Predicting Injectivity Decline in Water Injection Wells by Upscaling On-Site Core Flood Data

Similar documents
An experimental study of permeability determination in the lab

SPE DISTINGUISHED LECTURER SERIES is funded principally through a grant of the SPE FOUNDATION

The Integral Optimization Method of Oilfield Production System

FTSI Fracture Fluids 101

Reservoir Engineering

Analysis Fraction Flow of Water versus Cumulative Oil Recoveries Using Buckley Leverett Method

Sanitary and Environmental Engineering I (4 th Year Civil)

CONCENTRATE AND BRINE MANAGEMENT THROUGH DEEP WELL INJECTION. Abstract

Core Analysis of the Round Tank Queen Reservoir, Chaves County, New Mexico. By: Garrett Wilson

WATER RECYCLING PLANT IN WAFRA. Feras Al Salem

INVESTIGATION ON SURFACE AND SUBSURFACE FLUID MIGRATION: ENVIRONMENTAL IMPACT

Moving from Secondary to Tertiary Recovery Stages. 9 TH ANNUAL WYOMING EORCO2 CONFERENCE JULY 14-16, 2015 Casper, WY By Jim Mack MTech Ventures LLC

SPE Distinguished Lecturer Program

DEEPA TM Stimulation of Natural Fracture Networks in Austin Chalk

A Method for Stimulation Candidate Well Selection

Providing clear solutions with innovative design

Petroleum Production Optimization

Study on the Workover Fluid Formula and Performance of the Prevention Reservoir

Successful Completion Optimization of the Eagle Ford Shale

RESERVOIR SIMULATION STUDIES OF FORMATION DAMAGE FOR IMPROVED RECOVERY ON OIL-GAS RESERVOIRS

MODIFICATIONS TO KOZENY-CARMAN MODEL To ENHANCE PETROPHYSICAL RELATIONSHIPS

Reclamation of Sand Filter Backwash Effluent using HYDRAcap LD Capillary UF Membrane Technology

The SPE Foundation through member donations and a contribution from Offshore Europe

Down Hole Flow Assurance

Appraising the Performance of Cyclic Production Scheme through Reservoir Simulation, a Case Study Tariq Al-Zahrani, Saudi Aramco

Enhanced Oil Recovery Institute IOR/EOR Conference Jackson, Wyoming September 10 & 11, 2012

The Effect of Different Carbon Dioxide Injection Modes on Oil Recovery

The Impact Wear Behavior of Large Rocks on Slurry Pump Materials and Equipment.

SINTERED WIRE MESH.

Desalination Concentrate Disposal Using Injection Wells: Technical Challenges

NGWA s Water Well Construction Standard: ANSI/NGWA 01-14

Steam Injection. Dr. Helmy Sayyouh Petroleum Engineering Cairo University

Subsurface Distribution of ZVI/EHC Slurry Validating Radius of Influence. Josephine Molin, PeroxyChem October

Gilflo flowmeters. for steam, liquids and gases

Soil & Nutrient Losses from Small Sprinkler & Furrow Irrigated Watersheds in Southern Idaho

Microbial Solutions Treat Frac Water

Understanding the Behaviors of Gas Condensate Reservoirs

Injection Wells for Liquid-Waste Disposal. Long-term reliability and environmental protection

Microbial Fluid-Rock Interactions in Chalk Samples and Salinity Factor in Divalent Ca 2+ ions Release for Microbial Enhanced Oil Recovery Purposes

AD26 Systems for Iron, Manganese, Sulfide and Arsenic Removal

OIL TECHNOLOGY PORTFOLIO

SPE Copyright 2008, Society of Petroleum Engineers

Permeability, Flow Rate, and Hydraulic Conductivity Determination for Variant Pressures and Grain Size Distributions

CORE ANALYSIS REPORT Conventional Core. Vecta Oil & Gas, Ltd.

