MSDS Number: : F : H229 Pressurized container: May burst if heated.

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Transcription:

SECTION 1. IDENTIFICATION Product name : Product code : Manufacturer or supplier's details Company name of supplier : XL Brands, LLC Address : 198 Nexus Drive Dalton GA 30721 Telephone : (800) 367-4583 Telefax : (800) 547-0098 Emergency telephone number : (CHEMTREC): (800) 424-9300 (CHEMTREC International): (703) 527-3887 Industrial Health/Spill Emergency: (706) 277-1300 Danny Welch (ehs@trcc.com) SECTION 2. HAZARDS IDENTIFICATION GHS Classification : Compressed gas GHS Label element Hazard pictograms : Signal word Hazard statements Precautionary statements : Warning : H229 Pressurized container: May burst if heated. : P412 Do not expose to temperatures exceeding 50 C/ 122 F. P235 + P410 Keep cool. Protect from sunlight. P103 Read label before use. P102 Keep out of reach of children. Other hazards None known. 1 / 9

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components No hazardous ingredients SECTION 4. FIRST AID MEASURES If inhaled In case of skin contact In case of eye contact If swallowed Most important symptoms and effects, both acute and delayed : Move to fresh air in case of accidental inhalation of vapours. Oxygen or artificial respiration if needed. Call a physician or poison control centre immediately. : Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If symptoms persist, call a physician. : In case of eye contact, remove contact lens and rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Seek medical advice. : Do not induce vomiting without medical advice. If conscious, drink plenty of water. Never give anything by mouth to an unconscious person. : None known. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media Specific hazards during firefighting Specific extinguishing methods : Dry powder Foam Carbon dioxide (CO2) Water mist : Burning produces irritant fumes. Exposure to decomposition products may be a hazard to health. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire fighting to enter drains or water courses. : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use a water spray to cool fully closed containers. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. 2 / 9

Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. Exposure to decomposition products may be a hazard to health. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Use personal protective equipment. Ensure adequate ventilation. Material can create slippery conditions. Use non-slip safety shoes in areas where spills or leaks can occur. : Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Do not allow contact with soil, surface or ground water. Do not allow uncontrolled discharge of product into the environment. : Dam up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Sweep up and shovel. Pick up and transfer to properly labelled containers. Clean contaminated floors and objects thoroughly while observing environmental regulations. SECTION 7. HANDLING AND STORAGE Advice on protection against fire and explosion Advice on safe handling Conditions for safe storage Materials to avoid : The product is not flammable. Keep away from heat and sources of ignition. : Wear personal protective equipment. Handle with care. Take care to avoid waste and spillage when weighing, loading and mixing the product. : No smoking. Keep in properly labelled containers. Observe label precautions. Keep containers tightly closed in a dry, cool and wellventilated place. Store between 5 and 25 C in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. : Do not freeze. Keep away from food and drink. Keep away from tobacco products. 3 / 9

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Contains no substances with occupational exposure limit values. Engineering measures : Handle only in a place equipped with local exhaust (or other appropriate exhaust). Maintain air concentrations below occupational exposure standards. Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally required. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Use NIOSH approved respiratory protection. Hand protection Material : Impervious gloves Eye protection Skin and body protection Protective measures Hygiene measures : Safety glasses with side-shields Tightly fitting safety goggles Face-shield : Chemical resistant apron Footwear protecting against chemicals Skin should be washed after contact. Change working clothes after each workshift. : Avoid contact with skin. When using do not eat, drink or smoke. Personal protective equipment comprising: suitable protective gloves, safety goggles and protective clothing The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. : Do not smoke. Keep away from food and drink. Avoid contact with skin, eyes and clothing. Change working clothes after each workshift. Remove and wash contaminated clothing and gloves, including the inside, before re-use. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Colour : aerosol : white 4 / 9

Odour : characteristic ph : No data available Melting point/range : No data available Boiling point/boiling range : 212 F Flash point : > 212 F Vapour pressure : 18.65 mmhg (70 F) Density : 970-1,030 kg/m3 Solubility(ies) Water solubility Solubility in other solvents Partition coefficient: n- octanol/water Explosive properties : dispersible : Not applicable : No data available : Not applicable SECTION 10. STABILITY AND REACTIVITY Reactivity Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : Stable : Stable under recommended storage conditions. : Protect from frost, heat and sunlight. : No data available : Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx), dense black smoke. SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Product: Acute oral toxicity Acute inhalation toxicity : Remarks: No data available : LC50 (Rat): 1,500 g/m3 Exposure time: 4.0 h 5 / 9

The value is given in analogy to the following substances: Skin corrosion/irritation Product: Remarks: May irritate skin. May cause skin irritation and/or dermatitis. Serious eye damage/eye irritation Product: Remarks: May irritate eyes. Carcinogenicity IARC OSHA NTP No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Product: Toxicity to fish : Remarks: May cause long-term adverse effects in the aquatic environment. Toxicity to daphnia and other aquatic invertebrates : Remarks: May cause long-term adverse effects in the aquatic environment. Toxicity to algae : Remarks: May cause long-term adverse effects in the aquatic environment. Persistence and degradability No data available Bioaccumulative potential No data available 6 / 9

Mobility in soil No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues Contaminated packaging : Do not dispose of waste into sewer. Dispose of in accordance with local regulations. Can be landfilled or incinerated, when in compliance with local regulations. : Clean container with water. Empty containers should be taken to an approved waste handling site for recycling or disposal. SECTION 14. TRANSPORT INFORMATION International Regulation IATA-DGR UN/ID No. : UN 1950 Proper shipping name : Aerosols, non-flammable (AEROSOLS, ) Class : Packing group : Not assigned by regulation Labels : Non-flammable, non-toxic Gas Packing instruction (cargo : 203 aircraft) Packing instruction (passenger : 203 aircraft) IMDG-Code UN number : UN 1950 Proper shipping name : AEROSOLS Class : Packing group : Not assigned by regulation Labels : EmS Code : F-D, S-U Marine pollutant : no Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. National Regulations 49 CFR UN/ID/NA number : UN 1950 7 / 9

Instability SAFETY DATA SHEET Proper shipping name : AEROSOLS (AEROSOLS, ) Class : Packing group : Not assigned by regulation Labels : NON-FLAMMABLE GAS ERG Code : 126 Marine pollutant : no SECTION 15. REGULATORY INFORMATION SARA 302 SARA 313 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. California Prop 65 TSCA This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. All components of this product appear on the Inventory of Chemical Substances published by the U.S. Environmental Protection Agency (EPA) under the authority of the Toxic Substances Control Act (TSCA). SECTION 16. OTHER INFORMATION Further information NFPA: Flammability HMIS III: 0 HEALTH 1 Health 1 0 FLAMMABILITY 0 PHYSICAL HAZARD Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Revision Date : 8 / 9

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. US / EN 9 / 9