance of refractory materials used in the various cyclone systems Cyclone Bricks installation. Brand name Seven Cast 45 NM Seven Cast 50 NM Seven Cast 40 NM 01 W Seven Cast 30 N SIC M Type of product LCC LCC LCC LCC MONOLITHICS GUNNING MIXES Seven Gun 50 RN Seven Gun 50 NM Seven Gun 40 RM 01 W Seven Gun 45 NM 01 W Seven Gun 32 N SIC N Seven Gun 30 R SIC M Seven Brick 38 KM Seven Brick 40 KM A Seven Brick 50 KM A Fireclay brick Fireclay brick Alumina brick Operating condition Soft (Stages I,II) (Stages I,II,III) (Stages III,IV,V) Hard (Stages III,IV,V) Soft/ (Stages I,II,III) (Stages III,IV,V) /Hard (Stages III,IV,V) Soft (Stages I,II,III,) (Stages III, IV, V) Hard (Stages,III, IV, V) 3

3. Calciner The Calciner plays an important role in the cement manufacturing process being the first step of the clinker production process. The main property of the calciner s refractory lining is to withstand to the chemical attacks coming from the hot gases of the process. Refractory materials must have low porosity and good thermal stability. Brand name Type of product Operating condition Process temperatures = ~ 900-1100 C Application zone B Seven Cast 50 NM LCC B Seven Cast 40 NM 01 W LCC B Seven Cast 55 NH 01 V-10 LCC Hard B Seven Cast 50 RD 01 W LCC Hard B Seven Cast 30 NC SIC LCC Hard A Seven Cast 57 N SIC H LCC Hard A Seven Cast 50 ND 15 Y LCC Hard A A Seven Cast 45 U ZIR LCC Hard A MONOLITHICS GUNNING MIXES Seven Gun 50 RM Seven Gun 50 NM Seven Gun 40 RM 01 W Seven Gun 45 NM 01 W Seven Gun 57 RH 01 V CO Hard B Seven Gun 32 N SIC M A B B Calciner. Seven Gun 50 ND 15 Y Hard A Seven Gun 60 R SIC M Hard A Seven Brick 40 KM Fireclay brick Soft B Seven Brick 50 KM Alumina brick Hard A/B Seven Brick 60 KM Alumina brick Hard A/B Seven Brick 40 KM A Fireclay brick Hard A/B Seven Brick 50 KM A Alumina brick Hard A/B 4. Riser duct Calciner Gunning application (Gas Tight) The riser duct is a problematic zone due to: - build-ups, alkali infiltration, and chemical attack to the steel anchors. Following the general rule, we suggest lining the duct with bricks in the round sections and with castables in the square sections. AND GUNNING MIXES Seven Cast 50 NM LCC Seven Gun 50 RM Seven Gun 50 NM Seven Brick 40 KM Fireclay brick Soft Seven Brick 40 KM A Fireclay brick Seven Brick 50 KM A Alumina brick Hard Calciner Shot Creting application 4

5. Smoke chamber The smoke chamber is a critical area, where build-ups, frequent use of high pressure water pump which causes thermal shock make it necessary to use special refractories. Smoke chamber. Smoke chamber anchoring. C Smoke chamber. Low cement gunning installation Seven Cast 30 N SIC M LCC Seven Cast 30 NC SIC LCC Hard Seven Cast 57 N SIC H LCC Hard Seven Cast 45 U ZIR LCC Hard Seven Cast 50 ND 15Y LCC Hard MONOLITHICS GUNNING MIXES Seven Gun 32 N SIC M Seven Gun 50 ND 15Y Hard Seven Gun 60 R SIC M Hard 6. Nose ring Smoke chamber. Low cement gunning application The nose ring is also a critical area, requiring special monolithic refractory material which has an excellent resistance to: High Thermal Shock Mechanical Resistance Chemical Attack Resistance. Our Seven Cast AS 30, has been developed by our R&D department, to ensure the best performance for this critical area, along with a very fast installation time. Seven Cast 50 RD 01 W Low cement Seven Cast 30 NC SIC Low cement Hard Seven Cast 78 NB Low cement Seven Cast 80 NX Low cement Hard 7. Tertiary air duct Casting the nose ring. For the tertiary air duct we suggest abrasion resistant castables for the most stressed areas. For the other areas we suggest to use fireclay bricks. Seven Cast 80 NH Low cement Hard Seven Flow 80 NH Self flowing Hard Seven Cast 55 NH 01V-10 Low cement Hard Tertiary air duct. Lined with fireclay bricks. Seven Brick 40 KM Fireclay brick Soft 5

