MATERIAL SAFETY DATA SHEET Product Name CAS # Product use Manufacturer LEGEND HMIS/NFPA Severe Serious Moderate Slight Minimal 4 3 2 1 1 Product and Company Identification WhirlOut Mixture Cleaner Iron Out dba Summit Brands 721 Engle Road Fort Wayne, IN 4684-5875 US Phone: 26-483-2519 Emergency Phone: 1-8-424-93 (CHEMTREC) Health Flammability Physical Hazard Personal Protection / 3 B 2 Hazards Identification 3 Emergency overview Potential short term health effects Routes of exposure Eyes Skin Inhalation Ingestion Target organs Chronic effects Signs and symptoms DANGER -- CORROSIVE Eye, Skin contact, Inhalation, Ingestion May cause chemical burns May cause blindness May cause chemical burns Harmful contact may not cause immediate pain Harmful if inhaled Dust may cause respiratory tract irritation or chemical burns Harmful if swallowed May cause chemical burns to mouth, throat and stomach Eyes Skin Respiratory system Prolonged or repeated exposure may cause chemical burns The product causes burns of eyes, skin and mucous membranes 3 Composition / Information on Ingredients Ingredient(s) CAS # Percent 497-19-8 4-7 1213-79-3 15-4 7758-29-4 15-4 First aid procedures Eye contact Skin contact Inhalation Ingestion 4 First Aid Measures Immediately flush with cool water Remove contact lenses, if applicable, and continue flushing for 15 minutes Obtain medical attention immediately Brush away excess of dry material Immediately flush with cool water for 15 minutes Obtain medical attention if irritation persists Wash contaminated clothing well before reuse or discard If symptoms develop move victim to fresh air If symptoms persist, obtain medical attention Do not induce vomiting Rinse mouth with water, then drink one or two glasses of water Obtain medical attention Never give anything by mouth if victim is unconscious, or is convulsing #15562 Page 1 of 6
General advice If you feel unwell, seek medical advice (show the label where possible) Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves Show this safety data sheet to the doctor in attendance Avoid contact with eyes and skin Keep out of reach of children 5 Fire Fighting Measures Flammable properties Not flammable by WHMIS/OSHA criteria Extinguishing media Suitable extinguishing media Treat for surrounding material Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighters Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Firefighters should wear full protective clothing including self contained breathing apparatus May include and are not limited to: Oxides of carbon Oxides of nitrogen Hydrogen chloride Oxides of phosphorus 6 Accidental Release Measures Personal precautions Methods for containment Methods for cleaning up Handling Storage Exposure limits Ingredient(s) Keep unnecessary personnel away Do not touch or walk through spilled material Do not touch damaged containers or spilled material unless wearing appropriate protective clothing Keep people away from and upwind of spill/leak Prevent entry into waterways, sewers, basements or confined areas Before attempting clean up, refer to hazard data given above Use broom or dry vacuum to collect material for proper disposal without raising dust Rinse area with water Prevent large spills from entering sewers or waterways Contact emergency services and supplier for advice 7 Handling and Storage Use good industrial hygiene practices in handling this material Do not get this material in your eyes, on your skin, or on your clothing Keep out of the reach of children Keep in a dry, cool and well-ventilated placestore in a closed container away from incompatible materials 8 Exposure Controls / Personal Protection Exposure Limits ACGIH-TLV OSHA-PEL Engineering controls ACGIH-TLV OSHA-PEL ACGIH-TLV OSHA-PEL General ventilation normally adequate #15562 Page 2 of 6
