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Product Sustainability I m green TM polyethylene Beatriz Luz Product Sustainability May 2014

Agenda Biopolymers Brazilian Scenario Product Sustainability Renewable feedstock LCA WFT and LUC Recyclability Responsible sourcing Communication and education Key learning Conclusion

Biopolymers I m Green Polyethylene biobased recyclable

Market drivers A dynamic industry growing at a rate of roughly 20 percent per year Biopolymers is the evolution of plastics that will contribute significantly to a sustainable society. IB is key to creating a low-carbon economy and it provides a sustainable, commercially viable route out of over-dependence on fossil fuels and on financial services for economic growth. Jonathon Porrit The US Biobased Products Preferred Procurement Program is to increase the development, purchase and use of biobased products through government procurement programmes and voluntary product certification and labeling for consumers.

Green Polyethylene x Fossil Polyethylene sugarcane Oil Ethanol Nafta Dehidration Purification Polyethylene Cracking Purification Green ethylene Polimerization Fossil Ethylene Technology: The production route for green polyethylene and the fossil polyethylene are exactly the same, therefore the green polymer has got the same characteristics, quality and properties than the fossil equivalent.

How do we define product sustainability? Eco-design, design for recycling, RecyClass, circular economy, new business models...

Agenda Brazilian Scenario Product Sustainability Renewable feedstock LCA WFT and LUC Recyclability Responsible sourcing Communication and education Key learning Conclusion

Brazilian Scenario Favorable aspects for the development of biopolymers

Brazilian Scenario Favorable aspects for the development of biopolymers The largest watershed in the world

Brazilian Scenario Favorable aspects for the development of biopolymers Intense solar radiation and climate diversification

Brazilian Scenario Favorable aspects for the development of biopolymers Pioneer in research and development of biofuels

The product sustainability journey July 2007 Preliminary investigation environmental assessment based on secondary data September 2010 Plant start up Code of conduct established Biobased carbon verification PHASE 1 April 2011 Product validation Product certified by Vinçotte PHASE 2 October 2013 Environmental Assessment LCA, WFT, LUC Primary data Key suppliers Critically reviewed ISO 14040 PHASE 3 PHASE 0 99% biobased content verified by ASTM D6866

Agenda Brazilian Scenario Product Sustainability Renewable feedstock LCA WFT and LUC Recyclability Responsible sourcing Communication and education Key learning Conclusion

FILTER CAKE Sugarcane Ethanol Efficient use of resources VINNASSE SUGAR SUGAR CANE SUGAR CANE CRUSHING SUGAR SYRUP ETHANOL PRODUCTION INDUSTRIAL ETHANOL GREEN ETHYLENE GREEN POLYETHYLENE BAGASSE ETHANOL FUEL ENERGY

Brazilian Electricity Matrix 83,1% Hydropower Hard coal Oil, Petroleum based 1,7% 2,8% 4,6% 0,5% 2,7% 4,6% Natural gas Wind Nuclear Bagasse: the same contribuition as natural gas

Brazilian Electricity Matrix 83,1% The sugarcane harvesting happens during the dry season when water reservoirs for hidropower electricity is low. Bio-electricity from bagasse is essential for the Brazilian Energy Matrix 1,7% 2,8% 4,6% 0,5% 2,7% 4,6% Energy Credits: replacement for natural gas Economic factor: export additional electricity to the grid generate additional revenue

Sugarcane Ethanol Production & Productivity 49 70 671 285 64 MEXICO 39 101 INDIA Productivity ton/ha COLOMBIA 79 BRASIL Production MM ton¹ 80 31 AUSTRALIA Reference: FAO STAT, Crystalsev; Sindpeças; Global Insight; Bear Stearns; McKinsey analysis, UNICA, Raizen

Land Usage Significant potential for sustainable growth Total Area 851.48 Millions of hectares Protected/ Native 495,6(58%) 0,02% 50% Sugar Cane 8.14 (2.4%) Sugar 50% Ethanol Arable Land 329.94 (39%) Agriculture 51.7 (16%) Pasture 158.75 (48%) Available 111.34 (33%) Other 25.92 (3%) Braskem s capacity of I m green polyethylene production: 200 kton/year 460 millions liters of Ethanol = approx. 68 thousand hectares