8. Grate cooler The formed clinker falls from the kiln into the grate cooler. The cooler area is also a problematic zone due to high thermal shock and abrasion. We use high quality raw materials and special binders in our monolithics, which are capable of resisting the severe conditions in the grate cooler. Grate cooler. Seven Cast 50 NM LCC Soft Seven Cast 57 ND LCC Seven Cast 55 NH 01V -10 LCC Hard Seven Cast 50 RD 01 W LCC Hard Seven Cast 30 NC SIC LCC Hard Seven Cast 78 NB LCC Hard Seven Cast 80 NH LCC Hard Seven Flow 80 LCC Hard MONOLITHICS GUNNING MIXES Seven Gun 50 RM Seven Gun 50 NM Seven Gun 32 N SIC M Hard Seven Gun 57 RH 01V CO Hard Seven Brick 40 KM Fireclay brick Soft Seven Brick 50 KY Alumina brick Seven Brick 60 KX Alumina brick Hard Grate cooler. Standard Seven Refractories packaging. 1200 kg pallets in EPAL 80x120. 9. Kiln hood For this area we suggest refractories with low thermal conductivity, good abrasion resistance and good resistance to chemical attack. Brand name Type of product Operating condition Seven Cast 50 NM LCC Soft Seven Cast 40 NM 01W LCC Soft Seven Cast 59 ND LCC Seven Cast 30 N SIC M LCC Hard Seven Cast 55 NH 01 V -10 LCC Hard MONOLITHICS GUNNING MIXES Seven Gun 50 NM Soft Seven Gun 32 N SIC M Hard Seven Gun 57 RH 01 VC0 Hard Seven Brick 40 KM Fireclay brick Soft Seven Brick 50 KX Alumina brick Seven Brick 60 KX Alumina brick Hard Kiln hood. Kiln Hood. Gunning installation 6

10. Pre-cast Shapes For critical areas such as the grate cooler roof and bull nose we can produce monolithic precast shapes in order to provide to our customers quicker start-ups. Seven Cast 30 NC SIC Precast shapes Seven Cast 50 RD 01 W Precast shapes Hard Seven Cast 59 ND Precast shapes Hard Precast Shapes: Grate cooler roof application 11. Complementary products The anchoring systems Our anchoring systems help to improve the life expectancy of the monolithic areas. We can offer tailor made solutions dependent on the customer s requirements: - Steel anchors (AISI 304 (1.4301), AISI 310 S (1.4845), AISI 309 (1.4828) and AVESTA 253 MA. - Anchor bricks (228 mm, 305 mm and 355 mm) in our quality Seven Brick 60 KB. For the different areas within the cement plant, we suggest a combination of steel and brick anchors be used, to maximise efficiency for the various conditions that are encountered. Anchor name Sketch Material Available STEEL ANCHORS V AISI 304 (1.4301) AISI 310 S (1.4845) AVESTA 253 MA CV AISI 304 (1.4301) AISI 310 S (1.4845) AVESTA 253 MA CBH AISI 304 (1.4301) AISI 310 S (1.4845) AVESTA 253 MA Cast anchor ANCHOR BRICKS A 228 mm A 305 mm A 355 mm AISI 309 CAST (1.4828 cast) Seven Brick 60 K (60 % Al 2 O 3 ) 7

