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Cambridge International Examinations Cambridge International General Certificate of Secondary Education *5864453464* PYSICAL SCIENCE 0652/31 Paper 3 (Core) October/November 2017 1 hour 15 minutes Candidates answer on the Question Paper. No Additional Materials are required. READ TESE INSTRUCTIONS FIRST Write your Centre number, candidate number and name on all the work you hand in. Write in dark blue or black pen. You may use an B pencil for any diagrams, graphs, tables or rough working. Do not use staples, paper clips, glue or correction fluid. DO NOT WRITE IN ANY BARCODES. Answer all questions. A copy of the Periodic Table is printed on page 20. Electronic calculators may be used. At the end of the examination, fasten all your work securely together. The number of marks is given in brackets [ ] at the end of each question or part question. This document consists of 20 printed pages. DC (ST/FC) 160376/4 R [Turn over

2 1 A student measures the density of a liquid. Fig. 1.1 shows the apparatus she uses. 000g A B Fig. 1.1 (a) (i) Name apparatus A, which is used to measure the volume of the liquid. Name apparatus B, which is used to measure the mass of the liquid. (b) Table 1.1 shows the student s results. mass of A when empty / g Table 1.1 mass of A and liquid / g volume of liquid / cm 3 275 429 118 (i) Calculate the mass of the liquid in A. Calculate the density of the liquid in A. Show your working and give a unit....g [1] density =... unit... [3]

3 (c) The student pours the liquid into a beaker. She puts some aluminium powder at the bottom of the beaker. She gently heats the beaker, as shown in Fig. 1.2. She observes the aluminium powder slowly move upwards. aluminium powder aluminium powder heat Fig. 1.2 (i) Fill in the blanks in the sentence to explain why the aluminium powder moves upwards. When the liquid is heated it..., causing the density to... and the warm water to rise to the top of the liquid. [2] Name the method of thermal energy transfer that the experiment demonstrates.... [1] [Turn over

2 Complete the passage by writing terms from the list in the blank spaces. Each term may be used once, more than once or not at all. 4 addition polymerisation bitumen boiling points chromatography diesel ethanol fractional distillation gases hydrocarbons melting points paraffin Crude oil is a mixture of.... The components in crude oil are separated using.... This process depends on the different... of the components. The molecules in crude oil with the longest carbon chains make up the fraction called.... One of the products made from crude oil is ethene, which can be made into poly(ethene) by a process called.... [5]

3 (a) Fill in the blanks in the sentences to describe the operation of the solar cells. 5 Solar energy is transferred to the Earth by infra-red and... radiation. Solar energy from the... is converted by the solar cells to... energy. [3] (b) (i) Nuclear power stations use nuclear fission to produce power. Explain what is meant by nuclear fission....[3] Suggest one advantage and one disadvantage of nuclear power stations compared with coal-fired power stations. advantage of nuclear power stations disadvantage of nuclear power stations...[2] [Turn over

4 Fig 4.1 shows apparatus used to react iron filings with air. Fig 4.2 shows the same apparatus a few days later. 6 iron filings rusted iron filings water water Fig. 4.1 Fig. 4.2 (a) (i) The oxygen in the air in the test-tube reacts with the iron. Suggest why the water level stops rising 21% of the way up the test-tube. Name the main gas present in the test-tube in Fig. 4.2 after the oxygen has reacted. (b) (i) Balance the equation for the reaction between iron and oxygen.... Fe +... O 2... Fe 2 O 3 [1] Name the type of reaction shown in this experiment. (c) The experiment is repeated using copper instead of iron. Suggest what is observed. Give a reason for your answer. observation...... reason......[2]

5 (a) Fig. 5.1 shows a ray of light incident on the surface of a rectangular glass block. 7 incident ray i r reflected ray glass block Fig. 5.1 Some of the light is reflected at the surface and some is refracted through the block. (i) State the relationship between angle i and angle r shown on Fig. 5.1. On Fig. 5.1, draw the refracted ray through the glass block and out again. [2] [Turn over

(b) Fig 5.2 shows two rays of light from a small lamp at the bottom of a swimming pool. 8 water ray A X ray B lamp Fig. 5.2 (i) Ray A emerges parallel to the surface of the water. Name the incident angle X shown in Fig. 5.2. Complete ray B to show its path after it reaches the surface of the water. [1]

