MATERIAL SAFETY DATA SHEET 1 Product and Company Identification Product Name 88% CAS # Product use Manufacturer Mixture Food Additive / Specialty chemical SODROX Chemicals Ltd 74 Wellington Road 124, RR #6 Guelph, ON N1H 6J3 CA Business Phone: 519-837-233 Fax: 519-837-33 Emergency Phone: 1-8-363-6824 2 Hazards Identification Emergency overview Potential short term health effects Routes of exposure Eyes Skin Inhalation Ingestion Target organs Chronic effects Signs and symptoms DANGER CAUSES EYE BURNS CAUSES SKIN BURNS Eye, Skin contact, Inhalation, Ingestion Causes chemical burns May cause blindness May cause chemical burns Causes chemical burns May cause respiratory tract irritation May cause chemical burns to mouth, throat and stomach Eyes Skin Mucous membranes Prolonged or repeated exposure to dilutions can cause drying, defatting and dermatitis The product may cause burns to eyes, skin and mucous membranes OSHA Regulatory Status This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 19112 Potential environmental effects See section 12 3 Composition / Information on Ingredients Ingredient(s) CAS # Percent 79-33-4 6-1 First aid procedures Eye contact Skin contact Inhalation Ingestion General advice Flammable properties 4 First Aid Measures Immediately flush with cool water Remove contact lenses, if applicable, and continue flushing for 15 minutes Obtain medical attention immediately Immediately flush with cool water for 15 minutes while removing contaminated clothing and shoes Discard or wash well before reuse Obtain medical attention if irritation persists If symptoms develop move victim to fresh air If symptoms persist, obtain medical attention Do not induce vomiting If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration Never give anything by mouth if victim is unconscious, or is convulsing Obtain medical attention If you feel unwell, seek medical advice (show the label where possible) Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves Show this safety data sheet to the doctor in attendance Avoid contact with eyes and skin Keep out of reach of children 5 Fire Fighting Measures Not flammable by WHMIS/OSHA criteria #1895 Page 1 of 6
Extinguishing media Suitable extinguishing media Dry chemical Carbon dioxide Alcohol foam Foam Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighters Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Firefighters should wear full protective clothing including self contained breathing apparatus May include and are not limited to: Oxides of carbon 6 Accidental Release Measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up Handling Storage Exposure limits Ingredient(s) Keep unnecessary personnel away Do not touch or walk through spilled material Do not touch damaged containers or spilled material unless wearing appropriate protective clothing Keep people away from and upwind of spill/leak Prevent entry into waterways, sewers, basements or confined areas Stop leak if you can do so without risk Before attempting clean up, refer to hazard data given above Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers Prevent large spills from entering sewers or waterways Contact emergency services and supplier for advice Never return spills to original containers for re-use 7 Handling and Storage DANGER -- CORROSIVE Use good industrial hygiene practices in handling this material Do not get in eyes, on skin or on clothing Wash thoroughly after handling Keep out of the reach of children Store in a closed container away from incompatible materials 8 Exposure Controls / Personal Protection Exposure Limits Engineering controls Personal protective equipment Eye / face protection Hand protection Skin and body protection Respiratory protection ACGIH-TLV Not established OSHA-PEL Not established Not normally required if good ventilation is maintained Wear chemical goggles Rubber gloves Confirm with a reputable supplier first As required by employer code Rubber apron recommended Where exposure guideline levels may be exceeded, use an approved NIOSH respirator General hygiene considerations Use good industrial hygiene practices in handling this material When using do not eat or drink Wash hands before breaks and immediately after handling the product 9 Physical and Chemical Properties Appearance Color Form Odor Liquid Colourless / Yellow / Light brown Liquid Characteristic #1895 Page 2 of 6
