CCS IN MEXICO AND ASSOCIATED COSTS. Rodolfo Lacy Mario Molina Center

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CCS IN MEXICO AND ASSOCIATED COSTS Rodolfo Lacy Mario Molina Center IEA-SENER Joint Workshop CCS in Mexico: Policy Strategy Options for CCS March 2012

National Energy Strategy 5% Renewables (Biomass, Solar, Geothermal, eolic) 2010 25% Natural Gas 2% Clean (Nuclear and Hydro) 2% Coal 65% Oil by 2026 fossil fuels will account for almost 65% *Estrategia Nacional de Energía, 2012

IEA workshop Demonstrative Project CCS+EOR status CSLF workshop Energy National Strategy presentation National Strategy for CCUS Mexican Atlas for Geological Storage EOR/EGR incorporation Demonstration Project 2012 FEB MAR JUN AUG OCT 2013 2014 2015-2019 COST STUDY, World Bank (1.2 MUSDlls) Basic Engineering, IIE (325 mil USDlls) PILOT PLANT CONSTRUCTION AND OPERATION Announcement Sustentability Fund CONTRACT consortium Integral Project (Pilot Plant+EOR)

Integral Project Pilot Plant + EOR As part of the National Energy Strategy, a CCS+EOR demonstration project is being considered in order to reduce emissions from CFE power plants and use that for EOR operations within PEMEX fields. The CCS Mexican Group* decided to pursue the design and construction of a Pilot Plant for capturing emissions. The plant will added to a CFE Power Plant in Poza Rica, Veracruz, in the Gulf of Mexico region**. The Integral Project will also include the transportation of to near production sites where PEMEX will use for EOR activities. 2 MW Pilot Plant Charleston, West Virginia, USA * Members: PEMEX, CFE, Ministry of Energy, Electrical Research Institute, Mexican Petroleum, Institute, Mario Molina Center, among others **The experience and experience obtained from the Pilot Plant will be an important source of information for the design of a large scale capture system for the demonstration project.

CCS+EOR Proposal It is planned that the first carbon capture project that will take place in Mexico must be a CCS+EOR form. This strategy will enable Mexico to start utilizing this low-carbon emission technology One of the main factors that support such a project is that the CFE, PEMEX, and geological reservoirs are stateown enterprises and assets *CCS+EOR. Carbon Capture and Storage + Enhance Oil Recovery

Sources in Mexico 2009 *Modificar mapa Río Escondido Carbón II Altamira Manzanillo Tula Tuxpan Poza Rica Dos Bocas Petacalco PETACALCO

Sources in Mexico Projections to 2025 PETACALCO

emission sources emission sources (>500,000 ton/year) in Veracruz state Company Name Sector Town eq (2008) eq (projection to 2025) CFE Central Termoeléctrica Adolfo López Mateos Energy Generation Tuxpan 4,364,184 4,318,360 Fuerza y Energía de Tuxpan S.A: de C.V. Energy Generation Tuxpan 2,662,755 2,634,796 PEMEX Complejo Petroquímico Morelos Oil and Petrochemical Industry Coatzacoalcos 1,792,074.0 2,240,093 PEMEX Complejo Petroquímico Cosoleacaque Oil and Petrochemical Industry Cosoleacaque 1,714,444.6 2,143,056 PEMEX Refinería Lázaro Cárdenas Oil and Petrochemical Industry Minatitlán 1,540,040 1,955,851 Central Ciclo Combinado, Dos Bocas Energy Generation Medellín 1,287,484 1,314,650 Central Turbo Gas, Adolfo López Mateos Energy Generation Tuxpan 1,479,082 1,463,552 Electricidad Águila de Tuxpan S. de R.L. de C.V. Energy Generation Tuxpan 1,388,296 1,417,589 Cementos Apasco S.A. de C.V. Cement Production Industry Ixtaczoquitlan 974,048 1,051,113 CFE Central Termoeléctrica Poza Rica Energy Generation Tihuatlan 227,212 573,048* * Taking into account the planned power increment, refitted to natural gas, and an increment in the capacity factor Company Name Sector Town PEMEX Gas y Petroquímica Básica. Complejo Procesador de Gas Nuevo PEMEX PEMEX Exploración y Producción. Estación de Complejo Procesador de Gas Ciudad PEMEX Cementos Apasco S.A. de C.V. Planta Macuspana emission sources (>500,000 ton/year) in Tabasco state eq (2008) eq (projection to 2025) Oil and Petrochemical Industry Centro 2,140,544 2,782,707 Oil and Petrochemical Industry Macuspana 1,091,740 1,419,262 Cement Production Industry Macuspana 567,342 612,228

Estimated Costs Centro Mario Molina evaluated in 2009 different alternatives for power generation plant with petroleum coke and carbon, combined with EOR in Mexico. It was concluded that fluidized bed boiler was the best economic option COSTS OF CCS + EOR* OPERATIONS IN MEXICO (USD/MWh) Power generation leveled cost Transport/Compression leveled cost IGCC 150 MW TECHNOLOGY OPTIONS IGCC 300 MW PCSC 300 MW FLUIDIZED BED 300 MW 155.73 16.41 NGCC 250 MW Injection/Storage leveled cost Total leveled cost EOR Total leveled cost with EOR value (externalities) ** Total leveled cost with EOR and externalities 0.24 172.38 111 61.38 13.36 48.02 *CCS. Carbon Capture and Storage EOR. Enhanced Oil Recovery with a $60 USD price per barrel. Obtaining 2.5 barrels per ton of injected **Calculated according to the externalities methodology adopted by the Mexican Ministry of Energy in 2009 SOURCE: CMM, 2009. Proyecto Demostrativo para Generar Energía Eléctrica a partir de Combustibles Fósiles libre de Emisiones de Gases de Efecto Invernadero.