6 (a) Zinc reacts with hydrochloric acid to form hydrogen. 9 A student sets up the apparatus shown in Fig. 6.1 to collect the hydrogen from this reaction. dilute hydrochloric acid test-tube hydrochloric acid water zinc delivery tube Fig. 6.1 (i) The apparatus has not been set up correctly. The hydrogen escapes into the atmosphere instead of going along the delivery tube. Suggest how the apparatus could be safely changed so that the hydrogen is collected in the test-tube. Adding a catalyst to a reaction increases the rate of that reaction. State two other ways of making the reaction shown in Fig. 6.1 faster. 1... 2... [2] (iii) State what is observed when a lighted splint is placed near the mouth of a test-tube full of hydrogen. [Turn over

10 (b) ydrogen is used as a fuel. (i) State what is meant by a fuel. State the product(s) when hydrogen is used as a fuel. (iii) ydrogen is rarely used as a fuel for cars. Suggest two reasons why it is difficult to use hydrogen as a fuel for cars. 1... 2... [2]

11 7 (a) Pitchblende is an ore of uranium. State what is meant by an ore.......[1] (b) Pitchblende contains radioactive isotopes. A scientist examines the radioactive nature of pitchblende. Fig. 7.1 shows the apparatus that is used. absorber detector pitchblende counter 4014 Fig. 7.1 The count on the count meter shows the number of emissions detected by the detector. The emissions over 5 minutes are measured with no pitchblende present. Different absorbers are then placed between the detector and the pitchblende. The number of emissions over 5 minutes for each absorber is measured using the detector and the count meter. The experiment is repeated. Table 7.1 over the page shows the results. [Turn over

12 Table 7.1 count test A B C D E pitchblende No Yes Yes Yes Yes absorber none none 3 cm lead experiment 1 experiment 2 3 cm aluminium 0.1 mm aluminium 38 5049 1045 1855 2735 42 5026 1058 1835 2812 (i) State why there is a count, even when there is no pitchblende near the apparatus. Identify from Table 7.1 which two tests show that α-radiation is present in the emissions from pitchblende. test... and test... [2] (iii) Describe the nature of an α-particle....[2] (iv) The results for experiment 2 are slightly different from the results for experiment 1. Explain what this tells us about the nature of radioactive emission.

8 Table 8.1 gives information about some elements of the Periodic Table. element group proton number 13 Table 8.1 nucleon number electron arrangement argon VIII 18 40 2.8.8 state at room temperature... ion does not ionise fluorine... 9 19 2.7... F sodium I 11 23... solid... sulfur VI...... 2.8.6 solid S 2 Complete Table 8.1 by writing in the correct information in the blank spaces. [7] [Turn over

14 9 Fig. 9.1 shows an electrical circuit. W X (a) (i) Identify the component labelled W. Fig. 9.1 W is a... [1] The resistance of component W is increased. State the effect, if any, this has on the current in the resistor X. (b) Fig. 9.2 shows a second circuit. Y A Fig. 9.2 Resistor Y has a resistance of 8.0 Ω. (i) On Fig. 9.2, draw a voltmeter to measure the potential difference across the battery. Use the circuit symbol for a voltmeter. [2] The voltmeter reads 4.6 V. Calculate the current in the circuit. Show your working. current =... A [2]

15 (c) (i) On Fig. 9.3, draw a second resistor connected in parallel with resistor Y. Label this resistor with a Z. A Y Fig. 9.3 [1] State how the ammeter reading in this circuit compares with the ammeter reading in the circuit in Fig. 9.2. [Turn over

16 10 (a) Gold is described as a native metal. (i) Suggest what is meant by native metal. Name one other native metal. (b) Aluminium is extracted from an ore. (i) Name an ore of aluminium. Iron ore is heated with carbon to extract iron. State why carbon cannot be used to extract aluminium from its ore. (iii) Aluminium and stainless steel are used to make saucepans. Name two other uses of stainless steel. 1... 2... [2]

17 11 (a) A student has three metal bars, A, B and C. The bars are aluminium, iron, and a magnet. e uses a second magnet to test each bar. The magnet attracts both ends of bar A. There is no force between the magnet and bar B. The magnet attracts one end of bar C and repels the other end. Identify which bar, A, B and C is aluminium,... iron,... a magnet.... [2] (b) The student hangs two nails on the magnet, as shown in Fig. 11.1. N magnet S nails Fig. 11.1 (i) Label, on Fig. 11.1, the poles induced in each nail. [1] Explain why the nails hang with the lower ends separated as shown in Fig. 11.1. [Turn over

