Development and Application of Liquid-cooled Lithium-ion Battery Pack Thermal Model

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Development and Application of Liquid-cooled Lithium-ion Battery Pack Thermal Model Model based approach by using GT-SUITE Yifan (Flora) Zhou DEP Fan He Optimal Xinran Tao Optimal Meng Li DEP Wei Tao FCA US LLC GT 17 - Plymouth, MI November, 2017 2017 FCA US LLC

Contents Background and motivation Battery electric-thermal modeling Application in production Conclusion Acknowledgement 11/06/2017 2

Motivation: Battery Thermal Modeling Battery cell temperature and hot spots can have a critical impact on cell, pack and battery system performance. Proper thermal management prevents: Thermal runaway Low fuel economy Reduced battery life Poor performance High-fidelity battery pack and cooling system model is important for accurate control and proper thermal management. ΔTemp Hot spot ΔTemp Battery Cooling system Pump sizing Flow, heater and AC control Warm-up strategy 11/06/2017 3

Heat generation Single Cell Modeling Concept Diagram: Battery pack and cooling system Every single cell GT model includes electrical and thermal sub-models This model is for an indirect liquid-cooling battery thermal system Vehicle speed Single Cell Cooling Fin Power demand Battery Thermal Pad Cooling Plate Thermal Pad Cooling Plate Battery: Electrical Battery: Thermal Cell temperature Heat removal by cooling system Cooling System 11/06/2017 4

Battery Model Capturing Current and Heat Generation Non-uniformity To resolve current, heat generation and temperature non-uniformity within one cell, a detailed electrical model consisting of cathode, anode and sub-cell electrical networks is required. A Single cell model consisting of 3 sub-cells (in 1x3 configuration) is shown below Rci: electrical resistances on cathode current collector Rin: internal resistance of sub-cell OCV: open circuit voltage of sub-cell\ H: Cell height W: Cell width 11/06/2017 5

Battery Cell Thermal Modeling A battery cell thermal model template has been developed. Battery thermal behavior prediction Battery cell model offers transient thermal behavior prediction, given variable charging/discharging cycles and different coolant flow rates and temperatures Battery temperature distribution prediction Battery pack Max/Min temperature prediction, as well as coolant temperature change can be achieved, by using simulation from knowledge of specific boundary conditions. Battery cell electric sub model for current density/heat generation distribution calculation Battery cell thermal sub model for temperature distribution estimation Q out Q in Battery Thermal Pad Cooling Plate Battery cell cooling --- natural convection Battery cell cooling pad/coolant flow thermal mass for heat removal rate estimation 11/06/2017 6

System Model Integration Assembly from previous slide battery cell model is packaged as a GT compound template. The battery cell temperature, coolant temperature and SOC can directly link to ICOS for system level co-simulation. Battery Pack Battery Cell Cooling Pipe ICOS: GT s co-simulation template -- UserCodeCControls 11/06/2017 7

Heat Transfer Coefficient Heat transfer coefficient (HTC) at cooling pad on the coolant side is calculated through Dittus-Boelter Correlation. Dittus-Boelter Correlation: h = 0.23 k d d μ cp (j μ )0.8 ( k )0.33 h: Heat transfer coefficient d: Hydraulic diameter k: Thermal conductivity μ: Fluid viscosity j: Mass flux cp: Heat capacity of fluid Effective convection thermal resistance of cooling plate derived from HTC as a transient function of coolant flow rate 11/06/2017 8

Simulation Assumptions By neglecting electric work done in the electrolyte and the reversible entropic loss, which can be neutralized during charging/discharging reaction, heat generation in one battery cell can be considered to be mainly contributed by Joule losses calculated as Q= RI 2 [watt] In which, I: Current, R: Internal resistance, Q: Heat generation rate Coolant inlet temperature and ambient temperature are set to be 18 C Battery cell divided into 3 uniform thermal masses. Inside each mass the heat generation is estimated as a function of local current density and equivalent resistance, arranged as shown with bottom part connected to cooling pad Cooling surface Different coolant volume flow rates are investigated Define the transient current profile Convective heat transfer coefficient between battery and air is 5W/m 2 K 11/06/2017 9

Simulation Cases Boundary Conditions Cas e Current Profile Coolant Flow Rate (L/min) Coolant Inlet T ( C) Ambient T ( C) Battery Cell Initial T ( C) Initial SOC 1 shown as Constant Flow Current Profile 1C 2 Profile shown as Coolant Flow 18 25 25 0.9 8,000s 11/06/2017 10

Case Battery Pack Results Correlation Current Profile Coolant Flow Rate Coolant Inlet T ( C) Ambient T ( C) Battery Cell Initial T ( C) 1 1C Constant Flow 18 25 25 0.9 Initial SOC Heat generation from battery charge & discharge Constant coolant mass flow rate applied for battery temperature stabilization Convection cooling & Cooling system effect Input electric current drops to 0A at 6,000s, without heat generation, the temperature decreases very fast A good correlation between test data and GT simulation results achieved with an error smaller than 1%. 6,000s 10,000s Max T @6,000s ( C) Coolant outlet T @10,000s ( C) Error 0.9% 0.05% 11/06/2017 11

Battery Pack Results Correlation Case Current Profile For the first 6000s, with no coolant flow applied, cell temperature increases Cell temperature drops slowly due to air convection without heat generation (current is 0A) during 6,000-8,000 sec of the simulation Coolant Flow Rate Coolant Inlet T ( C) Ambient T ( C) Battery Cell Initial T ( C) 2 1C Coolant Flow 3 18 25 25 0.9 Heat generation from battery charge & discharge Convection cooling Convection cooling & Cooling system effect Initial SOC Coolant started flowing after 8,000 sec, the battery temperature decreases dramatically. 6,000s 8,000s 10,000s Coolant flow begins Max T @6000s ( C) Coolant outlet T @10,000s ( C) Error -3.2% 1.1% 11/06/2017 12

Summary GT battery cell model template was applied to a battery thermal model for transient heat generation rate calculation, battery cell temperature distribution prediction and overall cooling system performance evaluation Integrated battery pack thermal model, developed with proposed single cell model offers accurate estimation of hottest individual cell temperature as well as battery pack coolant temperature change at outlet Proposed GT template-based battery pack model provided a fast simulation of thermal behavior and is convenient for integration into the whole vehicle level simulation Future work includes model based thermal management control strategy development and experimental validation for improved simulation accuracy 11/06/2017 13

Acknowledgement The authors gratefully appreciate support from Oliver Gross Andrew Best Craig Linguist Pawel Malysz Joe Wimmer Brad Holcomb 11/06/2017 14