Introduction to the Role of Tropospheric Ozone and Arctic Climate Ellen Baum May 8, 2008
There is a significant global role for tropospheric ozone and climate 1.4 Temperature impact from CO2 compared to other climate forcings, relative to 1750 1.2 Temperature in degrees C 1 0.8 0.6 0.4 0.2 Carbon dioxide Black carbon Tropospheric ozone Methane Ramanathan, 2008 0 CO2 Short-lived Climate Forcings 2
Initial Arctic modeling suggests a seasonally, averaged tropospheric ozone-derive temperature increase of 0.28 o C Temperature in degrees C 1.6 1.4 1.2 1 0.8 0.6 0.4 0.2 0 Temperature impact from CO2 compared to other climate forcings, relative to 1880 Carbon dioxide CO2 Black carbon Tropospheric ozone Methane Short-lived Climate Forcings Calculated from Quinn, et.al., ACP, 2008 Note: Different models were used to derive Global (previous slide) and Arctic (this slide) values. 3
Tropospheric ozone is formed in the atmosphere, not emitted Tropospheric ozone is formed in the atmosphere from precursor pollutants - oxides of nitrogen, volatile organic compounds, carbon monoxide, and methane in the presence of light and thus not directly emitted like most other air pollutants. Atmospheric lifetime of ozone is 1 to 2 weeks in summer and 1 to 2 months in winter. Ozone produced in a polluted region of one continent can be transported to another continent. 4
How ozone heats the Arctic The dominant heating pathway is probably transfer of heat produced by Northern Hemisphere ozone into the Arctic. Followed by transport of ozone from outside the Arctic To a smaller extent, ozone formation within the Arctic At the same time, there remain research questions to tease out the relative contributions and better understand precursor roles, including Contribution formed in the Arctic, both from in-arctic precursors and precursors transported into the Arctic. How will this change with a warmer Arctic? Importance of lifetimes, locations and seasonality of the shorter-lived precursors Relevance of looking at specific VOCs 5
Ozone abatement strategies have evolved along with understanding of the O 3 issues O 3 smog recognized as an URBAN problem: Los Angeles, Haagen-Smit identifies chemical mechanism 1950s Smog considered REGIONAL problem; role of biogenic VOCs discovered 1980s A GLOBAL perspective: Cimate impacts and role of intercontinental transport, background Present Abatement Strategy: NMVOCs + NO x +CH 4, CO adapted from Fiore, 2002 6
Different strategies and need for air quality versus climate benefits Air quality programs to reduce ozone levels focus largely on reducing peak ozone levels to protect human health and crop production. This favors strategies reducing local precursors - NOX and non-methane VOCs that are major contributors to peak ozone levels.
Need lower background for climate benefits To benefit climate by reducing net warming, a balanced approach must be taken to reducing all major ozone precursors given their complex atmospheric interactions. NOx is the most complicated precursor. In the short run, it reduces ozone and the radiative forcing from ozone. Over a longer period, however, reductions increase the lifetime of methane, and therefore contribute to warming. Also the nitrate aerosol has a cooling effect, which reductions remove. It s unclear where the balance lies between the negative impacts from increased in methane lifetime and aerosols, particularly nitrate, and the positive climate benefits from ozone reductions. This suggests that NOx reductions continue to be pursued for air quality benefits, with the recognition that climate benefits will need to come largely from carbon monoxide and methane reductions NOx OH CH4 lifetime 8
Climate role of CO, NOx and NMVOC Because CO also uses OH as an atmospheric sink, reducing it will make more OH available as methane sink. from pre-industrial time Using same calculations, and without double counting, methane is 0.59 W/m2, plus another 0.20 W/m2 from methane emissions via ozone. Shindell, Oslo Workshop, from IPCC 4AR, 2007 9