Particles (mg/nm 3 ) TUXPAN AIR EMISSIONS Levels of contaminant emissions expected from one unit at the power generation plant in Tuxpan WITH and WITHOUT capture system* NOM-085 for NOx (110 ppm v ) No capture Capture NOM-085 for SOx (550 ppm v ) NOM-085 for particles (250 mg/m 3 ) *The capture system requires an influent with NOx and SOx concentrations within the 10-20 ppm range

CCS + EOR First Approach: Tuxpan Power Plant General operation diagram* Conversion Generation levelized cost - 155.73 USdlls/MWh EOR/EGR FUEL SWITCHING TO COAL 300 MW Boiler fluidized bed NOM-085 Particles 10 PPM NOx & SOx capture Clean air Net Benefit 48.02 USdlls/MWh 93 USdlls/MWh con carbón 73 USdlls/MWh con petcoke Oil sells +111 USdlls/MWh Externalities COAL Boiler fluidized bed Gases cleaner Transport + Injection - 16.65 USdlls/MWh Compressor * Recovered- separation and reinjection +13.36 USdlls/MWh Limestone Particles NOx SOx Amine tower separator Bottom ashes Separación * Separation for para recovered re-inyección reinjection 0.5 Usdlls/1,000 0.5 Usdlls/1,000 ft 3 de CO ft3 2 recuperado * Esimated costs by Centro Mario Molina (being corroborated by PEMEX and IIE)

USD Millions Capture Costs Equivalent anual cost for the capture process (using amine) for one unit within the Tuxpan CFE facilities using 100% carbon fuel GENERATION UNIT Capture trains USD USD/year USD/year USD/year t/year t/year Inversion at Present value 2011 O & M Fuel Compression captured Avoided Fluidized Bed 7 44,042,710 15,811,018 18,756,075 30,920,647 2,159,456 1,598,674 SUBCRITICAL Pulverized Carbon SUPERCRITICAL Pulverized Carbon 7 64,149,578 15,537,853 18,165,633 34,232,079 2,143,655 1,599,301 6 47,828,111 14,249,157 16,801,261 30,313,648 1,957,405 1,453,836 Net Present Value In this option, PEMEX would acquire the captured. A sensibility analysis was also carried out to evaluate recovery cost for ton thus the investment on capture system and its operation will not result in economic losses X X X Selling price for (USD/ton) Subcritical FB PC Subcritical PC Supercritical

EOR sites in the Chicontepec Region The initial proposal was to run the demonstration project in the Tuxpan Power Plant that would be refitted to use coal as their primary source. However, due to CFE strategic decisions, it was decided to have the CCS project in the NGCC Power Plant located at Poza Rica. The first stage is the implementation of the Pilot Plant where the first arrangements for EOR will be implemented. CFE TUXPAN Fuel oil power plant NGCC Private power plant Oil sites located at Chicontepec Region that might be suitable for EOR operations

Power Plant and well sites at Poza Rica The Pilot Plant will capture up to 8 ton of per day. Well site at Poza Rica PEMEX has several well sites located at Poza Rica that are relatively close to the Power Plant facilitating the transport of the. Power Plant Localization of the Poza Rica Power Plant and well sites suitable for the injection of

Demonstration Project General scheme for the CCS+EOR demonstration project between CFE and PEMEX Source: Mario Molina Center

Levelized Costs CCS+EOR Levelized Costs Generation (including gas cleaning and capture) NGCC Power Plant 250 MW (Usdlls/MWh) 113.12 Compression and pumping 5.00 Transport* 0.80 Injection and Storage 0.30 Total levelized cost 119.22 Oil benefits -44.38 Total levelized cost including EOR** 74.84 Monetary value of avoided *** -5.38 Total levelized costs (including environmental externalities and EOR) * Basd on a 30 km distance from the injection point. ** Calculated with the selling of a 60 USD barrel, recovering 2.5 barrels per each ton injected, without considering the natural gas natural obtained simultaneously from the well. *** Calculated based on the SENER environmental externalities methodology used in 2009. 69.14 Source: Centro Mario Molina, preliminary estimations

PILOT PLANT Integral Operative System Amine providers 2 opertors Electrical Research Institute CFE Combustion gases equivalent to a 2MW plant Electricity Vapor NGCC Poza Rica Cooling water Solid and liquid residuals Laboratory PEMEX CMM Aditional PEMEX Exploration Mexican Petroleum Institute

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