Application of the Power Law Loss-Ratio Method of Decline Analysis

The Use of Walnut Shell Filtration with Enhanced Synthetic Media for the Reduction and/or Elimination of Upstream Produced Water Treatment Equipment

THINK. Filter Technology SIKA-B

INDUSTRIAL FILTRATION EQUIPMENT LWS Filter Series

MARPAK modular biomedia WASTEWATER TREATMENT

Technical Service Bulletin October 2013 TSB

Operating Conditions Optimization of Steam Injection in Enhanced Oil Recovery Using Duelist Algorithm

SPE Copyright 2012, Society of Petroleum Engineers

Hybrid RO & Softening Birjand Water Treatment Plant

Chem 321 Lecture 23 - Liquid Chromatography 11/19/13

Fracking Safety & Economics November 9, 2017 America 1 st Energy Conference, Houston Tx.

CARBONATE STIMULATION

American Water College 2010

DISPERSIVE SOILS. Dispersive soils are those in which the clay content has a high percentage of sodium.

Sand control case histories: Shape memory polymers, resins, shunt tubes

Evaluation of Conventional Activated Sludge Compared to Membrane Bioreactors

Aeration for Produced Water Management

AN EXPERIMENTAL STUDY OF THE OPTIMAL THICKNESS OF A SAND LAYER IN A SAND FILTER WATER QUALITY STRUCTURE. July 1994

Introduction to TFF. Sengyong Lee Ph.D. Professor/ Program Chair Biotechnology/ Biology Ivy Tech Community College Bloomington, Indiana

8 th Annual Wyoming CO 2 Conference

Advanced Enviro-Septic TM Basic Design and Installation Manual

Advancing the Science of In Situ Groundwater Remediation Petroleum Hydrocarbon Remediation Technologies

Dynamic Imaging Principle OIW/WIO Analysis

Removal of Algae and Cyanobacterial Toxins during Slow Sand and Bank Filtration

6 DRILLING AND COMPLETIONS

Standardization of the Evaluation Criteria on Petroleum Resources

A Hybrid Constructed Wetland System for Decentralized Wastewater Treatment

Borehole NMR: Different Problems Different Solutions

Utilization of shredded waste car tyres as a fracture seal material (FSM) in oil and gas drilling operations

Advances in media filtration. Leveraging advanced filtration media with a high oil loading capacity to improve water treatment

Carbon Dioxide Capture and Storage in Deep Geological Formations. Carbon Dioxide Capture and Geologic Storage

Bioreactor System ERT 314. Sidang /2011

Amending soils for improved hydraulic and edaphic properties. Todd A. Houser, MS, CPSS, CPESC DiGeronimo Aggregates LLC

Microfil GP. Range. Validation Guide. World Class Filtration Solutions

Technological Enhancement of PC Pumps for Heavy Oil Production. Courtney Ward P.Eng.

Wellhead & Wellstream Desanding Solutions for Offshore Production in Malaysia

Application of the Frontal Advance Equation to a linear system during MEOR

WATER TREATMENT PLANT BASED ON REVERSE OSMOSIS TECHNOLOGY litres Per Hour

POROSITY, SPECIFIC YIELD & SPECIFIC RETENTION. Physical properties of

Murphy Oil Company LTD.

Saint-Gobain Ceramic Materials

SPE Introduction. Objectives. There are three primary objectives of this new pumping method:

Water Based Critical Utilities. RO, WFI, and Steam

Cross Borehole Electrical Resistivity Tomography (ERT) Measurements

Reverse Osmosis Desalinators

Desalination Intake Approaches: Open Ocean Intake vs Subsurface. Monterey Bay Water Works Association

COPPER PRECIPITATION AND CYANIDE RECOVERY PILOT TESTING FOR THE NEWMONT YANACOCHA PROJECT

The Mechanism of Improved Oil Recovery by Sequential Waterflooding

EVALUATION OF WATER AND GAS INJECTION IN A CARBONATE RESERVOIR

Gaps and Challenges for Light and Tight EOR

Technology for. Unconsolidated

INJEÇÃO DE CO 2 PARA PRODUÇÃO ACRESCIDA DE METANO DE CARVÃO EM CAMADA CO 2 INJECTION FOR ENHANCED COALBED METHANE (ECBM)

