.,.ft~"""'" Adhesives National Starch and Chemical Company 10 Finderne Avenue P.O. Box 6500 Bridgewater, New Jersey 08807-0500 908-685-5000 CVfY/11~JC, CI}T/j~YST 'tlel7 c~ BONDMASTER PRODUCTS PRODUCT DATA: CATALYST 42-2301 ACID CATALYST CATAL YST 42-2301 should be used to catalyze KOR-LOK and DURO-LOK products where a green-blue glue line would be objectionable. APPLICATION Add 3% by weight to products in the KOR-LOK series or 5% by weight to products in the DURO-LOK series prior to use. Stir adhesive during catalyst addition and continue agitation for at least 5 minutes to assure uniform mixture. PRECAUTIONS This catalyst is acidic in nature. HANDLE WITH CARE! Protect eyes from catalyst. Should skin contact occur, wash the area immediately with water. In case of eye contact, flush with a large amount of water. Call physician immediately. Store catalyst in a cool place. ISSUE: 05/19/95SD Supersedes 07/22/93 SD TYPICAL PROPERTIES APPEARANCE Straw color VISCOSITY Water thin SOLIDS Approx.28% WEIGHT/GALLON Approx.1O.71bs. I!!! Less than 1 READ PRECAUTIONS BEFORE USING PRODUCT The information given and the recommendalions made herein are based on our research and are believed to be acrurate but no guarantee of their accuracy is made_ In every case we urge and recommend that purchasers before using any product in full scale production make their own tests to determine to their own satisfaction whether the product is of acceptable quality and is suitable for their particular purposes under their own operating conditions No representative of ours has any authority to waive or change the foregoing provisions but. subject to such provisions. our engineers are available to assist purchasers in adapting our products to their needs and to the circumstances prevailing in their business. Nothing contained herein shall be construed to imply the nonexistence of any relevant patents or to constitute a permission. inducement or recommendation to practice any invention covered by any patent. without the autihority from the owner of this patent. We also expect purchasers to use our products in accordance with the guiding principles of the Chemical Manufacturers Association's Responsible Care<!!> program.
f- ~ <~~ ~(>G '0/'.'7.Y s \v" G- t 1 NATIONAL STARCH AND CHEMICAL Stsrch & Chem/tt11 A member of the lei Group *** MATERIAL SAFETY DATA SHEET *** 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME CA TAL YST 42-2300 Manufacturer National Starch & Chemical Company Adhesives Division P.O. Box 6500, 10 Finderne Avenue Bridgewater, NJ 08807 USA EMERGENCY PHONES: MEDICAL: 866-359-5657 (Health & Safety Call Center-24 hours) TRANSPORT: CHEMTREC: 800-424-9300 (24 hours) CHEMTREC International: 703-527-3887 (call collect) Corporate Emergency Phone: 908-685-5100 (24 hours) MSDS Requests/Customer Service: See phone numbers in Section 16 SYNONYMS catalyst for DURO-LOK and KOR-LOk 2. COMPOSITION/INFORMATION ON INGREDIENTS CHEMICAL F AMIL Y Inorganic Metallic Compound CAS NUMBER 13548-38-4 7697-37-2 CONCENTRATION (%) <45 <5 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW DANGER! CORROSIVE. CAUSES SEVERE BURNS TO SKIN. CORROSIVE. CAUSES SEVERE OR PERMANENT DAMAGE TO EYES. CORROSIVE IF SWALLOWED. Blue Liquid Pungent odor EYE SKIN CONTACT INHALATION Extremely severe irritant/corrosive. May cause severe bums which could lead to permanent damage or total loss of vision. Corrosive, causes permanent skin dam"age. Unlikely to be hazardous by inhalation because of the low vapor pressure of the material at ambient temperature. PAGE I OF 6
INGESTION Corrosive to mouth, throat and stomach. 4 FIRST-AID MEASURES EYE SKIN CONTACT INHALATION INGESTION Immediately irrigate with eyewash solution or clean water, holding the eyelids apart, for at least 10 minutes. Obtain immediate medical attention. Immediately flush with large amounts of water; use soap if available. Remove contaminated clothing, including shoes, after flushing has begun. Obtain immediate medical attention. Using proper respiratory protection, immediately remove the affected victim from exposure. Administer artificial respiration if breathing has stopped. Keep at rest. Call for proper medical attention. If swallowed, DO NOT induce vomiting. Keep at rest. Get prompt medical attention. 5. FIREFIGHTING MEASURES AUTOIGNITION FLASH POINT EXTINGUISHING MEDIA SPECIAL FIREFIGHTING PROCEDURES FIRE & EXPLOSION HAZARDS LOWER EXPLOSION LIMIT (%) UPPER EXPLOSION LIMIT (%) FLAMMABILITY HAZARD CLASS Not available C02 Fire fighters should be equipped with self-contained breathing apparatus to protect against potentially toxic and irritating fumes. Combustion will evolve toxic and irritant vapors. o = Insignificant. 6 ACCIDENTAL RELEASE MEASURES SPILL AND LEAK PROCEDURES Absorb spillages onto sand, earth or any suitable absorbent material. Sweep up and shovel into waste drums. Wash the spillage area with water. Washings must be prevented from entering surface water drains. Disposal should be in accordance with local, state or national legislation. For safety and environmental precautions, please review entire Material Safety Data Sheet for necessary information. 7 HANDJ.JNG AND STORAGE STORAGE TEMPERATURE HANDLING/STORAGE SENSITIVITY TO STATIC ELECTRICITY SENSITIVITY TO MECHANICAL IMPACT 40-100 OF Store in a cool, dry area away from heat, sparks or fire. No No PAGE 2 OF 6
8. EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE LIMITS ACGIH-TWA: 0.5 mglm3 OSHA-PEL: 0.5 mglm3 ACGIH-TWA: 2 ppm ACGIH-STEL: 4 ppm OSHA-PEL: 2 ppm OSHA-STEL: 4 ppm VENTILA TION REQUIREMENTS General. EYE PROTECTION REQUIREMENTS Employee must wear splash-proof or dust-resistant safety goggles and a faceshield to prevent contact with this substance. GLOVE REQUIREMENTS CLOTHING REQUIREMENTS CHANGE/REMOV AL OF CLOTHING WASH REQUIREMENTS RESPIRATOR REQUIREMENTS Gloves should be worn because oflow ph. Employee must wear appropriate protective plothing and equipment to prevent any possibility of skin contact with thi$. substance. Remove contaminated clothing and launder before reuse. Wash before eating, drinking, or using toilet facilities. No respiratory protection is recommended while working with this material. However, if operating conditions create high vapor or mist concentration, use of an approved respirator is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES PURE SUBSTANCE OR MIXTURE PHYSICAL FORM COLOR ODOR ODOR THRESHOLD PH AS IS ph IN (1%) SOLUTION OXIDIZING PROPERTIES BOILING POINT MEL TING/FREEZING POINT SOLUBILITY IN WATER PARTITION COEFFICIENT (n-octanollwater) SPECIFIC GRAVITY (WATER=l) BULK DENSITY EVAPORATION RATE V APOR PRESSURE (mmhg) VAPOR DENSITY (air = 1) VOLATILES AUTOIGNITION FLASH POINT Mixture Liquid Blue Pungent Not available < 2 Not tested Approximately 212 Soluble 1.45 121b/gal 1 (Water = 1) 17.5 @20 C 0.62 60 %/wt Not available 10. STABILITY AND REACTIVITY STABILITY MATERIALS TO A VOID Stable Strong bases PAGE 3 OF 6
2I-March-2004 REACTIVITY HAZARD CLASS 2 = Reactive material. HAZARDOUS DECOMPOSITION PRODUCTS This product does not undergo spontaneous decomposition. Typical combustion products are carbon monoxide, carbon dioxide, nitrogen and water. REACTIVITY This material is highly acidic. 11. TOXICOLOGICAL INFORMATION ROUTE OF ENTRY Skin Contact; Eye Contact CHRONIC (LONG TERM) EFFECTS OF EXPOSURE EFFECTS OF CHRONIC EXPOSURE Although this product has not been tested for chronic effects it is judged as having a low order of toxicity based on component information. Use of good industrial hygiene practices is recommended. TARGET ORGANS Skin; Eyes; Lungs CARCINOGEN No. ORAL TOXICITY NOTES ON ORAL TOXICITY Corrosive to mouth, throat and stomach. Corrosive to mouth, throat and stomach. DERMAL TOXICITY NOTES ON DERMAL TOXICITY Corrosive, causes permanent skin damage. Corrosive, causes permanent skin damage. INHALATION TOXICITY NOTES ON INHALATION TOXICITY Inhalation of dust or vapor may cause severe irritation to the nasal passages and/or the respiratory system. Inhalation LC50 (0.5hr): Rat Inhalation of dust or vapor may cause severe 334 ppm irritation to the nasal passages and/or the respiratory system. NOTES ON EYE IRRITATION Extremely severe irritant/corrosive. May cause severe burns which could lead to permanent damage or total loss of vision. PAGE 40F6
Extremely severe irritant/corrosive. May cause severe burns which could lead to permanent damage or total loss of vision. 12. ECOLOGICAL INFORMATION POTENTIAL TO BIOACCUMULATE AQUATIC TOXICITY Unknown. None Established 13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHODS Disposal should be in accordance with local, state or national legislation. EMPTY CONTAINER WARNINGS Empty containers may contain product residue; follow MSDS and label warnings even after they have been emptied. 14. TRANSPORTATION INFORMATION This section provided for general information only. FOR NON-BULK SHIPMENTS. FOR MORE COMPLETE TRANSPORTATION REGULATORY INFORMATION PLEASE REFER TO THE SHIPPING DOCUMENTS ACCOMPANYING THE SHIPMENT OF THIS PRODUCT. DOT CLASSIFICATION PROPER SHIPPING NAME TECHNICAL NAME HAZARD CLASS U.N. NUMBER PACKING GROUP CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (CHROMIC NITRATE SOLUTION, NITRIC ACID) 8 UN3264 II The information provided herein may not include the impact of additional regulatory requirements (eg, for materials meeting the definition of a hazardous waste under RCRA, hazardous substances under CERCLA, and/of marine pollutants under CWA or other similar federal, state or local laws) or any associated exceptions or exemptions under regulations applicable to the transport of this material. 15. REGULATORY INFORMATION USA TSCA All components are on the TSCA inventory. SARAITITLE III Chromium CAS NUMBER 7440-47-3 7697-37-2 CONCENTRATION (%) 44.00 5.00 PAGE 5 OF 6
16. OTHER INFORMATION MSDS DATE FOR INFORMATION CONTACT: 20-February-2002 National Starch & Chemical Company Adhesive Division Product Information: Customer Relations: 1-888-480-6885 ADDITIONAL INFORMATION: The information given and the recommendations made herein apply to our product(s) alone and are not combined with other product(s). Such are based on our research and on data from other reliable sources and are believed to be accurate. No guaranty of accuracy is made. It is the purchaser's responsibility before using any product to verify this data under their own operating conditions and to determine whether the product is suitable for their purposes. PAGE 60F6