Personal protective equipment Eye / face protection Hand protection Skin and body protection Chemical splash goggles Rubber gloves Confirm with a reputable supplier first As required by employer code Respiratory protection Not normally required if good ventilation is maintained Avoid inhalation of dust Where exposure guideline levels may be exceeded, use an approved NIOSH respirator General hygiene considerations Use good industrial hygiene practices in handling this material When using do not eat or drink Wash hands before breaks and immediately after handling the product 9 Physical & Chemical Properties Appearance Color Form Odor Odor threshold Physical state ph Melting point Freezing point Boiling point Flash point Evaporation rate Flammability limits in air, lower, % by volume Flammability limits in air, upper, % by volume Vapor pressure Vapor density Specific gravity Octanol/water coefficient Auto-ignition temperature Viscosity Bulk density Percent volatile Powder White with gray specs Powder Solid 118 1% @ 2 C (Typical) None 84-94 g/ml (Typical) 1 Chemical Stability & Reactivity Information Chemical stability Conditions to avoid Incompatible materials Stable under recommended storage conditions Do not mix with anything but water Acids Oxidizers Caustics Reducing agents Hazardous decomposition products May include and are not limited to: Hydrogen chloride Oxides of nitrogen Oxides of carbon Oxides of phosphorus Possibility of hazardous reactions Hazardous polymerization does not occur 11 Toxicological Information Component analysis - LC5 Ingredient(s) LC5 4 mg/m3 guinea pig #15562 Page 3 of 6
Component analysis - Oral LD5 Ingredient(s) Effects of acute exposure Eye Skin Inhalation Ingestion Sensitization Chronic effects Carcinogenicity Mutagenicity Reproductive effects Teratogenicity LD5 49 mg/kg rat 31 mg/kg rat May cause chemical burns May cause blindness May cause chemical burns Harmful contact may not cause immediate pain Harmful if inhaled Dust may cause respiratory tract irritation or chemical burns Harmful if swallowed May cause chemical burns to mouth, throat and stomach Not classified or listed by IARC, NTP, OSHA and ACGIH Not classified or listed by IARC, NTP, OSHA and ACGIH Not classified or listed by IARC, NTP, OSHA and ACGIH Not classified or listed by IARC, NTP, OSHA and ACGIH Not classified or listed by IARC, NTP, OSHA and ACGIH Not classified or listed by IARC, NTP, OSHA and ACGIH 12 Ecological Information Ecotoxicity Components of this product have been identified as having potential environmental concerns Ecotoxicity - Freshwater Algae Data 497-19-8 12 Hr EC5 Nitzschia: 242 mg/l Ecotoxicity - Freshwater Fish Species Data 497-19-8 96 Hr LC5 Lepomis macrochirus: 3 mg/l [static] Ecotoxicity - Water Flea Data 497-19-8 48 Hr EC5 Daphnia magna: 265 mg/l Environmental effects Harmful to aquatic life Aquatic toxicity Persistence / degradability Bioaccumulation / accumulation Partition coefficient Mobility in environmental media Chemical fate information Other adverse effects 13 Disposal Considerations Waste codes Disposal instructions Waste from residues / unused products Contaminated packaging Review federal, provincial, and local government requirements prior to disposal #15562 Page 4 of 6
14 Transport Information US Department of Transportation (DOT) Basic shipping requirements: Proper shipping name Corrosive solid, basic, inorganic, nos (SODIUM METASILICATE PENTAHYDRATE) Hazard class UN number Packing group Additional information: Special provisions Packaging exceptions ERG number 8 UN3262 III IB8, IP3, T1, TP33 154 154 Transportation of Dangerous Goods (TDG - Canada) Basic shipping requirements: Proper shipping name Corrosive solid, basic, inorganic, nos (SODIUM METASILICATE PENTAHYDRATE) Hazard class UN number Packing group Additional information: Special provisions 8 UN3262 III 16 15 Regulatory Information Canadian federal regulations This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations Canada - WHMIS - Ingredient Disclosure List 497-19-8 1 % US Federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 19112 Occupational Safety and Health Administration (OSHA) 29 CFR 19112 hazardous Yes chemical CERCLA (Superfund) reportable quantity : 5 Copper: 5 Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Section 32 extremely No hazardous substance Section 311 hazardous chemical Yes Clean Air Act (CAA) Clean Water Act (CWA) Safe Drinking Water Act (SDWA) Drug Enforcement Agency (DEA) #15562 Page 5 of 6
Food and Drug Administration (FDA) WHMIS status WHMIS classification WHMIS labeling Controlled Class E - Corrosive Material State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm Inventory name Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) No United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) Disclaimer Effective date Expiry date 16 Other Information Information contained herein was obtained from sources considered technically accurate and reliable While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document 1-Dec-28 1-Dec-211 Prepared by Dell Tech Laboratories Ltd (519) 858-521 #15562 Page 6 of 6