MEASUREMENTS OF REMAINING OIL SATURATION IN MIXED-WET CARBONATES

0.01 Micron Membrane Filters

An Empirical Correlation for Two-Phase Inflow Performance Relationship in Horizontal Oil Wells

Construction. Injectable Hose for Sealing Construction Joints in Watertight Structures. Product Description. Tests. Product Data

Transcription:

Predicting Injectivity Decline in Water Injection Wells by Upscaling On-Site Core Flood Data Paul Evans Oil Plus Ltd. Hambridge Road, Newbury Berkshire, RG14 5SS, England Fax: +44 (0) 1635 49618 E-mail: p.evans@oilplus.co.uk Sidqi Abu-Khamsin King Fahd University of Petroleum & Minerals Box 652 Dhahran 31261, Saudi Arabia Fax: +966 (0) 3 8604447 E-mail: skhamsin@kfupm.edu.sa Peter F. Sanders Research & Development Center Saudi Arabian Oil Company P.O. Box 62, Dhahran Saudi Arabia, 31311 Fax: +966 (0) 3 8762804 E-mail: peter.sanders@aramco.com Abdulhadi Al-Amer Southern Area Producing Engineering Department Saudi Arabian Oil Company P.O. Box 4950, Udhailiyah 31311 Saudi Arabia Fax: +966 (0) 3 5777048 E-mail: abdulhadi.amer@aramco.com ABSTRACT Particles suspended in water used for injection into hydrocarbon reservoirs for secondary oil recovery can result in blockage of the reservoir rock pore throats, resulting in injectivity decline of injection wells. Particles such as biomass, corrosion products, silt and scale can be present, even in the most highly treated water injection systems. On-site coreflooding is a well accepted method to directly measure the plugging effects of live system water on reservoir rocks and set a realistic water quality specification to minimize formation damage. A major on-site core flooding study was undertaken on a large and complex seawater injection system in Saudi Arabia. Water from the Arabian Gulf is treated by filtration and deaeration before distribution through a long, complex, network of flowlines, some of which are bare carbon steel and some fusion - OGP 04 (1) -

bonded epoxy lined. This results in different particle types in different areas of the system, particularly with respect to bacteria and iron. Further, the water is injected into different areas of the field, with permeabilities ranging from <10 md to >1000 md. Data from the on-site coreflooding were combined with subsequent laboratory analysis of the particles and core plugs to determine the effects of the different water qualities on permeability. These data were then processed, upscaled to model injection wells and, finally, history matched to long term injectivity records. This enabled a matrix of water quality specifications to be derived for each area of the field, to give projected improvements in injection well half-lives ranging from 50% to 100%. 1. INTRODUCTION A major on-site core flooding study was undertaken on a large and complex seawater injection system in Saudi Arabia to determine appropriate injection water quality specifications with repect to particle loading and Total Suspended Solids. The system was described by Al-Wehaimid et al. (1994), although it has expanded significantly since then, with water now being injected into areas much further south. Water from the Arabian Gulf is treated by filtration and deaeration before distribution through a long, complex, network of flowlines, some of which are bare carbon steel and some fusion bonded epoxy lined. Filtration is accomplished with sand filters, and deaeration is by nitrogen-stripping, plus oxygen scavenging by sulfur dioxide. Organic biocides are regularly dosed at the outlet of the seawater treatment plant. In order to determine the appropriate water quality specification for the injection water in the various regions of the field, on-site coreflooding was undertaken using actual core plugs taken from the reservoir and the actual injection water at various locations in the system. Variations in pipeline materials result in differences in the nature of the suspended solids in different parts of the system, particularly in the amount of biomass and iron solids. The water quality tests, which were conducted along with the corefloods, cannot be definitely interpreted as indicating that there are deteriorations in quality along the flowlines since the tests were conducted consecutively and not simultaneously over a 6 week period. However, it is reasonable to infer that some deterioration did occur and also that there were periodically substantial upsets in water quality, with peaks of very poor quality (but of unknown duration and frequency). The suspended solids identified in the injection water were predominantly iron oxides and sulfides, clay particles and quartz grains, with lesser amounts of plankton particles and probable biomass. Reservoir quality decreases from north to south across the field. Consequently, it was anticipated that the water quality specification would be tighter in the south of the field, compared to the northern areas. The degree of natural fracturing in the carbonate reservoir also has an impact on the water quality specification for individual wells. Within the field there is a mix of horizontal and vertical injection wells: the larger injection surface area of a horizontal well, compared to a vertical well, results in a smaller impact of water quality on injectivity. Therefore, it may also be anticipated that a tighter water quality specification would be required for a vertical well, compared to a horizontal well. 2. ON-SITE COREFLOODING - OGP 04 (2) -

