DIN SEAMLESS CIRCULAR TUBES MADE FROM STEELS WITH LOW TEMPERATURE SERVICE

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DIN 17173-85 SEAMLESS CIRCULAR TUBES MADE FROM STEELS WITH LOW TEMPERATURE SERVICE The subclauses marked with a single dot give specifications which are to be agreed upon at the time of ordering. The subclauses marked with a two dots give specifications which optional and may be agreed upon at the time of ordering. 1. Field of application 1.1 This standard applies to seamless circular tubes made from carbon and alloy steels with low temperature toughness, as listed in table 1, for low temperature applications. These tubes are predominantly used in the construction of chemical plant vessels, pipework and for general mechanical engineering purposes. Note. Seamless fine grain steel tubes (see DIN 17179) and seamless stainless austenitic steel tubes (see DIN 178) are also used for low temperature applications. 1.2 If tubes complying with the requirements of this standard are intended for use in installations subject to regular inspection, the specifications in the relevant codes of practice shall be taken into consideration, e.g. the Technische Regeln Druckbehalter (Technical rules for pressure vessels). Merkblatter) (Instruction sheets of the pressure vessels Study Grop) (AD Instruction sheets). The same applies for other fields of application for which additional specifications exist. Grade Mfg. Process Chemical composition (%) C Si Mn P S Ni Cr Mo Others TStN S 0.17Max 0.Max 0.Max 0.0Max 0.025Max - - - Al 0.020Min TStV S 0.17Max 0.Max 0.~0.80 0.0Max 0.025Max - - - Al 0.020Min 26CrMo4 S 0.22~0.29 0.Max 0.~1. 0.0Max 0.025Max - 0.90~1.20 - - 11MnNi53 S 0.14Max 0.Max 0.85~1. 0.0Max 0.025Max 0.~0.80 - - Al 0.020Min 13MnNi63 S 0.18Max 0.Max 0.85~1. 0.0Max 0.025Max 0.~0.85 - - - 10Ni14 S 0.15Max 0.Max 0.~0.80 0.025Max 0.020Max 3.25~3.75 - - - 12Ni19 S 0.15Max 0.Max 0.~0.80 0.025Max 0.020Max 4.~5. - - - X8Ni19 S 0.10Max 0.Max 0.~0.80 0.025Max 0.025Max 8.00~10.00 - - - Grade Material Tensile Test MPa or N/mm 2 number Min Yield point Tensile Strength Remarks (Similar to JIS) TStN 1.08 225 3~4 - TStV 1.7219 t 25mmMax2 25mm<t mmmax 2 3~490 -

26CrMo4 26CrMo4 t 25mmMax4 25mm<t mmmax 420 5~7 - t 25mmMax 285 11MnNi53 1.6212 13MnNi63 1.6217 10Ni14 1.5837 12Ni19 1.5680 X8Ni19 1.5662 13mm<t 25mmMax 5 25mm<t mmmax 2 t 13mmMax 5 13mm<t 25mmMax 3 25mm<t mmmax 3 t 25mmMax 3 25mm<t mmmax 3 t 25mmMax 390 25mm<t mmmax 380 t 25mmMax 490 25mm<t mmmax 480 410~5-490~610-4~6 (STBL46) 510~710-6~8 (STBL) JIS and Corresponding Foreign s JIS ASTM BS DIN NF ISO Index G3464 STBL380 C A334 Gr1 C 33 HFS410LT C 17173 FONi14 Ni 24/2 TS6 C C014 (STBL39) " CFS410LT C 17174 X8Ni9 Ni " ERW410LT C " CEW410LT C STBL4 Ni A334 Gr3 Ni 33 HF3LT100 Ni A49-2 TU10N14 Ni 24/2 TS43 Ni (STBL46) " CF3LT100 Ni A49-213 TU10N14 Ni STBL690 Ni A334 Gr8 Ni 33 HFS9LT196 Ni A49-2 TUZ6N9 Ni 24/2 TS Ni (STBL) " CFS9LT196 Ni A49-215 TUZ6N9 Ni

