01. Identification of substance, preparation and company Product name (15050541004038) Manufacturer/Supplier Stefan Kupietz GmbH & Co. KG Street/P.O. Box August-Wilhelm-Kühnholz-Straße 9 Country code/postal code/town/city 26135 Oldenburg Telephone / Fax +49(0)441/20 69 50 / +49(0)441 /20 69 520 Emergency information +49(0)171 / 27 333 53 02. Composition/information on ingredients Hazardous components 1-METHOXY-2-PROPANOL ; EC-No. : 203-539-1 ; CAS-No. : 107-98-2 Classification : R 10 ETHYL ACETATE ; EC-No. : 205-500-4 ; CAS-No. : 141-78-6 Classification : F ; R 11 Xi ; R 36 R 67 R 66 Oligotriacrylat ; CAS-No. : 52408-84-1 Classification : Xi ; R 36 Pigment Green 1 ; EC-No. : 269-840-5 ; CAS-No. : 1325-75-3 Classification : R 52/53 Xi ; R 36 Acrylharz Classification : Xi ; R 36 2-METHYL-1-(4-METHYLTHIOPHENYL)-2-MORPHOLINOPROPAN-1-ONE ; EC-No. : 400-600-6 ; CAS-No. : 71868-10-5 Percentage : 2,5-5 % Classification : N ; R 51/53 Xn ; R 22 2,2 -(METHYLIMINO)DIETHANOL ; EC-No. : 203-312-7 ; CAS-No. : 105-59-9 Classification : Xi ; R 36 PENTAERYTHRITOL TRIACRYLATE ; EC-No. : 222-540-8 ; CAS-No. : 3524-68-3 Classification : R 43 Xi ; R 36/38 PENTAERYTHRITOL TETRAACRYLATE ; EC-No. : 225-644-1 ; CAS-No. : 4986-89-4 Classification : R 43 Xi ; R 36/38 2,4,6,-Trimethylbenzoylphenylphosphinsäureethylester ; EC-No. : 282-810-6 ; CAS-No. : 84434-11-7 Classification : R 52/53 (2-METHOXYMETHYLETHOXY)PROPANOL ; EC-No. : 252-104-2 ; CAS-No. : 34590-94-8 Page : 1 / 6
Percentage : 25-30 % For the wording of the listed risk phrases refer to section 16. 03. Hazards identification Hazard designation Flammable. May cause sensitisation by skin contact. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Irritating to eyes. Classification : R 10 R 43 R 52/53 Xi ; R 36 04. First-aid measures General Immediately remove all contaminated clothing. After inhalation Let in fresh air. After skin contact Wash away with soap and water and rinse. After eye contact Flush with plenty of water (10-15 min.). Call a physician. After ingestion Drink plenty of water. 05. Fire-fighting measures Suitable extinguishing media Alcohol resistant foam, CO2, powders, water spray. Additional information Cool endangered containers with water in case of fire. 06. Accidental release measures Personal precautions Keep away from ignition sources on account of the organic solvent content and air room well. Do not inhale vapours. Environmental precautions Take up with a liquid absorbing material and proceed according to the waste disposal regulations. Do not empty into drains. Methods for cleaning up/collecting Remove mechanically, take-up residues with absorbing material. 07. Handling and storage Information for safe handling Normal precautions taken when handling chemicals should be observed. Only use in locations with adequate suction ventilation. Information about protection against explosions and fires Take precautionary measures against static discharges. Keep away from ignition sources and provide for good ventilation. Requirements to be met by storerooms and containers Do not leave vessels open, earth storage containers. Information about separation of incompatible products Store the foodstuffs separately. Keep away from oxidizing agents, from strongly alkaline and strongly acid materials. Further information about storage conditions Store containers tightly closed in a cool well ventilated place. Storage class (VCI) : 3A Page : 2 / 6
08. Exposure controls and personal protection Components with critical values that require monitoring at the workplace (exposure limits) (2-METHOXYMETHYLETHOXY)PROPANOL ; CAS-No. : 34590-94-8 Specification : TRGS 900 - maximum limit in the atmosphere at the workplace ( D ) Value : 50 ppm / 310 mg/m 3 Category : 1(I) Version date : 01.01.2006 Specification : threshold limit value ( EC ) Value : 50 ppm / 308 mg/m 3 H Version date : 08.06.2000 1-METHOXY-2-PROPANOL ; CAS-No. : 107-98-2 Specification : TRGS 900 - maximum limit in the atmosphere at the workplace ( D ) Value : 100 ppm / 370 mg/m 3 Category : 2(I) Y Version date : 01.01.2006 Specification : Short term exposure limit ( EC ) Value : 150 