Sugarcane Ethanol Brazilian Agroecological Zoning Programme Floresta Amazônica 2.000 km Areas for sugarcane expansion: Areas with proper conditions for mechanical harvesting Degraded pasture land Regions with lower need for water usage in production 2.500 km No sugarcane expansion Areas with sensitive ecosystems Amazon Forest Pantanal Wetlands Upper Paraguay river basin Cerrado areas Soil and weather condition = productivity (no expansion to Amazon and Pantanal) Respect for food security 87% DA PRODUÇÃO NACIONAL

Sugarcane Ethanol Vinçotte - French certification The renewable content is validated through the C-14 test Beta analytics. Star system based on % of renewable content Green polyethylene got a 4 start rating indicating more than 80% renewable content

Life Cycle Analysis Study Premisses Functional Unit:: 1 kg of resin Boundary: cradle to gate Data coverage Brazilian Scenario 3 ethanol suppliers + Centre-South Average (Jan a March 2012) Green PE Plant (Feb, March and April 2012) 38% Others* 9% Mill A 17% Mill B 62% Software: SimaPro Method CML 2001 Substitution credit methodology system expansion 37% Mill C 6 Impact categories: GWP, Fossil energy demand, Ozone layer depletion, Eutrophication, Acidification, Photochemical Ozone Potential + Water Footprint and LUC *Brazil Centre South dataset

Life Cycle Analysis The Base Case 1 kg of Green HDPE (slurry process, average ethanol supply) following a system expansion approach to account for the electricity co-generated during the process. dluc is also considered to account for the soil carbon stocks and also the biogenic carbon due to the CO2 removal during sugarcane growth

The LCA Practitioners Team Study prepared by: Brazilian experts: Critical Review Panel Andreas Detzel (Chair - IFEU) Martina Krueger (IFEU) Ramani Narayan (Michigan State University)

LCA Main Impact Categories Impact by process stage Global Warming Potential Fossil Energy Consumption Ozone Layer Depletion Potential Eutrophication Potential Acidification Potential Photochemical Ozone Creation Potential Sugarcane Ethanol Green Ethylene HDPE

Global Warming Potential LCA Results Harvesting 1,11 Industrial process Industrial process 0,23 1,22 0,24 Industrial process GWP 100 Balance Positive and negative emissions SUGAR CANE ETHANOL GREEN ETHYLENE GREEN POLYETHYLENE Biogenetic carbon - 3,14-1,10 dluc - 0,71 Green eletricity Braskem av. LCA Kg CO 2 eq /kg bio-based PE - 3,13-0,48 1,22 0,24 Total - 2,15 Kg CO 2 eq /kg bio-based PE

Global Warming Potential HDPE (SLURRY) UNIB GÁS, GRID ELEC ETHYLENE FOSSIL FUEL HEAT E POWER TRANSPORT 9% 8% ETHANOL BAGASSE, DIESEL 42% GWP100 41% SUGARCANE DIESEL, FIELD EMISSIONS, TRASH BURN

Global Warming Potential Braskem bio-based HDPE (slurry) Comparative view: Biobased x Fossil based Braskem fossil HDPE 1,83 Delta 3,98 BRASKEM FOSSIL POLYETHYLENE Kg CO 2 eq /kg fossil PE -2.0-1.0 0 1.0 2.0 kg CO 2 eq/ kg of green PE -2,15 GREEN POLYETHYLENE Kg CO 2 eq /kg bio-based PE

The impact of international transport to markets 2 + % USA + 2 % Europe -2,10 * -2,10 * -2,05 * + 4 % Japan *GWP Kg CO 2 eq/kg bio-based PE SUGAR CANE TREM USINA TRUCK The transport impact throught the life cycle accounts to 9% Brazil -2,15 The impact of international transport. Kg CO 2 eq/kg bio-based PE

Fossil energy consumption Sugarcane ethanol generates bioelectricity contributing to reduce fossil energy demand More than 80% of energy used for green PE production is renewable energy

