2008 PRTR water emissions of priority substances www.prtr.bund.de 4590 installations total 404 installations with releases to water 235 installations with releases of priority substances
2008 PRTR water emissions of priority substances 0 50 100 0 50 100 mineral industry other activities paper and wood production and processing waste and wastewater management trichlororbenzenes (all isomers) trichloromethane tetrachloroethane (PER) tetrachlormethane pentachlorophenole (PCP) PAH octylphenole and ethoxylates nonylphenole and ethoxylates Nickel and its compounds naphtalene mercury and its compounds lead and its compounds isoproturone hexachlorocyclohexane (HCH) fluoranthene endosulfane diuron dioxins and furanes (as Teq) dichloromethane (DCM) di (2 ethylhexyl)phthalate (DEHP) cadmium and its compounds anthracene 1,2 Dichlorethane (EDC) chemical industry energy sector food and beverage sectro metal industry trichlororbenzenes (all isomers) trichloromethane tetrachloroethane (PER) tetrachlormethane pentachlorophenole (PCP) PAH octylphenole and ethoxylates nonylphenole and ethoxylates Nickel and its compounds naphtalene mercury and its compounds lead and its compounds isoproturone hexachlorocyclohexane (HCH) fluoranthene endosulfane diuron dioxins and furanes (as Teq) dichloromethane (DCM) di (2 ethylhexyl)phthalate (DEHP) cadmium and its compounds anthracene 1,2 Dichlorethane (EDC) 0 50 100 0 50 100 number of reported releasse
2008 PRTR water emissions of priority substances 0 5000 10000 15000 20000 0 5000 10000 15000 20000 mineral industry other activities paper and wood production and processing waste and wastewater management trichlororbenzenes (all isomers) trichloromethane tetrachloroethane (PER) tetrachlormethane pentachlorophenole (PCP) PAH octylphenole and ethoxylates nonylphenole and ethoxylates Nickel and its compounds naphtalene mercury and its compounds lead and its compounds isoproturone hexachlorocyclohexane (HCH) fluoranthene endosulfane diuron dioxins and furanes (as Teq) dichloromethane (DCM) di (2 ethylhexyl)phthalate (DEHP) cadmium and its compounds anthracene 1,2 Dichlorethane (EDC) chemical industry energy sector food and beverage sectro metal industry trichlororbenzenes (all isomers) trichloromethane tetrachloroethane (PER) tetrachlormethane pentachlorophenole (PCP) PAH octylphenole and ethoxylates nonylphenole and ethoxylates Nickel and its compounds naphtalene mercury and its compounds lead and its compounds isoproturone hexachlorocyclohexane (HCH) fluoranthene endosulfane diuron dioxins and furanes (as Teq) dichloromethane (DCM) di (2 ethylhexyl)phthalate (DEHP) cadmium and its compounds anthracene 1,2 Dichlorethane (EDC) 0 5000 10000 15000 20000 reported releases (kg/y) 0 5000 10000 15000 20000
2008 PRTR water emissions of priority substances 0 20 40 60 80 100 0 20 40 60 80 100 mineral industry other activities paper and wood production and processing waste and wastewater management trichlororbenzenes (all isomers) trichloromethane tetrachloroethane (PER) tetrachlormethane pentachlorophenole (PCP) PAH octylphenole and ethoxylates nonylphenole and ethoxylates Nickel and its compounds naphtalene mercury and its compounds lead and its compounds isoproturone hexachlorocyclohexane (HCH) fluoranthene endosulfane diuron dioxins and furanes (as Teq) dichloromethane (DCM) di (2 ethylhexyl)phthalate (DEHP) cadmium and its compounds anthracene 1,2 Dichlorethane (EDC) chemical industry energy sector food and beverage sectro metal industry trichlororbenzenes (all isomers) trichloromethane tetrachloroethane (PER) tetrachlormethane pentachlorophenole (PCP) PAH octylphenole and ethoxylates nonylphenole and ethoxylates Nickel and its compounds naphtalene mercury and its compounds lead and its compounds isoproturone hexachlorocyclohexane (HCH) fluoranthene endosulfane diuron dioxins and furanes (as Teq) dichloromethane (DCM) di (2 ethylhexyl)phthalate (DEHP) cadmium and its compounds anthracene 1,2 Dichlorethane (EDC) 0 20 40 60 80 100 percentage of total release 0 20 40 60 80 100
