Safety Data Sheet. Product Identification Product Name: Biomix 20, Biomix 35, BioMix 50 Natural Hydraulic Lime Mortar

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Transcription:

Safety Data Sheet 1. PRODUCT AND COMPANY IDENTIFICATION Product Identification Product Name: Biomix 20, Biomix 35, BioMix 50 Product Use: Natural Hydraulic Lime Mortar Company Identification Edison Coatings, Inc. 3 Northwest Drive Plainville, CT 06062 Edison Coatings Tech Info Phone: 1-860-747-2220 Emergency Phone: 1-800-535-5053 2. HAZARDS IDENTIFICATION Hazard Classification This material is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR 1910.1200. Skin Irritation Category 2 Eye Irritation Category 2A Respiratory Sensitization Category 1 Skin Sensitization Category 1 Carcinogen Category 2 Label Elements Hazard Pictograms Signal Word: WARNING

Hazards May cause skin irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Causes eye irritation. Suspected of causing cancer through repeated inhalation over a long period of time. Precautionary Statements Prevention Wash thoroughly after handling. Wear protective gloves/clothing/eye protection/face protection. Avoid breathing dust. Other Hazards No data available Response IF SWALLOWED: Do not induce vomiting. If conscious, have victim drink plenty of water and call a physician immediately. IF ON SKIN: Wash with soap and water. If skin irritation occurs: Get medical advice. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice. Storage Store in dry, cool environment. Disposal Dispose of contents in accordance with local regulations.

3. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS Ingredient Name CAS-No. Lime 1305-62-0 Di-Calcium Silicate 10034-77-2 Limestone 471-34-1 Calcium Sulfate 7778-18-9 Magnesium Oxide 1309-48-4 Calcium Oxide 1305-78-8 Crystalline Silica 14808-80-7 Chromates Various Arsenic (Impurity in Limestone) 7440-38-2 Lead (Impurity in Limestone) 7439-92-1 Nuisance Dust Various Approx. Chemical Name Weight% <20% Calcium Hydroxide <15% Di-Calcium Silicate <5% Calcium Carbonate 0.2 1.0% Calcium Sulfate 0 0.8% Magnesium Oxide 0 0.1% Calcium Oxide <80% Silicon Dioxide 0 0.001% Various <0.5 ppm Arsenic <1 ppm Lead Various Various 4. First Aid Measures Eye Contact: Flush eyes with plenty of water for 15 min. while holding eyelids open. Get medical attention. Skin Contact: Wash skin with cool water and ph-neutral soap or a mild detergent. Seek medical treatment in all cases of prolonged exposure to wet product. Ingestion: Do not induce vomiting. If conscious, have victim drink plenty of water and call a physician immediately. Inhalation: Remove victim to fresh air. Seek medical help if coughing and other symptoms do not subside. Inhalation of gross amounts of this product requires immediate medical attention. Medical Conditions Aggravated by Exposure: Pre-existing upper respiratory and lung diseases. Unusual sensitivity to hexavalent chromium salts.

5. FIRE FIGHTING MEASURES Extinguishing Media: None required. Unusual fire and explosion hazards: None. Fire Fighting Procedures: Material will not burn. None required. 6. ACCIDENTAL RELEASE MEASURES Action to be taken if material is released or spilled: If the material is spilled, use dustless methods (vacuum) and place into closable container for disposal, or flush with water. Do not dry sweep. Wear protective equipment. 7. HANDLING AND STORAGE Precautions to be taken in handling and storage: Keep this product dry until use. Normal temperatures do not affect the material. Avoid breakage of bagged material or spills of bulk material. Promptly remove dusty clothing or clothing which is wet with cement fluids and launder before reuse. Wash thoroughly after exposure to dust or wet cement mixtures or fluids. Use dustless systems for handling, storage, and cleaning so that airborne dust does not exceed the PEL. Use adequate ventilation and dust collection. Practice good housekeeping. Do not permit dust to collect on walls, floors, sill, edges, machinery, or equipment. Maintain clean and fit test respirators in accordance with OSHA regulations. Maintain and test ventilation and dust collection equipment. Wash or vacuum clothing which has become dusty. 8. PERSONAL PROTECTIVE EQUIPMENT AND EXPOSURE CONTROLS Personal Protective Equipment Eye and Face Protection: Where potentially subject to splashes or puff of material, wear safety glasses with side shields or goggles. In extremely dusty environments and unpredictable environments, wear unvented or indirectly vented goggles to avoid eye irritation or injury. Contact lenses should not be worn when working with this product.