ppm / 568 mg/m 3 H Version date : 08.06.2000 Specification : threshold limit value ( EC ) Value : 100 ppm / 375 mg/m 3 H Version date : 08.06.2000 ETHYL ACETATE ; CAS-No. : 141-78-6 Specification : TRGS 900 - maximum limit in the atmosphere at the workplace ( D ) Value : 400 ppm / 1500 mg/m 3 Category : 2(I) Y Version date : 01.01.2006 Personal protective equipment General protective and hygiene measures The usual precautionary measures for the handling of chemicals have to be observed. Hand protection Use protective butyl rubber gloves (0,5 mm). Permeationtime of glovematerial: level >= 240 min (4h) EN374 Eye protection Use tightly fitting safety glasses. 09. Physical and chemical properties Image Form : Colour : Odour : Relevant safety data Liquid. Coloured. Noticeable. Boiling point / range : ( 1013 hpa ) > 100 C Flash point : 23-61 C Abel-Pensky Vapour pressure : ( 50 C ) < 1100 hpa Page : 3 / 6
Density : ( 20 C ) 0,9-1,4 g/cm 3 Solvent-separation test : ( 20 C ) < 3 % Flow time : ( 20 C ) 12-222 s DIN-cup 4 mm Additional information The physical specifications are approximate values and refer to the used safety relevant component(s). 10. Stability and reactivity Materials to avoid Keep away from oxidizing agents, strongly alkaline and strongly acid materials in order to avoid exothermic reactions. In connection with inorganic and organic acids, acid chlorides and isocyanates. 11. Toxicological information Experience on practice Slight narcotic effect. Prolonged inhalation of vapours in high concentrations may lead to headache, giddiness and nausea. 12. Ecological information Details on elimination (persistance / degradibility) In case of appropriate conduction into adapted biological purification plants no disturbances have to be expected. Additional ecological information General ecological information Do not empty into waters or drains. 13. Disposal considerations Product Recommendation In accordance with local official regulations. Waste key - 080111 Contaminated packaging Contaminated packaging must be emptied of all residues and, following appropriate cleaning, may be sent to a recycling plant. (Waste code 080112 contains no org. solvents). Uncleaned packaging must be disposed of in the same manner as the medium. (Waste code 150110) 14. Transport information Land transport ADR/RID Classification Class : 3 Kemlercode : 30 Substance number : 1263 Classification-Code : F1 Special provisions : 640E LQ 7 Proper shipping name PAINT RELATED MATERIAL Packaging Packaging group : III Label : 3 Maritime transport IMDG/GGVSea Classification IMDG-Code : 3 EmS number : F-E / S-E UN number : 1263 Marine Poll. : - LQ 5 l Page : 4 / 6
Proper shipping name PAINT RELATED MATERIAL Packaging Packaging group : III Label : 3 Air transport ICAO-TI and IATA-DGR Classification Class : 3 UN number : 1263 Proper shipping name PAINT RELATED MATERIAL Packaging Packaging group : III Label : 3 15. Regulatory information Classification according to EC directives Danger symbol and danger designation Xi ; Irritant Hazard-determining components of labelling PENTAERYTHRITOL TRIACRYLATE ; CAS-No. : 3524-68-3 PENTAERYTHRITOL TETRAACRYLATE ; CAS-No. : 4986-89-4 R-phrases 10 Flammable. 43 May cause sensitisation by skin contact. 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 36 Irritating to eyes. S-phrases 61 Avoid release to the environment. Refer to special instructions/safety data sheets. 51 Use only in well-ventilated areas. 37 Wear suitable gloves. 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 24/25 Avoid contact with skin and eyes. National regulatory information Water pollution classification Class : 2 according VwVwS 16. Other information Further information R-Phrases of components 10 Flammable. 11 Highly flammable. 22 Harmful if swallowed. 36 Irritating to eyes. 36/38 Irritating to eyes and skin. 43 May cause sensitisation by skin contact. 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Page : 5 / 6
66 Repeated exposure may cause skin dryness or cracking. 67 Vapours may cause drowsiness and dizziness. These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Page : 6 / 6