The objective of the on-site coreflooding was to investigate the effects of potential injection waters on reservoir rock matrix permeability by passing water through core plugs prepared from reservoir material and recording the changes in measured permeability. The coreflooding was carried out at several points throughout the seawater injection system. The study began at the Seawater Treatment Plant, proceeded to the Water Supply Station, followed by Water Injection Pumping Stations and, finally, injection wellheads. On-site coreflooding was carried out on a total of 56 core plugs at 9 different locations. Three core plugs (high, medium and low permeability) were flooded simultaneously in the on-site coreflooding rig (see Figure 1). The coreflooding was carried out in a mobile laboratory that was moved between the sampling locations. A coreflooding rig was connected directly to the water pipelines via suitable sample points and the water was flooded through the plugs as a side stream from the pipeline. This prevents the degradation of the water, for instance due to the oxidation of dissolved iron, which would occur during storage of water samples. The plugs were flooded at relatively high flow rates and very large volumes of water were flooded through the plugs. In the case of the high permeability plugs, up to 150 litres (~17,000 pore volumes) of water was flooded through an individual plug over the 2 days duration of the coreflood. The on-site coreflooding study was carried out continuously over a period of 6 weeks. By varying the degree of filtration (using cartridge filters in the coreflooding rig) throughout the duration of the coreflood, and analysing the changes in water quality across the plugs, the causes of any permeability changes which occur during the flooding tests may be deduced. Each individual plug was flooded with up to four different water qualities (ultra filtered, fine filtered, coarse filtered and unfiltered) with respect to the water quality in the pipeline. The coreflooding methodology is based on the technique set out in the standard method ASTM D 4520-95. In the following sections, the water grade values are related to degree of water filtration as follows: Water Grade Degree of Water Filtration Filtration Grade 1 Ultra filtered 1 µm 2 Fine filtered 3 µm 3 Coarse filtered 10/20 µm 4 Unfiltered, with respect to the water quality in the pipeline None Core plugs from three areas of the field (southern, central and northern) were flooded with water from the various sampling locations in order to investigate the impact of the varying water quality on plug permeability. A baseline permeability decline was established by flooding a full set of core plugs at the outlet of the Seawater Treatment Plant. Subsequently, additional sets of core plugs were flooded with water from further downstream in the injection system to assess how evolving water quality affects plug permeability. Core plugs were prepared from reservoir core material and were generally grainstone carbonate rocks, mostly pelletoid with some skeletal foraminifera and elongated bioclasts. An example core flooding profile is presented in Figure 2 (medium permeability from center of field), in which it can be clearly seen that the rate of permeability decline is determined by water quality. The flooding water quality in this particular case was as follows: - OGP 04 (3) -