Methane is different Unlike other ozone precursors, methane is not a typical, short-lived ozone precursor. Because methane has a long atmospheric lifetime (8-10 years), emissions become well mixed. Neither air quality nor climate benefits depend strongly on the location of the CH4 emission reductions, implying that the lowest cost emission controls can be targeted. There are, though, regions where methane effects on O3 are enhanced. These include locations with high NOx emissions (e.g., in southern California); regions near the down welling branches of the Hadley cell, at roughly 30 N and 30 S (over the Sahara region of North Africa, the Middle East), or regions with active convection (Caribbean Sea and Gulf Coast of the United States). Given that most of the ozone-related temperature in the Arctic comes from global transport, the benefits of these reductions should be felt in the Arctic. 10
MODELED CLIMATE IMPACTS OF 50% REDUCTIONS IN ANTHROPOGENIC EMISSIONS Methane Radiative Forcing (W/m2) Ozone Radiative Forcing (W/m2) CH4 NOx* VOC NOx &VOC CO -0.3 +.06 -.01 +.05 -.02 -.07 -.06 -.01 -.07 -.01 Total Forcing (W/m2) -.37 0 -.02 -.02 -.03 * doesn t include aerosol climate effects EPA/OAQPS Workshop, 2001 11
Near-term climate impacts are critical to Arctic protection Given concerns about irreversible arctic climate impacts that may occur within the next two decades, should a 20 year GWP, instead of the typical 100 year equivalency, be used to evaluate arctic impact reduction options? Using 20 year impacts more than doubles the warming benefits from methane emissions reductions and would increase CO reduction warming benefits by at least 50 percent. This will also increase the economic value of such emissions, which means much more expensive reductions than typically addressed in current supply curves are feasible. Rypdal, 2005 12
Where are emissions occurring? Next four slides. 13
CO, emissions, Edgar 2000 Agricultur e/biomass burning midand high latitude grassland fires Temperate fires Agriculture waste burning Industry Power generation Charcoal production Waste incineration Biofuels Transport road Residential Industry Power generation Savanna burning refineries, coke ovens, gas works Residential, Commercial Deforestation onroad transport non-road land transport, ie. rail Fossil Fuels Air transport Oil production, Iron and Steel Shipping
NOX, 2000 FROM EDGAR Agriculture /biomass burning MID AND HIGH LAT GRASS FIRES MID AND HIGH LAT FOREST FIRES AG. WASTE BURNING INDUSTRY POWER GENERATION RESIDENTIAL Biofuels SAVANNAH AND SHRUBS FIRES INDUSTRIAL TROPICAL FOREST FIRES Indu -stry BUILDING MATERIALS NON-FERROUS IRON AND STEEL OIL PRODUCTION SHIPPING AVIATION NON ROAD TRANSPORT ROAD TRANSPORT POWER GENERATION REFINERIES, COKE OVENS, GAS WORKS RESIDENTIAL, COMMERICAL Fossil Fuels
Non methane VOCS, 2000 Agriculture /biomass burning MID LAT SAVANNAH TROPICAL FOREST FIRES FIRES MID LAT FOREST FIRES SAVANNAH FIRES AG WASTE BURNING SOLVENTS WASTE HANDLING INDUSTRY POWER GENERATION RESIDENTIAL ROAD TRANSPORT Biofuels INDUSTRY REFINERIES, GAS WORKS, COKE OVENS RESIDENTIAL IRON &STEEL OIL PROD NON-ROAD TRANSPORT AIR Industry GAS PRODUCTION/ TRANS Fossil Fuels
METHANE, 2000 EDGAR LANDFILLS WASTEWATER 15 TREATMENT MID/HIGH LATITUDE AG WASTE FOREST FIREST BURNING SAVANNAH AND SHRUB FIRES TROPICAL FOREST FIRES ANIIMAL WASTE MANAGEMENT HUMAN WASTEWATER DISPOSAL BIOFUEL COMMERCIAL/ RESIDENTIAL RESIDENTIAL COAL PRODUCTION GAS PRODUCTION OIL PRODUCTION OIL PRCESSES GAS FLARING ENTERIC FERMENTATION RICE CULTIVATION
Conclusions Traditional clean air regulation programs addressing ozone will not benefit climate and thus the Arctic. Substantial methane and CO reductions are needed reduce ozone warming of the Arctic. Research and analytical questions remain, including whether targeting global hot spots to reduce ozone could have an enhanced benefit in the Arctic. 18
Climate impact, by source category, from multiple emissions, in 2030, SRES A1B 03 ST =ozone impact 03 LT = CH4 affects Black number a top each column is total forcing From Unger, et. al. JGR, 2008 19
Relative importance of different regions to annual mean Arctic concentration at surface and atmosphere. From Shindell, et. al. ACPD, 2008 20