Table 1. Chemical composition (cast analysis) of steels with low temperature toughness for seamless tubes. Steel grade % by mass Symbol Material number C Si Mn P S Al min Cr Mo Nb Ni V TTSt N TTSt V 1.08 0.17 0. min 0. 0.0 0.025 0.020 - - - - - 26 CrMo 4 0.7219 0.22 to 0.29 0. 0. to 0.80 0.0 0.025-0.90 to 1.20 0.15 to 0. - - - 11 MnNi 5 3 1.6212 0.14 0. 0. to 1. 0.0 0.025 0.020 - - 0.05 0. 1) to 0.80 0.05 13 MnNi 6 3 1.6217 0.18 0. 0.85 to 1. 0.0 0.025 0.020 - - 0.05 0. 1) to 0.85 0.05 10 Ni 14 1.5837 0.15 0. 0. to 0.80 0.025 0.020 - - - - 3.25 to 3.75 0.05 12 Ni 19 1.80 0.15 0. 0. to 0.80 0.025 0.020 - - - - 4. to 5. 0.05 X 8 Ni 9 1.5662 0.10 0. 0. to 0.80 0.025 0.020 - - 0.10-8.00 to 10.00 0.05 1) The lower fimit value for the nickel content may be reduced to not less than 0.15% by mass for tubes with wall thicknesses not exceeding 10mm Table 2. Permissible deviations between the results of the chemical composition determined by the product analysis and the limiting values for the cast analysis. Element Limiting values for the cast analysis as specified in table 1 % by mass Permissible deviations between the results of product analysis and the limiting values for the cast analysis 1) % by mass C 0.29 0.02 Si Mn 0. > 0. 0. 0.80 > 0.80 1. 0.03 0.05 0.06 0.10 P 0.0 0.005 S 0.025 0.005 Al 0.020 0.005 Cr 1.20 0.10 Ni 0.85 > 0.85 3.75 0.05 0.07

Mo > 3.75 5. 8.00 10.00 0.10 > 0.10 0. 0.10 0.15 0.01 0.04 Nb 0.05 0.01 V 0.05 0.01 1) If several product analyses are carried out for a single cast and if these analyses show contents for a single element outside the range specified for the cast analysis, this for multiple annealing shall be 1 minutes. An attempt should be made to keep to the lower limit of the temperature range where the holding time exceeds 90 minutes. Table 3. Mechanical properties of the tubes in the as delivered condition 1) Steel grade Symbol Material number Heat treatment condition 2) Wall thickness s mm Upper yield stress N/ mm2 mm Tensile strength N/ mm2 Elongation after fracture (Lo = 5 do) longitudinal transverse % min TTSt N 1.08 N s 10 225 3 to 3 25 23 TTSt V 1.06 V 25 <s 2 2 3 to 490 23 21 28CrMo 4 1.7219 V 25 < s 4 420 5 to 7 18 16 s 13 285 11 MnNi 5 3 1.6212 N 3) 13 < 5 410 to 5 24 22 25 < s 2 s 13 5 13 MnNi 8 3 1.6217 N 3) 13 < 3 490 to 610 22 20 25 < s 3 10 Ni 14 1.5637 V 4) 25 < s 3 3 4 to 6 20 18 12 Ni 19 1.5680 V 4) 25 < s 390 380 510 to 710 19 17