Water Grade Number of particles 2 µm diameter in 0.5 ml Total Suspended Solids (mg/l) 1 130 0.03 2 294 0.07 3 333 0.10 4 607 0.16 The water quality of the injection water was generally good, and the additional filtration by the filter cartridges in the on-site coreflooding rig, resulted in some very clean water qualities. The particle size distribution of the water samples was measured using a Coulter Z1 particle counter, manufactured by Beckman Coulter Limited. The total suspended solids (TSS) concentration of the flooding waters was determined using standard membrane filtration techniques (NACE Standard TM0173-99). Due to the very low suspended solids content of the flooding waters, it was necessary to filter 20 litres of water in order to obtain an accurate measurement. However, even with the very low solids content of the injection water, the permeability of the core plugs declined and the rate of permeability decline was dependent on the measured water quality. The differences in rate of permeability decline with different water qualities can be clearly seen if the initial permeability at each coreflood stage is normalized. Figure 3 presents an example of the normalized permeability plot, demonstrating increasing rate of permeability decline with decreasing water quality (normalized data from Figure 2). 3.1. Treatment of Coreflood Data 3. SCALING UP OF COREFLOOD RESULTS Perkins and Gonzalez (1985) provide a methodology for scaling up coreflood results to determine the pressure increase across a skin due to poor water quality and this methodology was used in this study. The pressure increase across the skin damage is given by the following equation: i µ R w w s Ps = (1) A f Where: P s = pressure increase as the result of skin damage due to poor water quality (psi) i w = water injection rate, bwpd µ w = water viscosity, cp R s = resistance to flow caused by skin damage, ft/md A f = Area over which solids from injection water are deposited, sq ft. The area calculation may take into account the perforation details of a perforated injection interval. Of these factors, both i w and µ w are known for a particular injection well, while A f can be calculated as the surface area of the open-hole or perforated section of the borehole. Only R s is unknown, however this can be calculated from coreflooding data in the following manner. - OGP 04 (4) -

The total pressure drop across the core can be considered to be the sum of the pressure drop across the initial core plug, plus the pressure drop across the filter cake formed at the upstream face of the core plug by filtration of suspended solids from the injection water. This relationship is summarised in the following equation: i µ L i µ R w w c w w s Pc = + (2) ka c A c Where: P c = L c = A c = Surface area of core face (ft 2 ) k = Core permeability (md) Pressure drop across length of core (psi) Length of core (ft) For a fixed water quality, growth of the pressure drop across the skin damage is directly proportional to the volume of water injected, and the concentration of total solids introduced at the upstream face of the core. It is also inversely proportional to the core area. Thus, R s, as determined from the laboratory measurements, can be correlated vs. W i /A c, where W i represents the cumulative volume of water. The additional flow resistance caused by solids loading increases as additional water is injected. This relationship can be represented by the following linear expression: λwi R s = (3) A Where: λ = Water quality coefficient (md -1 ) Figure 4 presents an example of the calculation of water quality coefficients using the coreflood data presented in Figures 2 and 3. In Figure 4, the R s values (calculated using equation 2) are plotted against W i and the gradient of the fitted line through this cross-plot is the water quality coefficient (λ in A equation 3). As the water quality becomes worse and the rate of plug permeability decline increases, the value of the water quality coefficient increases. A water quality coefficient (λ) was calculated for each stage of each coreflood, except for grade 1 water. During grade 1 waterflooding the permeability varies due to factors unrelated to water quality such as the movement of fines within the plug and, therefore, it is not appropriate to use this data to make predictions of the effect of water quality on well injectivity. Therefore, grade 2 was the best water quality and grade 4 was the worst water quality used in the modelling. Variations in the unfiltered water quality from location to location results in variations in the quality of the water at the different filtration grades. Thus, water quality coefficients were calculated for each grade of filtration at every location. - OGP 04 (5) -