2008 PRTR water emissions of priority substances a more detailed look into chemical industry waste and waste water management
Chemical Industry 0 20 40 60 80 100 0 20 40 60 80 100 0 20 40 60 80 100 explosives and pyrotechnic products gases non metals, metal oxides oxygen containing hydrocarbons salts simple hydrocarbons trichlororbenzenes (all isomers) trichloromethane PAH octylphenole and ethoxylates nonylphenole and ethoxylates Nickel and its compounds naphtalene mercury and its compounds lead and its compounds hexachlorocyclohexane (HCH) dioxins and furanes (as Teq) dichloromethane (DCM) di (2 ethylhexyl)phthalate (DEHP) cadmium and its compounds anthracene 1,2 Dichlorethane (EDC) acids basic inorganic chemicals basic organic chemicals basic pharmaceutical products basic plastic materials dyes and pigments trichlororbenzenes (all isomers) trichloromethane PAH octylphenole and ethoxylates nonylphenole and ethoxylates Nickel and its compounds naphtalene mercury and its compounds lead and its compounds hexachlorocyclohexane (HCH) dioxins and furanes (as Teq) dichloromethane (DCM) di (2 ethylhexyl)phthalate (DEHP) cadmium and its compounds anthracene 1,2 Dichlorethane (EDC) 0 20 40 60 80 100 0 20 40 60 80 100 percentage of total release 0 20 40 60 80 100
waste and waste water management 0 50 100 recovery or disposal of hazardous waste Urban waste water treatment plants > 100,000 p.e. trichlororbenzenes (all isomers) trichloromethane tetrachloroethane (PER) tetrachlormethane pentachlorophenole (PCP) octylphenole and ethoxylates nonylphenole and ethoxylates Nickel and its compounds mercury and its compounds lead and its compounds isoproturone hexachlorocyclohexane (HCH) fluoranthene endosulfane diuron dioxins and furanes (as Teq) dichloromethane (DCM) di (2 ethylhexyl)phthalate (DEHP) cadmium and its compounds 1,2 Dichlorethane (EDC) incineration of non hazardous waste Independently operated industrial waste water treatment plants Landfills receiving > 10 t/d or > 25.000 t tot. Capacity trichlororbenzenes (all isomers) trichloromethane tetrachloroethane (PER) tetrachlormethane pentachlorophenole (PCP) octylphenole and ethoxylates nonylphenole and ethoxylates Nickel and its compounds mercury and its compounds lead and its compounds isoproturone hexachlorocyclohexane (HCH) fluoranthene endosulfane diuron dioxins and furanes (as Teq) dichloromethane (DCM) di (2 ethylhexyl)phthalate (DEHP) cadmium and its compounds 1,2 Dichlorethane (EDC) 0 50 100 0 50 100 number of reported releasse
waste and waste water management 0 20 40 60 80 100 recovery or disposal of hazardous waste Urban waste water treatment plants > 100,000 p.e. trichlororbenzenes (all isomers) trichloromethane tetrachloroethane (PER) tetrachlormethane pentachlorophenole (PCP) octylphenole and ethoxylates nonylphenole and ethoxylates Nickel and its compounds mercury and its compounds lead and its compounds isoproturone hexachlorocyclohexane (HCH) fluoranthene endosulfane diuron dioxins and furanes (as Teq) dichloromethane (DCM) di (2 ethylhexyl)phthalate (DEHP) cadmium and its compounds 1,2 Dichlorethane (EDC) incineration of non hazardous waste Independently operated industrial waste water treatment plants Landfills receiving > 10 t/d or > 25.000 t tot. Capacity trichlororbenzenes (all isomers) trichloromethane tetrachloroethane (PER) tetrachlormethane pentachlorophenole (PCP) octylphenole and ethoxylates nonylphenole and ethoxylates Nickel and its compounds mercury and its compounds lead and its compounds isoproturone hexachlorocyclohexane (HCH) fluoranthene endosulfane diuron dioxins and furanes (as Teq) dichloromethane (DCM) di (2 ethylhexyl)phthalate (DEHP) cadmium and its compounds 1,2 Dichlorethane (EDC) 0 20 40 60 80 100 0 20 40 60 80 100 percentage of total release
merging PRTR and UWWTD UWWTP (PRTR (5f)) 202 sewage treatment plants size > 100,000 p.e. (100,000-2.9 Mio. p.e.) loads of priority substances (17 substances reported) substances specific thresholds UWWTP (91/271/EWG) agglomerations > 2,000 p.e. ~ 4000 in Germany (234 plants > 100,000 p.e) organic design capacity (p.e.) nominal load (p.e.)
