DATE: 6/1/12 Page 1 of 7 SECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifier Chemical characterization ( Mixture ) polychloroprene adhesive with modified synthetic resins and stabilizers in a mixture of organic solvents Details of the supplier of the safety data sheet Manufacturer Company name: SHOE PRODUCTS Street: 05 Cortlandt Street Place: USA Belleville, NJ 07109 Telephone: 97-751-7579 Fax: 97-759-724 E-mail: petronioshoeglue@aol.com Contact person: Don Rinaldi Supplier Company name: SHOE PRODUCTS Street: 05 Cortlandt Street Place: Belleville, NJ 07109 Telephone: 97-751-7579 Fax: 97-759-724 E-mail: petronioshoeglue@aol.com Contact person: Don Rinaldi Emergency 24hr Assistance Infotrac: 800-55-505 SECTION 2: Hazards identification Route(s) of Entry Signs and Symptoms of Exposure Carcinogenicity (NTP): Carcinogenicity (IARC): Carcinogenicity (OSHA): Other hazards In use, may form flammable/explosive vapour-air mixture. SECTION : Composition/information on ingredients Mixtures
DATE: 6/1/12 Page 2 of 7 Hazardous components CAS No. Components Quantity 68476-50-6 Solvent 60/95 25-5 % 141-78-6 Ethylacetate 20-0 % 110-82-7 Cyclohexane 20-0 % SECTION 4: First aid measures Description of first aid measures After inhalation Move to fresh air in case of accidental inhalation of vapours. call a physician. Consult a physician. If symptoms persist, After contact with skin Take off all contaminated clothing immediately. Wash off with soap and water. Grease skin after contact. After contact with eyes Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Consult a physician. After ingestion Do not induce vomiting. Call a physician immediately. Indication of any immediate medical attention and special treatment needed In case of shortness of breath, give oxygen. Risk of product entering the lungs on vomiting after ingestion. SECTION 5: Firefighting measures Extinguishing media Suitable extinguishing media carbon dioxide (CO2) dry chemical foam water spray Unsuitable extinguishing media high volume water jet Special hazards arising from the substance or mixture In the event of fire and/or explosion do not breathe fumes. In case of fire production of HCl-gases. Advice for firefighters In the event of fire, wear self-contained breathing apparatus. Additional information Use water spray to cool unopened containers. SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures Remove all sources of ignition. When using do not smoke. Ensure adequate ventilation. Environmental precautions Do not let product enter drains. Methods and material for containment and cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Dispose of as special waste in compliance with local and national regulations SECTION 7: Handling and storage Precautions for safe handling
DATE: 6/1/12 Page of 7 Advice on safe handling Use only in well-ventilated areas. Use only in area provided with appropriate exhaust ventilation. Provide sufficient air exchange and/or exhaust in work rooms. Advice on protection against fire and explosion Keep away from sources of ignition - No smoking. Take precautionary measures against static discharges. In use, may form flammable/explosive vapour-air mixture. Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Keep containers tightly closed in a cool, well-ventilated place. Keep at temperatures between 5 and 40 C. Advice on storage compatibility Keep away from food, drink, and animal feeding stuffs. Further information on storage conditions Keep away from heat. Protect against freezing. Keep container tightly closed in a dry and well-ventilated place. Keep away from direct sunlight. SECTION 8: Exposure controls/personal protection Control parameters Exposure limits CAS No. Components ppm mg/m³ fib/cc Category Origin 110-82-7 Cyclohexane 00 1050 TWA (8 h) PEL 141-78-6 Ethyl acetate 400 1400 TWA (8 h) PEL 68476-50-6 Solvent 60/95 200 1000 TWA (8 h) MAK Exposure controls 200 1000 TWA (8 h) MAK 200 1000 TWA (8 h) MAK Protective and hygiene measures When using do not eat or drink. When using do not smoke. Wash hands before breaks and immediately after handling the product. Use protective skin cream before handling the product. Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink, and animal feeding stuff. Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment. (gas filter type A2 ) Hand protection solvent-resistant gloves: nitrile rubber, butyl-rubber, fluoric rubber Test suitability of gloves before use. Eye protection safety glasses