Odor threshold Physical state Liquid ph < 2 Melting point Freezing point Boiling point Pour point Evaporation rate Flash point Auto-ignition temperature Flammability limits in air, lower, % by volume Flammability limits in air, upper, % by volume Vapor pressure Vapor density Specific gravity 12 Octanol/water coefficient Solubility (H2O) Viscosity Percent volatile 23 F (11 C) (4% solution) Complete 5-6 MPas @25 C (5-9% solution) 1 Stability and Reactivity Reactivity Possibility of hazardous reactions Chemical stability Conditions to avoid Incompatible materials Reacts vigorously with alkaline material This product may react with reducing agents Hazardous polymerization does not occur Stable under recommended storage conditions Do not mix with other chemicals Bases Reducing agents Hazardous decomposition products May include and are not limited to: Oxides of carbon 11 Toxicological Information Component analysis - LC5 Ingredient(s) Component analysis - Oral LD5 Ingredient(s) Effects of acute exposure Eye Skin Inhalation Ingestion Sensitization Chronic effects Carcinogenicity Mutagenicity Reproductive effects Teratogenicity Name of Toxicologically Synergistic Products LC5 LD5 181 mg/kg guinea pig; 3543 mg/kg rat; 4875 mg/kg mouse Causes chemical burns May cause blindness May cause chemical burns Causes chemical burns May cause respiratory tract irritation May cause chemical burns to mouth, throat and stomach Non-hazardous by WHMIS/OSHA criteria Non-hazardous by WHMIS/OSHA criteria Non-hazardous by WHMIS/OSHA criteria Non-hazardous by WHMIS/OSHA criteria Non-hazardous by WHMIS/OSHA criteria Non-hazardous by WHMIS/OSHA criteria #1895 Page 3 of 6
12 Ecological Information Ecotoxicity Components of this product have been identified as having potential environmental concerns Ecotoxicity - Freshwater Algae - Acute Toxicity Data 79-33-4 7 Hr EC5 Pseudokirchneriella subcapitata: 35 mg/l Ecotoxicity - Freshwater Fish - Acute Toxicity Data 79-33-4 96 Hr LC5 Brachydanio rerio: 32 mg/l [semi-static]; 96 Hr LC5 Lepomis macrochirus: 1-18 mg/l [static]; 96 Hr LC5 Oncorhynchus mykiss: 1-18 mg/l [static] Ecotoxicity - Water Flea - Acute Toxicity Data 79-33-4 48 Hr EC5 Daphnia magna: 24 mg/l; 48 Hr EC5 Daphnia magna: 18-32 mg/l [Static] Persistence / degradability Bioaccumulation / accumulation Mobility in environmental media Environmental effects Aquatic toxicity Partition coefficient Chemical fate information Other adverse effects 13 Disposal Considerations Disposal instructions Waste from residues / unused products Contaminated packaging Review federal, state/provincial, and local government requirements prior to disposal 14 Transport Information US Department of Transportation (DOT) Basic shipping requirements: Proper shipping name Corrosive liquid, acidic, organic, nos (LACTIC ACID) Hazard class 8 UN number UN3265 Packing group II Additional information: Special provisions B2, IB2, T11, TP2, TP27 Packaging exceptions 154 ERG number 153 Transportation of Dangerous Goods (TDG - Canada) Basic shipping requirements: Proper shipping name CORROSIVE LIQUID, ACIDIC, ORGANIC, NOS (LACTIC ACID) Hazard class UN number Packing group Additional information: Special provisions 8 UN3265 II 16 #1895 Page 4 of 6
Canadian federal regulations WHMIS status WHMIS classification WHMIS labeling 15 Regulatory Information This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations Controlled Class E - Corrosive Material Occupational Safety and Health Administration (OSHA) Yes 29 CFR 19112 hazardous chemical US Federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 19112 CERCLA (Superfund) reportable quantity None Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Section 32 extremely No hazardous substance Section 311 hazardous chemical Yes Clean Air Act (CAA) Clean Water Act (CWA) State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm Inventory name Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) No United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) 16 Other Information Severe Serious Moderate Slight Minimal LEGEND HMIS/NFPA Disclaimer Effective date 4 3 2 1 Health Flammability Physical Hazard Personal Protection / 3 X 3 Information contained herein was obtained from sources considered technically accurate and reliable While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document 15-Feb-212 #1895 Page 5 of 6
Expiry date 15-Feb-215 Prepared by Dell Tech Laboratories Ltd (519) 858-521 Other information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document This MSDS conforms to the ANSI Z41/Z1291-21 Standard Note: The responsibility to provide a safe workplace remains with the user The user should consider the health hazards and safety information contained herein as a guide and should take those precautions required in an individual operation to instruct employees and develop work practice procedures for a safe work environment The information contained herein is, to the best of our knowledge and belief, accurate However, since the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by the use of this material It is the responsibility of the user to comply with all applicable laws and regulations Attention: Receiver of the chemical goods / MSDS coordinator - As part of our commitment to the Canadian Association of Chemical Distributors (CACD) Responsible Distribution initiative, Sodrox Chemicals Ltdrequire, as a condition of sale, that you forward the attached Material Safety Data Sheet(s) to all affected employees, customers, and end-users Sodrox Chemicals Ltd will send any available supplementary handling, health, and safety information to you at your request #1895 Page 6 of 6