The water quality coefficients are strongly dependent on permeability, and when the water quality coefficients are plotted against maximum permeability to water, a strong negative correlation can be observed. Essentially, the lower permeability core plugs block at a higher rate than the high permeability core plugs. Therefore, the low permeability core plugs have high water quality coefficients compared to high permeability plugs, for a given water quality and coreflood location. An example of this is given in Figure 5, in which all of the coreflood data from one particular location is plotted. For a given permeability value, the water quality coefficient values increase, as water quality decreases. 3.2. Well Performance Modelling The water quality coefficients determined from the on-site coreflooding were used in a matrix well performance model in order to predict the impact of various water qualities on the rate of injectivity decline. The modelled rates were matched to historical well injectivity declines, using the water quality coefficients for the unfiltered water from the relevant injection wellhead location. The match was achieved by varying the effective diameter of the injection zone. The naturally fractured nature of the reservoir carbonates means that the effective surface area for injection is greater than the cylindrical surface area of the well bore. The surface area was increased to correspond to fracture half-lengths of between 2 and 12 ft. There is a general positive correlation between the fracture lengths used in the model, and effective well-test permeability. This relationship helps to validate the use of variable length fractures in the model, because the increasing well-test permeability reflects more extensive fracturing within the injection zone. However, it should be noted that a similar history match could also be obtained with less extensive fractures and better wellhead water quality. The extent of fracturing in the injection zone controls the surface area over which the water is being injected. Surface area is one of the critical factors (together with water quality coefficient and injection rate) that control the development of the skin from the suspended solids in the injection water. Once a match was achieved to the historical data for the actual injection water quality, the impacts of different water qualities on well injectivity decline were assessed by using different water quality coefficients (see example in Figure 6 for a well at which wellhead corefloods were conducted). In this way it was possible to build up relationships between water quality and well half-life for the various regions of the reservoir areas (north, central and southern) and for vertical and horizontal wells. The well half-life is defined as the time taken for the injectivity of a well to decrease by one half. 4. RESULTS The following table gives the recommended water quality specification determined for six typical wells across the field. The water quality specification has been set using criteria of 50%, 75% and 100% increases in well half-life compared to current well performance. Well Location South Center North - OGP 04 (6) -

Well Orientation Horizontal Vertical Horizontal Vertical Horizontal Vertical Number of particles 50% 2 µm diameter in 246 338 410 511 711 630 increase in 0.5 ml Well-Half Life Total Suspended 0.07 0.08 0.09 0.14 0.11 0.10 Solids (mg/l) 75% increase in Well-Half Life 100% increase in Well-Half Life Number of particles 2 µm diameter in 0.5 ml Total Suspended Solids (mg/l) Number of particles 2 µm diameter in 0.5 ml Total Suspended Solids (mg/l) 239 253 362 463 704 582 0.07 0.07 0.09 0.13 0.11 0.10 232 231 314 415 697 534 0.07 0.07 0.08 0.12 0.10 0.10 The water quality specifications were determined by interpolating between the well half-life and water quality values for water grades 2, 3 and 4 for each well and well head core flooding location. This interpolation allows the determination of the water quality corresponding to a 50%, 75% and 100% increase in well half-life compared to the historical well half-life value. The water quality specification becomes tighter towards the southern end of the field, reflecting the general decrease in reservoir quality in the south. In addition, the water quality specifications are generally tighter for the vertical wells compared to the horizontal wells in a particular area, reflecting the greater detrimental impact of poor water quality on the shorter injection intervals of vertical wells. The specification in a particular well is also related to the degree of natural fracturing. Overall, the injection water quality specifications derived from this study are generally less stringent (in terms of number of particles 2 µm in 0.5 ml) than the existing specification of a maximum of 200 particles > 2 µm in 0.5 ml, albeit the latter is currently interpreted as that set for treated water leaving the Water Treatment Plant, not that arriving at the injection wells. However, the TSS specifications determined during this study are approximately 50% of the initial specification value of a maximum of 0.2 mg/l. In the northern area the specification can be relaxed (in terms of number of particles 2 µm in 0.5 ml), but in the poorer reservoir quality areas of the central and southern areas, the original water quality specification still largely applies. 5. CONCLUSIONS Well performance modelling, incorporating data from on-site coreflooding, was able to match to the historical injection rates of various wells. The matching parameter used was the extent of natural fracturing in the vicinity of the injection well, reflected in the effective well-test permeability. The well performance models enable the prediction of well-half life for various water qualities, which in turn can be used to predict the water qualities corresponding to 50%, 75% and 100% increases in well half-life. New injection water quality specifications have been determined from on-site coreflood tests. Although these are not very different numerically from the current ones, it is clear that these should be applicable at the injection wells (ideally bottomhole) and not only in water produced at the Water Treatment Plant. - OGP 04 (7) -