ODC distribution > 1.000.000 > 500.00-1.000.000 Ausbaugröße in EW > 300.000-500.000 > 200.000-300.000 > 150.000-200.000 > 100.000-150.000 0 10 20 30 40 50 60 Anzahl der KA
smallest plants with reported releases priority substance ODC p.e nominal load p.e. load kg/a Nickel 105.000 44.714 118,9 Mercury 105.000 93.127 1,30 Lead 115.000 78.842 170,3 Cadmium 115.000 78.842 17,10 Di-2-Ethylhexylphthalat 130.000 71.000 20,40 Nonylphenol 133.000 71.000 4,84 PCP 168.000 136.000 9,98 Dichloromethan 170.000 176.000 48,97 Octylphenole und Octylphenolethoxylate 170.000 176.000 4,90 1-2-Dichlorethan 170.000 176.000 97,95
smallest plants with reported releases priority substancef ODC p.e nominal load p.e. load kg/a Tributyltin 270.000 180.552 1,61 Diuron 440.000 335.091 2,49 Trichlormethane 422.000 409.602 136,0 Trichlorbenzenes 422.000 409.602 1,21 Hexachlorcyclohexane 422.000 409.602 4,95 Isoproturon 445.000 405.850 9,16 Fluoranthene 500.000 432.999 2,00
per capita emissions -mercury and compounds- 0,00007 0,00006 EW-spezifische Hg-Fracht (kg/ew/a) 0,00005 0,00004 0,00003 0,00002 0,00001 0 0 200.000 400.000 600.000 800.000 1.000.000 1.200.000 1.400.000 Nominalbelastung (EW)
per capita emissions -mercury and compounds- 56 reports 27 measured 25 calculated 4 estimated
per capita emissions -lead and compounds- 0,0025 0,002 EW-spezifische Blei-Fracht (kg/ew/a) 0,0015 0,001 0,0005 0 0 200.000 400.000 600.000 800.000 1.000.000 1.200.000 1.400.000 1.600.000 1.800.000 Nominalbelastung (EW)
per capita emissions -lead and compounds- 48 reports 23 measured 20 calculated 5 estimated
per capita emissions -cadmium and compounds- 0,00025 EW-spezifische Cadmium-Fracht (kg/ew/a) 0,0002 0,00015 0,0001 0,00005 0 0 200.000 400.000 600.000 800.000 1.000.000 1.200.000 1.400.000 1.600.000 1.800.000 2.000.000 Nominalbelastung (EW)
per capita emissions -cadmium and compounds- 18 reports 13 measured 4 calculated 1 estimated
per capita emissions -nickel and compounds- 0,005 0,0045 EW-spezifische Nickel-Fracht (kg/ew/a) 0,004 0,0035 0,003 0,0025 0,002 0,0015 0,001 0,0005 0 0 200.000 400.000 600.000 800.000 1.000.000 1.200.000 1.400.000 1.600.000 1.800.000 2.000.000 Nominalbelastung (EW)
per capita emissions -nickel and compounds- 132 reports 66 measured 61 calculated 5 estimated
per capita emissions -Nonylphenole- 0,00030 0,00025 EW spezifische N-Fracht (kg/ew/a) 0,00020 0,00015 0,00010 0,00005 0,00000 0 200.000 400.000 600.000 800.000 1.000.000 1.200.000 Nominalbelastung EW
per capita emissions Di-2-Ethylhexylphthalate 0,00035 0,0003 EW-spezifische Arsen-Fracht (kg/ew/a) 0,00025 0,0002 0,00015 0,0001 0,00005 0 0 200.000 400.000 600.000 800.000 1.000.000 1.200.000 Nominalbelastung (EW)
conclusions the urban waste water system is an important source detailed and regionalised knowledge of infrastructure necessary reliable extrapolations via per-capita emission factors high quality analytical data required (LOD artifacts)
our next steps evaluate data from special investigations design»sample«for model calculations design and perform monitioring program
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