SAFETY DATA SHEET. Section 1: Identification of the substance/mixture and of the company/undertaking. Section 2: Hazards identification

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Transcription:

Sent to: Public Server Addition. Page: 1 Compilation date: 11/10/2011 Revision date: 09/11/2015 Revision No: 2 Section 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name: REACH registered number(s): 01-2119474443-37 CAS number: 1569-01-3 EINECS number: 216-372-4 Synonyms: BANNERNOL DOWANOL PNP 1-PROPOXYPROPAN-2-0L PROPYLENE- 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of substance / mixture: Distribution of substance. Formulation & (re)packing of substances and mixtures. Uses in coatings. Use in cleaning agents. Lubricant / Lubricating oil. PC39: Cosmetics, personal care products. 1.3. Details of the supplier of the safety data sheet Company name: Leading Solvents Marston Business Park Rudgate Tockwith York YO26 7QF Tel: 01423 358058 Fax: 01423 358923 Email: enquiries@leading-solvents.co.uk 1.4. Emergency telephone number Emergency tel: 01423 358058 (Office Hours Only) Section 2: Hazards identification 2.1. Classification of the substance or mixture Classification under CLP: Most important adverse effects: Eye Irrit. 2: H319; Flam. Liq. 3: H226 Flammable liquid and vapour. Causes serious eye irritation. 2.2. Label elements Label elements: Hazard statements: H226: Flammable liquid and vapour. H319: Causes serious eye irritation.

Signal words: Hazard pictograms: Warning GHS02: Flame GHS07: Exclamation mark Page: 2 Precautionary statements: 2.3. Other hazards Other hazards: PBT: P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280: Wear protective gloves/protective clothing/eye protection/face protection. P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P370+378: In case of fire: Use dry sand/dry chemical or alcohol resistant foam to extinguish. P403: Store in a well-ventilated place. In use, may form flammable / explosive vapour-air mixture. This product is not identified as a PBT/vPvB substance. Section 3: Composition/information on ingredients 3.1. Substances Chemical identity: CAS number: 1569-01-3 EINECS number: 216-372-4 REACH registered number(s): 01-2119474443-37 Section 4: First aid measures 4.1. Description of first aid measures Skin contact: Eye contact: Ingestion: Inhalation: Remove all contaminated clothes and footwear immediately unless stuck to skin. Wash immediately with plenty of soap and water. Immediately flood the eye with plenty of water for at least 15 minutes,holding the eye open. Remove any contact lenses and open eyes wide apart. Get medical attention if any discomfort continues Wash out mouth with water. Consult a doctor. Remove from exposure, rest and keep warm. In severe cases, or if recovery is not rapid or complete, seek medical advice. 4.2. Most important symptoms and effects, both acute and delayed Skin contact: Eye contact: Ingestion: Irritation, defatting, dryness and cracking. There may be irritation and redness. There may be irritation of the throat.

Inhalation: No symptoms. Page: 3 4.3. Indication of any immediate medical attention and special treatment needed Immediate / special treatment: Not applicable. Section 5: Fire-fighting measures 5.1. Extinguishing media Extinguishing media: Alcohol resistant foam. Water spray. Carbon dioxide. Dry chemical powder. 5.2. Special hazards arising from the substance or mixture Exposure hazards: Flammable. In combustion emits toxic fumes. Forms explosive air-vapour mixture. 5.3. Advice for fire-fighters Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes. Section 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions: Refer to section 8 of SDS for personal protection details. Notify the police and fire brigade immediately. Eliminate all sources of ignition. Turn leaking containers leak-side up to prevent the escape of liquid. 6.2. Environmental precautions Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding. 6.3. Methods and material for containment and cleaning up Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method. Do not use equipment in clean-up procedure which may produce sparks. 6.4. Reference to other sections Reference to other sections: Refer to section 8 of SDS. Section 7: Handling and storage 7.1. Precautions for safe handling Handling requirements: Smoking is forbidden. Use non-sparking tools. Ensure there is sufficient ventilation of the area. Avoid the formation or spread of mists in the air. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions: Suitable packaging: Store in a cool, well ventilated area. Keep container tightly closed. Keep away from sources of ignition. Prevent the build up of electrostatic charge in the immediate area. Ensure lighting and electrical equipment are not a source of ignition. Original container stored in a dry and cool place.