Eutrophication Semi perenial characteristics of sugarcane and crop rotation = peanuts production Process waste: filter cake and vinasse Avoids the use of 1,449,010 metric tons of chemical fertilizers (Datagro 2008) Tons per hectare 0,5 Vinnasse Tomato 2,2 Cotton 1,0 0,7 Coffee Sugar cane Filter Cake Liquid Effluent

Water Footprint Accounting Plantation & Mill Green WFP Rain water, plant intake Direct Main component: evapotranspiration of sugarcane Vinasse and filter cake recycling relatively minor impact Note data gaps and non-linear relationship Indirect Bio-diesel blend for field operations Blue WFP Production water, from rivers Direct Processing of sugarcane in the mill (e.g. washing of cane, steam generation for processing) Indirect Inputs such as biodiesel & grid electricity Grey WFP Water needed to dilute effluent Direct Phosphorus, nitrogen, potassium from fertilisers Indirect Only data for biodiesel available Allocation Ethanol & electricity exported to the grid by the mills Data provided by: ETH Bioenergia, Tarumã and GASA operated by Raízen (Cosan) located in the west of São Paulo State, within the catchment area of the Paraná Basin.

Water Footprint Green (data from Cabral et al., 2012) Blue Grey Water for industrial use 1992 5m³/ ton. cane crushed Blue 2007/ 2008 1,89 m³/ ton. cane crushed 2009/2010 1,49 m³/ ton. cane crushed 2012 Our study = 1,10 m³/ ton. cane crushed Braskem Supplier E4tech WFP calculations Brazil average Mekonnen & Hoekstra (2010b)

Water Sustainability Annual precipitation data Harvesting occurs during the dry season. 300 200 100 0 Janeiro Fevereiro Março Abril Maio Junho Julho Agosto Setembro Outubro Novembro Dezembro Annual Precipitation Data (Average 1993 2009)

Water Sustainability Water Scarcity Average water scarcity does not exceed 14%. Crop growing season during months with high precipitation so WFP not an issue Monitor agricultural activities impact closely 14 % 12 10 8 6 4 2 0 Janeiro Fevereiro Março Abril Maio Junho Julho Agosto Setembro Outubro Novembro Dezembro Water scarcity in the Paraná Basin

Direct and Indirect LUC Crop- or pastureland Land available For cultivation New sugarcane New crop-or pasture land DIRECT LUC INDIRECT LUC

Land use change dluc VINNASSE FILTER CAKE CHEMICAL FERTILISER - 1,1 Kg CO 2 eq/kg bio-based PE Degraded soil CO 2 New sugarcane Recovered soil CO 2

Product Reciclability End of life Closed Loop I m green polyethylene is 100% recyclable. It can be disposed on the existing recycling schemes for traditional PE I m green polyethylene can generate bio-electricity if send to EfW plants

Agenda Brazilian Scenario Product Sustainability Renewable feedstock LCA WFT and LUC Recyclability Responsible sourcing Communication and education Key learning Conclusion

Responsible Sourcing Code of conduct for ethanol suppliers In line with Brazilian Legislation The 5 pilars 1. Reduction of Cane Burning 2. Conserving biodiversity 3. Good Environmental Practices 4. Respect for Human Rights 5. Life Cycle Assessment (LCA) Guaranteed by a 3rd party auditing programme

Responsible Sourcing 2010 / 2011 2011/2012 2012/2013 2013/2014 Plant start up Internal auditing programme Implementation of the 3rd party auditing programme 94,7% of mills audited* (target) Development of the 3rd party auditing programme partners selection 90% of mills audited* *corresponding of 80% of the volume of ethanol supplied

3 rd Party Auditing Programme Methodology 1ª stage: Mill selection - Mills that contribute to 80% of the volume supplied - Validity of auditing: 2 years 2ª stage: Site visit - 3rd party auditor to follow the assessment checklist - Critical ranking system - Produce the auditing report with or without points for improvement 3ª stage: Continuous Improvement - Suppliers meeting: audit feedback - Actions discussed - Re-validation of commitment from the supplier - Action plan for improvement (if applicable)

3 rd Party Auditing Programme Results All mills commited to the code of conduct To date 87% of the mills have been audited Target 94,7% No mills have shown high critical results Action Plan is being received by all audited mills. The non-delivery of the action plan will get the mill to be audited again.

