KLEENEX Green Certified Foam Skin Cleanser

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Transcription:

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Product code : 11285, 35042, 91565, 91591,12565 Manufacturer or supplier's details Recommended use of the chemical and restrictions on use Company : Kimberly-Clark Australia Pty. Limited 52 Alfred Street, Milsons Point Sydney 2061 Australia Telephone : +61 1800-647-994 Telefax : +61 2-9957-5687 E-mail address Responsible/issuing person : sdscontact@kcc.com Emergency telephone number : +61 1800-647-994 This telephone number is available during office hours only. Recommended use : Skin-care SECTION 2. HAZARDS IDENTIFICATION GHS Classification Not a hazardous substance or mixture. GHS label elements Not a hazardous substance or mixture. Other hazards which do not result in classification None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous components Chemical name CAS-No. Concentration (% w/w) Propylene Glycol 57-55-6 < 10 1 / 8

SECTION 4. FIRST AID MEASURES If inhaled : No hazards which require special first aid measures. In case of skin contact : Not required under normal use. Wash off with plenty of water. Get medical attention if irritation develops and persists. In case of eye contact : Flush eyes with water at least 15 minutes. Get medical attention if eye irritation develops or persists. If swallowed : Not required under normal use. Drink 1 or 2 glasses of water. If large quantities of this material are swallowed, call a physician immediately. Most important symptoms and effects, both acute and delayed : No hazards which require special first aid measures. None known. Notes to physician : No hazards which require special first aid measures. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Hazardous combustion products : Carbon monoxide, carbon dioxide and unburned hydrocarbons (smoke). No hazardous combustion products are known Specific extinguishing methods Special protective equipment for firefighters : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : In the event of fire, wear self-contained breathing apparatus. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Not required under normal use. Environmental precautions : No special environmental precautions required. Methods and materials for containment and cleaning up : Flush with water. SECTION 7. HANDLING AND STORAGE 2 / 8

Advice on safe handling : Avoid spillage on floor as the product can become very slippery when wet. Hygiene measures : not required under normal use Conditions for safe storage : No special storage conditions required. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type Control parameters Basis (Form of exposure) / Permissible concentration Propylene Glycol 57-55-6 TWA 150 ppm AU OEL 474 mg/m3 TWA 10 mg/m3 AU OEL TWA (particulate) 10 mg/m3 AU OEL TWA (Total (vapour and particles)) 150 ppm 474 mg/m3 AU OEL Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally required. Protective measures : No special protective equipment required. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Colour : clear Odour : pleasant ph : 5-6 Melting point/range : No data available Boiling point/boiling range : > 212 C Flash point : Not applicable Upper explosion limit : Not applicable Lower explosion limit : Not applicable Relative density : 15-25 3 / 8

Solubility(ies) Water solubility : completely soluble SECTION 10. STABILITY AND REACTIVITY Incompatible materials : No information available. SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Acute oral toxicity : LD50 Oral (Rat, male and female): 22,000 mg/kg Method: Acute toxicity estimate GLP: no Acute inhalation toxicity : LC50 (Rabbit): > 317,042 mg/m3 Exposure time: 2 h Method: No information available. GLP: no Acute dermal toxicity : LD50 Dermal (Rabbit): > 2,000 mg/kg Method: No information available. GLP: no Skin corrosion/irritation Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation GLP: No information available. Serious eye damage/eye irritation Species: Rabbit Result: No eye irritation Method: OECD Test Guideline 405 GLP: No information available. 4 / 8

Respiratory or skin sensitisation Test Type: Maximisation Test Species: Guinea pig Method: OECD Test Guideline 406 Result: Did not cause sensitisation on laboratory animals. GLP: No information available. Chronic toxicity STOT - single exposure Product: Remarks: Not applicable STOT - repeated exposure Product: Remarks: Not applicable Aspiration toxicity Product: No aspiration toxicity classification SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 40,613 mg/l Exposure time: 96 h Test Type: static test Method: No information available. GLP: no Toxicity to daphnia and other aquatic invertebrates : EC50 (Americamysis): 18,800 mg/l Exposure time: 96 h Test Type: static test Method: No information available. GLP: yes Toxicity to algae : EC50 (Pseudokirchneriella subcapitata (green algae)): 24,200 mg/l Exposure time: 72 h Test Type: static test 5 / 8

Method: OECD Test Guideline 201 GLP: yes Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC: 13,020 mg/l Exposure time: 7 d Persistence and degradability No data available Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with local regulations. Contaminated packaging : Dispose of as unused product. SECTION 14. TRANSPORT INFORMATION International Regulation UNRTDG Not regulated as a dangerous good IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. National Regulations ADG Not regulated as a dangerous good SECTION 15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Standard for the Uniform Scheduling of Medicines and : No poison schedule number allocated 6 / 8

Poisons Prohibition/Licensing Requirements : There is no applicable prohibition or notification/licensing requirements, including for carcinogens under Commonwealth, State or Territory legislation. SECTION 16. OTHER INFORMATION Full text of other abbreviations AICS - Australian Inventory of Chemical Substances; ANTT - National Agency for Transport by Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR - Carcinogen, Mutagen or Reproductive Toxicant; CPR - Controlled Products Regulations; DIN - Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NOM - Official Mexican Norm; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; SADT - Self- Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vpvb - Very Persistent and Very Bioaccumulative; WHMIS - Workplace Hazardous Materials Information System Further information Other information : The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other 7 / 8

materials or in any process, unless specified in the text. Date format : dd.mm.yyyy The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. AU / EN 8 / 8