Page: 4 7.3. Specific end use(s) Specific end use(s): Section 8: Exposure controls/personal protection 8.1. Control parameters Workplace exposure limits: DNEL/PNEC Values Type Exposure Value Population Effect DNEL Dermal 9 mg/kg/day Workers Systemic DNEL Inhalation 217 mg/m3 Workers Systemic DNEL Dermal 2.2 mg/kg/day Consumers Systemic DNEL Inhalation 26 mg/m3 Consumers Systemic DNEL Oral 2.2mg/kg/day Consumers Systemic PNEC Fresh water 0.1 mg/l - - PNEC Marine water 0.01 mg/l - - PNEC Fresh water sediments 0.386 mg/kg - - PNEC Marine sediments 0.0386 mg/kg - - PNEC Soil (agricultural) 0.0185 mg/kg - - 8.2. Exposure controls Engineering measures: Respiratory protection: Hand protection: Eye protection: Skin protection: Environmental: Ensure there is sufficient ventilation of the area. Ensure lighting and electrical equipment are not a source of ignition. In case of insufficient ventilation,wear suitable respiratory equipment. Butyl, nitrile or pvc coated gloves. Ensure gloves are manufactured/tested in accordance with BS EN 374. Safety goggles. Ensure eye bath is to hand. Impermeable protective clothing. Do not flush into surface water or sanitary sewer system. If the product contaminates rivers and lakes or drains inform respective authorities. Section 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties State: Colour: Odour: Evaporation rate: Oxidising: Solubility in water: Liquid Colourless ethereal Highly soluble

Page: 5 Viscosity: Boiling point/range C: 149-150 Melting point/range C: -70 Flammability limits %: lower: 1.3 upper: 10.6 Flash point C: 46 Part.coeff. n-octanol/water: log Kow 0.621 Autoflammability C: 252 Vapour pressure: 3.8hPa@25C Relative density: 0.880 ph: VOC g/l: 9.2. Other information Other information: Section 10: Stability and reactivity 10.1. Reactivity Reactivity: Stable under recommended transport or storage conditions. 10.2. Chemical stability Chemical stability: Stable under normal conditions. Stable at room temperature. 10.3. Possibility of hazardous reactions Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions. Decomposition may occur on exposure to conditions or materials listed below. 10.4. Conditions to avoid Conditions to avoid: Heat. Hot surfaces. Sources of ignition. Flames. 10.5. Incompatible materials Materials to avoid: Strong oxidising agents. Strong acids. 10.6. Hazardous decomposition products Haz. decomp. products: Carbon monoxide, carbon dioxide, aldehydes and ketones. Section 11: Toxicological information 11.1. Information on toxicological effects Relevant hazards for substance: Hazard Route Basis Serious eye damage/irritation OPT Hazardous: calculated Symptoms / routes of exposure Skin contact: Eye contact: Ingestion: Inhalation: Irritation, defatting, dryness and cracking. There may be irritation and redness. There may be irritation of the throat. No symptoms.

Page: 6 Section 12: Ecological information 12.1. Toxicity Ecotoxicity values: 12.2. Persistence and degradability Persistence and degradability: Biodegradable. 12.3. Bioaccumulative potential Bioaccumulative potential: No bioaccumulation potential. 12.4. Mobility in soil Mobility: Readily absorbed into soil. 12.5. Results of PBT and vpvb assessment PBT identification: This product is not identified as a PBT/vPvB substance. 12.6. Other adverse effects Other adverse effects: Negligible ecotoxicity. Section 13: Disposal considerations 13.1. Waste treatment methods Disposal operations: NB: Transfer to a suitable container and arrange for collection by specialised disposal company. The user's attention is drawn to the possible existence of regional or national regulations regarding disposal. Section 14: Transport information 14.1. UN number UN number: UN1993 14.2. UN proper shipping name Shipping name: FLAMMABLE LIQUID, N.O.S. 14.3. Transport hazard class(es) 14.4. Packing group Transport class: 3 Packing group: III 14.5. Environmental hazards Environmentally hazardous: No Marine pollutant: No 14.6. Special precautions for user Special precautions: No special precautions.

Tunnel code: D/E Transport category: 3 Section 15: Regulatory information Page: 7 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.2. Chemical Safety Assessment Chemical safety assessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier. Section 16: Other information Other information Other information: Phrases used in s.2 and s.3: Legal disclaimer: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 453/2010. * indicates text in the SDS which has changed since the last revision. H226: Flammable liquid and vapour. H319: Causes serious eye irritation. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product. [final page]