X 8 Ni 9 1.5662 V 25 < s 490 480 6 to 8 18 16 1) The values for the mechanical properties of tubes with wall thicknesses greater than mm, with the exception of steels TTSt N and TTSt V, shall be agreed at the time of ordering. 2) N = normalized; V = quenched and tempered. 3) Tempering can, occasionally, be necessary after normalizing. In this case, the manufacturer shall inform the purchaser, and shall indicate to him the tempering temperature. 4) If this is permitted by the dimensions, normalizing (N), with additional tempering as necessary, may be carried out at the manufacturer's discretion instead of quenching and tempering (V). The purchaser shall be informed if this is the case. Table 4. Requirements relating to the impact energy in the impact test on ISO V-notch test pieces 1), 2) Steel grade Wall thickness Location of test Minimum values of impact energy. Symbol Material number s mm pieces relative to tube axis -196-120 -110-100 -90 - - - -20 +20 TTSt N 1.06 s 10 TTSt V 1.06 25 <s 26 CrMo 4 1.7219 s 11 MnNi 5 3 13 MnNi 6 3 1.6212 1.6217 s 10 Ni 14 1.5637 25 <s

12 Ni 19 1.5680 25 < s X 8 Ni 9 1.5662 s 1) The values for tubes with wall thicknesses exceeding mm, with the exception of steels TTSt N and TTSt V, shall be agreed at the time of ordering. 2) The impact energy values shall each determined for the lowest test temperature stated for the steel grade concerned; the values of impact energy at higher test temperatures shall be considered to have been demonstrated by the same determination. 3) Average value from three test pieces, only one individual value may fall short of the specified minimum value by a imum of % (see also subclause 6.4.2). 4) The values given in subclause 6.5.2 shall apply for wall thicknesses less than 10mmmm. 5) To be determined only by agreement. Table 5. Types of length and permissible deviations in length. Type of length Permissible deviations in length, in mm Manufacturing length 1) 1) Specified length ± 0 Exact lengths up to 6m over 6m up to 12m over 12m +10 0 +15 0 By agreement. 1) The products are supplied in the manufacturing lengths occurring in production. The lengths differ according to the diameter. wall thickness and manufacturer's works and shall be agreed at the time of ordering. Table 6. Permissible deviations in outside diameter. Outside diameter da mm Permissible deviation in diameter Tube barrel and tube ends At tube ends, subject to particular agreement 1)

da 100 ±1% da (values up to ± 0.5mm are permitted in all cases). ± 0.4mm 100 < da 200 ± % da ± 0.5% da 200 < da ± 1% da ± 0.6% da 2) 1) Over a length of about 100mm from the tube ends. 2) Subject to agreement at the time of ordering, the permissible deviation may also be referred to the inside diameter, in which case the permissible deviation in wall thickness is to be taken into account. Permissible deviation in wall thickness for outside diameters da Table 7. Permissible deviations in wall thickness da 1mm 1mm <da 320mm and wall thicknesses s 320nn <da 6mm 2*sn 2*sn < s 4*sn > 4*sn 0.05da 0.05da <s 0.11da > 0.11 da 0.05da 0.05da< s da 0.09da > 0.09da +15% -10% +12.5% -10% ±9% +17.5% -12.5% ± 12.5% ±110% +22.5% -12.5% +15% -12.5% +12.5% -10% Note. Sn is the standard wall thickness as specified in DIN 2448. Subject to agreement, the tubes may be supplied with the joint faces prepared. In this case, the form of joint faces shall be specified. 5.10.5. Masses per unit length and permissible deviations The values of masses per unit length of tubes are specified in DIN 2448. The following deviations from these values are permitted: +12 % for a single tube; -8 +10 % for a batch of tubes not less than 10t by mass. -5

JIS and Corresponding Foreign s JIS ASTM BS DIN NF ISO Index G3464 STBL380 C A334 Gr1 C 33 HFS410LT C 17173 FONi14 Ni 24/2 TS6 C C014 (STBL39) " CFS410LT C 17174 X8Ni9 Ni " ERW410LT C " CEW410LT C STBL4 Ni A334 Gr3 Ni 33 HF3LT100 Ni A49-2 TU10N14 Ni 24/2 TS43 Ni (STBL46) " CF3LT100 Ni A49-213 TU10N14 Ni STBL690 Ni A334 Gr8 Ni 33 HFS9LT196 Ni A49-2 TUZ6N9 Ni 24/2 TS Ni (STBL) " CFS9LT196 Ni A49-215 TUZ6N9 Ni