18 12 Table 12.1 gives some information about members of a homologous series of acids. Table 12.1 acid formula structure methanoic CO 2 O C O ethanoic C 3 CO 2 O propanoic C 2 5 CO 2 C C C O (a) Explain what is meant by the term homologous series..........[2] (b) Draw the structure of ethanoic acid in the space below. [2] (c) Ethanoic acid reacts with sodium hydroxide. One of the products is a salt called sodium ethanoate. Name the other product....[1]

19 (d) Ethanoic acid is a weak acid. (i) Suggest the p of ethanoic acid.... [1] State how you would measure the p of ethanoic acid. Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the publisher will be pleased to make amends at the earliest possible opportunity. To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced online in the Cambridge International Examinations Copyright Acknowledgements Booklet. This is produced for each series of examinations and is freely available to download at www.cie.org.uk after the live examination series. Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.

20 Group The Periodic Table of Elements 1 hydrogen 1 2 e helium 4 I II III IV V VI VII VIII 3 Li lithium 7 4 Be beryllium 9 atomic number atomic symbol Key name relative atomic mass 11 Na sodium 23 12 Mg magnesium 24 19 K potassium 39 20 Ca calcium 40 37 Rb rubidium 85 38 Sr strontium 88 55 Cs caesium 133 56 Ba barium 137 87 Fr francium 88 Ra radium 5 B boron 11 13 Al aluminium 27 31 Ga gallium 70 49 In indium 115 81 Tl thallium 204 6 C carbon 12 14 Si silicon 28 32 Ge germanium 73 50 Sn tin 119 82 Pb lead 207 22 Ti titanium 48 40 Zr zirconium 91 72 f hafnium 178 104 Rf rutherfordium 23 V vanadium 51 41 Nb niobium 93 73 Ta tantalum 181 105 Db dubnium 24 Cr chromium 52 42 Mo molybdenum 96 74 W tungsten 184 106 Sg seaborgium 25 Mn manganese 55 43 Tc technetium 75 Re rhenium 186 107 Bh bohrium 26 Fe iron 56 44 Ru ruthenium 101 76 Os osmium 190 108 s hassium 27 Co cobalt 59 45 Rh rhodium 103 77 Ir iridium 192 109 Mt meitnerium 28 Ni nickel 59 46 Pd palladium 106 78 Pt platinum 195 110 Ds darmstadtium 29 Cu copper 64 47 Ag silver 108 79 Au gold 197 111 Rg roentgenium 30 Zn zinc 65 48 Cd cadmium 112 80 g mercury 201 112 Cn copernicium 114 Fl flerovium 116 Lv livermorium 7 N nitrogen 14 15 P phosphorus 31 33 As arsenic 75 51 Sb antimony 122 83 Bi bismuth 209 8 O oxygen 16 16 S sulfur 32 34 Se selenium 79 52 Te tellurium 128 84 Po polonium 9 F fluorine 19 17 Cl chlorine 35.5 35 Br bromine 80 53 I iodine 127 85 At astatine 10 Ne neon 20 18 Ar argon 40 36 Kr krypton 84 54 Xe xenon 131 86 Rn radon 21 Sc scandium 45 39 Y yttrium 89 5771 lanthanoids 89103 actinoids 57 La lanthanum 139 89 Ac lanthanoids actinoids The volume of one mole of any gas is 24 dm 3 at room temperature and pressure (r.t.p.). actinium 58 Ce cerium 140 90 Th thorium 232 59 Pr praseodymium 141 91 Pa protactinium 231 60 Nd neodymium 144 92 U uranium 238 61 Pm promethium 93 Np neptunium 62 Sm samarium 150 94 Pu plutonium 63 Eu europium 152 95 Am americium 64 Gd gadolinium 157 96 Cm curium 65 Tb terbium 159 97 Bk berkelium 66 Dy dysprosium 163 98 Cf californium 67 o holmium 165 99 Es einsteinium 68 Er erbium 167 100 Fm fermium 69 Tm thulium 169 101 Md mendelevium 70 Yb ytterbium 173 102 No nobelium 71 Lu lutetium 175 103 Lr lawrencium