Skin Protection: Avoid contact with unhardened product. If contact occurs, promptly wash affected area with soap and water. Where prolonged exposure to unhardened product might occur, wear impervious clothing and gloves to eliminate skin contact. Where required, wear sturdy boots that are impervious to water to eliminate foot and ankle exposure. Do not rely on barrier creams; barrier creams should not be used in place of gloves. Periodically wash areas contacted by dry product or wet product or fluids with a ph-neutral soap. Wash again at the end of work. If irritation occurs, immediately wash affected area and seek treatment. If clothing becomes saturated with wet product, it should be removed and replaced with clean, dry clothing. Other Personal Protection Data: Eye wash fountains and safety showers should be available for emergency use. Usual industrial work clothes should be worn. Respiratory Protection: Avoid actions that cause dust to become airborne. However, a respirator is recommended for protection against crystalline silica. Use only a NIOSH-approved respirator. Ventilation: Use local exhaust or general dilution ventilation to control exposure within applicable limits. Exposure Guidelines There is no data available on either OSHA Permissible Exposure Limits (PEL s) or ACGIH Threshold Limit Value (TLV s) for components of product. 9. PHYSICAL PROPERTIES Odor: Normal for this product. Physical State: Solid; Graded, Granular Powder ph: Vapor Pressure (mmhg): Vapor Density (Air=1): Boiling Point: Solubility in Water: Miscible Coefficient of water/oil distribution: Density (grams per milliliter): 1.44 Evaporation Rate (Ether=1): Flash Point (Fahrenheit): Flash Point (Celsius): Lower Explosive Limit (%): Upper Explosive Limit (%): Autoignition temperature:

10. STABILITY AND REACTIVITY Stability: Conditions to Avoid: Incompatibility: Hazardous Polymerization: Hazardous Decomposition Products: Sensitivity to static discharge: All components are stable. Sub-freezing temperatures, Unintentional contact with water Strong oxidizing agents None anticipated. Silica will decompose with hydrofluoric acid, which gives off a corrosive gas, Silicon Tetrafluoride. Adding water produces caustic calcium hydroxide. Not determined. 11. TOXICOLOGICAL INFORMATION Mutagens/Teratogens/Carcinogens: This product is not listed as a carcinogen by NTP, OSHA, or IARC. It may, however, contain trace amounts of substances listed as carcinogens by these organizations. Crystalline silica, a potential trace level contaminant in this product, is now classified by IARC as a known human carcinogen (Group 1). NTP has characterized respirable silica as reasonably anticipated to be [a] carcinogen. 12. ECOLOGICAL DATA No information on ecology is available. 13. DISPOSAL CONSIDERATIONS The packaging and material maybe land-filled, however, material should be covered to minimize generation of airborne dust. RCRA: Crystalline silica (quartz) is NOT classified as a hazardous waste under the Resource Conservation and Recovery Act. Dispose of waste material according to local, state, and federal regulations. Dispose of bags in an approved landfill or incinerator 14. TRANSPORTATION INFORMATION No information on transportation is available.

15. REGULATORY INFORMATION OSHA Hazard Communication Rule, 29 CFR 1910.1200 This product is considered a hazardous chemical under this regulation, and should be part of any hazard communication program. CERCLA/Superfund, 40 CFR 117 and 302 This product is not classified as a hazardous substance under these regulations. SARA (Title III), Section 311 and 312 This product qualifies as a hazardous substance with delayed health effects. Toxic Substance Control Act Some substances in this product are on the TSCA inventory list, one of them being Crystalline silica (quartz) appearing on the EPA TSCA inventory under CAS# 14808-80-7. The Federal Hazardous Substances Act This product is a hazardous substance subject to statutes promulgated under the subject act. NTP A component of this product, respirable crystalline silica (quartz) is classified as a probable carcinogen. California PROPOSITION 65 A component of this product, crystalline silica (quartz) is classified as a substance known to the state of California to be a carcinogen. 16. OTHER INFORMATION Effective Date: Revision Date: 16/Apr/2015 8/Aug/2017