Responsible Sourcing NGO partnerships BFA Methodology Scorecard BRASKEM PILOT September 2013 Goal An ideal bioplastic feedstock is one that: WWF USA - BFA Biobased Feedstock Alliance helping to build a more sustainable future for the bioplastics industry - Brand Owners led initiative - Feedstock scorecard for risk management - Tailored pilot with Braskem supplier 1. Is legally sourced, conforms to UDHR and is 4. Does not result in destruction of critical ecosystems, loss of produced in a safe and healthy way for workers and Feedstock 1/Region Feedstock 2/Region Feedstock 1/Region Feedstock 2/Region HCV habitats or deforestation surrounding communities Indicator Score Total % Met Score Total % Met Indicator Score Total % Met Score Total % Met Legal Production 8,31 8,03 Biodiversity Occupational Health & Safety 10 Cradle to Gate GHG 8,58 Labor Rights 10 Land Use Change Impacts 10 Chemical Use: Nutrients & Pest Management 7,36 Chemical Use: Nutrients & Pest Management 7,36 64,31 92% 0 0% 63,97 91% 0 0% Water Management 10 Soil Management 10 Land Use Change Impacts 10 Water Management 10 Co-product and Waste Management 8,64 Local & Indigenous Communities 10 2. Is one that is derived from renewable biomass 5. Provides tangible environmental benefits with minimal Feedstock Feedstock 1/Region Feedstock 2/Region 1/Region Feedstock 2/Region whose production is sustainably managed environmental impacts* ** Indicator Score Total % Met Score Total % Met Indicator Score Total % Met Score Total % Met 8,58 Biodiversity 8,03 Cradle to Gate GHG Land Use Change Impacts 10 Cradle to Gate GHG 8,58 Chemical Use: Nutrients & Pest Management 7,36 Land Use Change Impacts 10 54,58 91% 0 0% Soil Management 10 Chemical Use: Nutrients & Pest Management 7,36 62,61 89% 0 0% Water Management 10 Soil Management 10 Co-product and Waste Management 8,64 Water Management 10 Co-product and Waste Management 8,64 3. Does not adversely impact food security or affordability and maintains or improves social and Feedstock 1/Region Water Footprint Data Feedstock 2/Region economic conditions along with ecosystem services in producing communities** Indicator Score Total % Met Score Total % Met Blue Green Grey Food Security/Affordability 10 Feedstock 1/Region Local & Indigenous Communities 10 Feedstock 2/Region Water Management 10 50 100% 0 0% Soil Management 10 Ecosystem Services 10 Solidaridad - Solidaridad Global Farmer Support Programme (FSP) - emerging countries focus - Sugarcane supply chain engagement: farmers, ethanol mills, Braskem and its clients - Increase awareness about sustainability and promote transparency in the sector - Development of tools to promote sustainable practices in the farms, to support the improvement in the field and to monitor progress

Agenda Brazilian Scenario Product Sustainability Renewable feedstock LCA WFP and LUC Recyclability Responsible sourcing Communication and education Key learnings Conclusion

Communication And Education I m green TM : applied to indicate % of renewable content

Agenda Brazilian Scenario Product Sustainability Renewable feedstock LCA WFT and LUC Recyclability Responsible sourcing Communication and education Key learnings Conclusion

Key Learnings LCA is an essential tool to measure product sustainability Data gaps still exists - the best available information has been used. Identification of hot spots for continuous improvement The full picture: Understanding the value chain Study transparency: Methodologies and premises must be clearly stated

Agenda Brazilian Scenario Product Sustainability Renewable feedstock LCA WFT and LUC Recyclability Responsible sourcing Communication and education Key learnings Conclusion

Conclusion SUGAR CANE Life cycle thinking and the circular economy VINNASSE FILTER CAKE Responsible claims LCA based communication Sustainable sourcing co-responsibility avoiding burden shift. Add value. BAGASSE ENERGY GREEN POLYETHYLENE Continuous improvement at the Green Ethylene plant Working with clients for product development and understanding the value proposition

Thank you! Beatriz Luz Product Sustainability beatriz.luz@braskem.com