DATE: 6/1/12 Page 4 of 7 SECTION 9: Physical and chemical properties Information on basic physical and chemical properties Form: Color: Odor: ph-value: Changes in the physical state Melting point: Boiling point: Flash point: Lower explosion limits: Upper explosion limits: Ignition temperature: liquid yellow ester-like, mild not applicable -4 - +8 C Test method 40-80 C DIN 5 171-18 C 0,6 vol. % 1 vol. % 260 C DIN 51 755 DIN 51 794 Vapour pressure: (at 20 C) 120 hpa DIN EN 12 Density (at 20 C): 0,810 g/cm³ DIN 51 757 Water solubility: Viscosity / dynamic: (at 20 C) Solvent content: SECTION 10: Stability and reactivity Stability: Possibility of Hazardous Reactions: Stable Will not occur insoluble 1050 mpa s 79 % DIN 5018 Conditions to avoid Above 10 C, hazardous fumes may be released. No decomposition if used as directed. Incompatible materials Keep away from oxidizing agents, strongly alkaline and strongly acid materials in order to avoid exothermic reactions. Hazardous decomposition products Heating can release hazardous gases. Carbon oxides In the event of fire the following can be released: carbon dioxide (CO2) Carbon monoxide SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Health injuries are not known or expected under normal use. Specific effects in experiment on an animal no data available No data is available on the product itself. Irritation and corrosivity Inhalation of vapours may cause irritation of the respiratory system in very susceptible persons. May cause skin and eye irritation in susceptible persons. Sensitizing effects contains Kolophonium
DATE: 6/1/12 Page 5 of 7 Severe effects after repeated or prolonged exposure Inhalation of vapours in high concentration can cause narcotic effects and metabolic acidosis. Carcinogenic/mutagenic/toxic effects for reproduction No data is available on the product itself. SECTION 12: Ecological information Toxicity The product is insoluble and floats on water. Persistence and degradability Taking into consideration the properties of several components, the product is estimated not to be readily biodegradable according to OECD classification. Bioaccumulative potential No data is available on the product itself. Mobility in soil No data is available on the product itself. Further information Do not let product enter drains. SECTION 1: Disposal considerations Waste treatment methods Advice on disposal Dispose of as special waste in compliance with local and national regulations Contaminated packaging Offer rinsed packaging material to local recycling facilities. Recycling of packaging materials (dual system). SECTION 14: Transport information US DOT 49 CFR 172.101 Proper shipping name, containing a flammable liquid Dangerous Component: cyclohexane ID Number: UN Hazard Class or Division: Label: Land transport (ADR/RID) UN number: Hazard label: Hazardous Material: : cyclohexane +10 Classification Code: F1
DATE: 6/1/12 Page 6 of 7 Limited quantity: Hazard-no.: Tunnel restriction code: Special provisions: 640H E1 Transport category: Inland waterways transport UN number: LQ7 D/E Hazardous Material: cyclohexane Hazard label: +10 Classification Code: Limited quantity: : 640H Marine transport UN number: Hazard label: F1 LQ7 Hazardous Material: : cyclohexane +10 Marine pollutant: Limited quantity: EmS: Category A : 22, 944, 955 Category: A Air transport UN/ID number: Hazard label: 5 L F-E, S-D Hazardous Material: cyclohexane +10
DATE: 6/1/12 Page 7 of 7 Limited quantity Passenger: IATA-packing instructions - Passenger: IATA-max. quantity - Passenger: IATA-packing instructions - Cargo: IATA-max. quantity - Cargo: : Y09 E 220 L SECTION 15: Regulatory information U.S. Regulations SECTION 16: Other information 10 L 09 60 L 10 220 L Hazardous Materials Information Label (HMIS) Health: 1 Flammability: 4 Physical Hazard: 2 Personal Protection: C NFPA Hazard Ratings Health: Flammability: Reactivity: Unique Hazard: 1 4 0 Other data The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport, and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material. 1 4 0