Insulating products M.O.T ( C) Chemical composition % Bulk density (kg/m 3 ) Type of product Al 2 O 3 SiO 2 F 2 O 3 INSULATING BRICKS Light weight insulating brick dens 450 900 15 67-4,1 450 Light weight insulating brick type 23 1260 45 50 0,9 600 Light weight insulating brick type 26 1430 56 40 0,8 800 Type of product M.O.T ( C) Chemical composition % Al 2 O 3 SiO 2 CaO (MgO) Bulk density (kg/m 3 ) INSULATING COMPLEMENTARY PRODUCTS Light weight insulating slabs 1000-45 45 225 Light weight insulating slabs 1100-45 47 225 Ceramic fibre boards 1260 45 55-300 Ceramic fibre blanket 1260 45 55-64,96,128,160 Biosoluble fibre blanket 1200-65 29 64,96,128,160 Biosoluble fibre blanket 1300-75 22 64,96,128,160 12. Engineering and technical support Seven Refractories have the resources able to provide turn-key projects. Our engineering department develops new complete projects. We are able to supply the Refractory materials along with the necessary engineering for the refractory linings. Our supervisors, supervise the complete installation of our products from start to finish on a worldwide basis. Gunning installation Tuning of the gunning machine g u n n i n g i n s ta l l at i o n g u n n i n g m a c h i n e a s s e m b ly Shot Creting installation. Quality inspection 8

R e s e a r c h And Susta i n a b l e Development Seven Refractories has incorporated environmental concerns about climate change in its innovative approach to the market; not only in making our factory more electrically independent by using renewable energy sources, but in the entire manufacturing process cycle and quality control. The respect of the environment is a core value of Seven Refractories. Selection of the raw materials, dedicated and oriented research, composition architecture and on the field technical experts are the key-points for outstanding efficiency and reliability of the refractory linings, excellent control of the thermal load distribution and low product variability in time. t e s t i n g 100% e n e r g y p r o d u c t i o n LCC= Low cement castable RC = Regular castable SFC = Self flowing castable RG = Regular gunning mix = Low cement gunning mix LCC-S = Low cement castable - Shotcreting 11

S e r v i c e s provided Preliminary study and investigation for the project edition Design and architecture, bill of materials, thermal calculation Full range of products for lining and maintenance Regular, low, ultra-low and no-cement castables Regular and dense low-cement gunning mix Ramming Shotcreting Grouting, patching and dry vibrating products Insulating castables Fireclay and Alumina Bricks for static parts and Rotary Kiln Steel Anchors and Anchor Bricks Insulating firebricks, Biosoluble Fibers and insulating boards Supply of mixer, gunning machines, pump, etc. Training on mixing, gunning and maintenance techniques Training on equipment usage Supervision and monitoring by experienced technicians Global Research & Development Monitoring and targeting of results Technical advice from experts Slovenia Seven Refractories d.o.o. Poslovna cona Risnik 40, 6215 Divača Tel. +386 5 739 57 60 Ukraine Seven Refractories Ukraine LLC Glinki str., 7, office 1102 49000 Dnepropetrovsk Tel. +38 062 209 21 05 Austria Seven Refractories GesmbH Landstraßer Hauptstraße 88/7 1030 Wien Tel. +43 676 303 88 08 Russia Seven Refractories LLC Liteyny prospekt, 26, liter A, premise 475, office 522 191028 Saint-Petersburg Tel. 0078 12 616 13 73(4) Fax 0078 12 616 13 73(4) 105 Germany Seven Refractories Deutschland GmbH Becherstraße 20 40476 Düsseldorf Tel. +49 211 544 770 25 Italy Seven Refractories Srl Via Carlo Mussa 832 15073 Castellazzo Bormida Tel. +39 013 127 88 68 Kazakhstan Seven Refractories Asia Quarter 028, block 1383, Bukhar-Zhirau district 100408 Doskey, Karaganda Tel. +77 212 505 077 info@sevenrefractories.com www.sevenrefractories.com ISO 9001 ISO 14001 07-2017