Improving the water quality to meet the specification set out in the results table will have significant benefits for the field operator. An increase in the well half-life will reduce the frequency of well workovers (thus reducing costs), but will also increase the total amount of water injected into an injection well in a given time period. The net increase in well injection rate associated with better water quality should result in higher reservoir pressures, and possibly an increase in oil productivity. It is important to inject water at the correct rate, and in the required time period in order for reservoir performance forecasts to be accurate and to meet long-term production targets and to optimize overall oil recovery. ACKNOWLEDGEMENTS The authors thank the many field and management personnel from Southern Area Producing Engineering Department, Saudi Aramco, for their support, help and encouragement during the field work and subsequent data analysis. - OGP 04 (8) -

REFERENCES [1.] Al-Wehaimid, A.A, Ahmed, T., Al-Ibrahim, T.M., Chen, R.B. and Rosser, H.R., 1994. Incorporation of system demand in the criteria for optimization of Saudi Aramco's seawater injection system bactericide treatment program. In: Proceedings of 2nd International Conference on Chemistry in Industry, Manama, Bahrain, October 1994. Pub. American Society of Chemistry. Paper O-25: 225-234. [2.] ASTM D 4520-95, Re-approved 1999: Standard Practice for Determining Water Injectivity Through the Use of On-Site Floods. [3.] NACE Standard TM0173-99, Revised 1999: Methods for Determining Quality of Subsurface Injection Water Using Membrane Filters. [4.] Perkins, T. K. & Gonzalez, J.A., 1985: The Effect of Thermoelastic Stresses on Injection Well Fracturing. SPE 11332. - OGP 04 (9) -

Figure 1 Schematic of On-Site Coreflooding Rig Pipeline Filter Skid Core Holder Skid Sample Point Sample Point 10 µm 3 µm 1 µm Core Plugs Cartridge Filters Sample Points / Volumetrics Outside Mobile Laboratory Inside Mobile Laboratory - OGP 04 (10) -

100 Figure 2 Example Coreflood Profile 90 Percentage of Maximum Permeability 80 70 60 50 40 30 20 Grade 1 Water Grade 2 Water Grade 3 Water Grade 4 Water 10 0 0 2000 4000 6000 8000 10000 12000 14000 Pore Volumes Passed - OGP 04 (11) -

100 Figure 3 Example of Normalised Coreflood Data 90 Normalised Percentage Permeability 80 70 60 50 40 30 20 Grade 2 Water Quality Grade 3 Water Quality Grade 4 Water Quality 10 0 0 500 1000 1500 2000 2500 3000 3500 4000 4500 Pore Volumes - OGP 04 (12) -

Figure 4 Example of Derivation of Water Quality Coefficients 0.0009 0.0008 0.0007 0.0006 Grade 2 Water Quality Grade 3 Water Quality Grade 4 Water Quality y = 8.83E-06x R 2 = 0.9752 Rs (ft/md) 0.0005 0.0004 0.0003 0.0002 0.0001 0.0000 y = 1.25E-06x R 2 = 0.9386 y = 5.67E-07x R 2 = 0.469 0 10 20 30 40 50 60 70 80 90 100 Wi/Ac(ft 3 /ft 2 ) 1.E-02 Figure 5 Example of Water Quality Coefficient versus Liquid Permeability Water Quality Coefficient (md -1 ) 1.E-03 1.E-04 1.E-05 1.E-06 Grade 2 Grade 3 Grade 4 1.E-07 1.E-08 10 100 1000 Maximum Liquid Permeability (md) - OGP 04 (13) -

Figure 6 Injectivity Predictions and Comparison with Historical Data 16000 14000 12000 Injection Rate (bwpd) 10000 8000 6000 4000 Grade 2 Water Grade 3 Water Grade 4 Water Historical Data 2000 0 0 50 100 150 200 250 300 350 400 450 500 550 600 650 700 750 Time (days) - OGP 04 (14) -