TECHNICAL POLYMERS. An extreme world needs extreme materials

TECHNICAL POLYMERS An extreme world needs extreme materials

LET S RUN TOGETHER Let's run together. Like the runner, Arkema is in forward motion, determined, racing to develop the materials and innovations needed to meet tomorrow's challenges. Our legacy, developed over more than 50 years, includes materials used in some of the world's most hostile and demanding environments. Today our advanced materials reliably endure some of the industry's most extreme conditions - constantly in motion and constantly under attack. It s an extreme world. 1 An extreme world needs extreme materials.

OUR DRIVERS, BELIEFS, VISION BIOBASED LIGHTWEIGHT DURABILITY, RESISTANCE & LONGEVITY INNOVATION WITH VISION......AND WITH PARTNERS GLOBAL STRONG BRANDS DIFFERENTIATED PRODUCTS INTEGRATED With a 50-year legacy of solving some of the world s most extreme material challenges, Arkema s Technical Polymers continue to evolve to meet the challenges of a world that is becoming even more extreme. Our three flagship brand families, Kynar, Pebax and Rilsan, represent some of the world s highest performing polymers across an array of diverse markets, each of which demands durability, longevity and consistency of supply across the globe. We are committed to the safety of our customers, our employees, and the global community in which we operate. We are proud to be among the world s leaders in biobased and lightweight high performance polymers as well as our unmatched global integrated manufacturing and R&D capabilities. We aim to serve our customers locally while supplying them globally. Most importantly, we want to innovate with a common vision and a common mission, in collaboration with our customers. 2

MARKETS AND CUSTOMERS AT THE HEART OF OUR BUSINESS AUTOMOTIVE & TRANSPORTATION CONSTRUCTION (COATINGS) COATINGS & ADHESIVES CHEMICAL INDUSTRY & GENERAL INDUSTRIAL CONSUMER GOODS & HEALTHCARE ELECTRIC & ELECTRONICS WATER & ENVIRONMENT ENERGY OIL & GAS RENEWABLE ENERGIES Sharing a common mission with our customers allows us to move faster and to achieve greater results. Early engagement is key. We have a highly trained global technical team ready to serve you. We can help you to select the best solution, or to jointly develop that solution. We can share our experiences, our knowledge base, and our expertise. With manufacturing, R&D, and commercial support teams in all three major regions, we are well positioned to serve you locally while supplying you globally. Together, we can achieve great things. Kynar Pebax Rilsan 3

AN EXTREME WORLD NEEDS EXTREME MATERIALS AUTOMOTIVE EXTREME LIGHTWEIGHT & EMISSIONS REDUCTION OPTIONALLY BIOBASED SUBSEA EXTREME CHEMICAL & FLEX/FATIGUE RESISTANCE SPORTS EXTREME LIGHTWEIGHT ENERGY RETURN POWDER COATINGS EXTREME TOUGHNESS, ABRASION RESISTANCE CHEMICAL PROCESSING INDUSTRY EXTREME PURITY & WHITENESS CONSTRUCTION COATINGS EXTREME DURABILITY LITHIUM ION EXTREME ELECTROCHEMICAL STABILITY SOLAR EXTREME WEATHER RESISTANCE We have built our reputation upon a proven legacy of solving some of the planet s most extreme material challenges. We are leaders in many markets that require such extreme performance. Coatings that resist the long-term attack of sunlight Pipes and Fittings that resist harsh and corrosive chemicals Solar panels designed to last for decades in punishing environments Lithium ion batteries that contain aggressive electrochemical reactions Coatings that durably protect spline shafts, gear cogs, and machine components Lighter, faster, tougher sports shoes for athletes who set world records Automotive tubing, fittings, and components to replace metal and save weight Water filtration membranes that resist fouling and retain high throughput Additives that permanently impart antistatic properties and are compatible with a broad range of host resins 4

INNOVATIVE SOLUTIONS THREE FLAGSHIP BRAND FAMILIES Kynar Pebax Rilsan Polyvinylidene Fluoride (PVDF) resins and copolymers designed for extreme inertness in harsh environments, flame & smoke properties, durability, and ease of processing. For many years, Kynar fluoropolymers have been the de facto solution for several of the world s most challenging applications, such as binders for lithium ion batteries, flame resistant wire and cable jacketing, inert piping and fittings for corrosive chemicals, backsheets for long life solar panels, and for skyscraper coatings famous across the globe. Thermoplastic elastomers (TPE) designed for an outstanding combination of lightweight and energy return. Biobased grades available Pebax thermoplastic elastomers offer a highly desirable balance of low hysteresis (energy loss) and long life. They are famous in the sports world for propelling serious athletes to world records and gold medals in cleated shoes, running shoes, many types of sports equipment, skis and ski boots. These unique resins are also widely used in the medical catheter market due to their excellent torque translational efficiency, and ease of use. High performance polyamide resins, powder coatings, and additives that deliver toughness, flexibility, and chemical resistance. Biobased grades available Four sub-families of pellets and powders designed for a wide range of markets and applications. 5

INNOVATIVE SOLUTIONS THE RILSAN POLYAMIDE FAMILY Rilsan ultra-high performance PA 11 resins, alloys, and ready-to-use powder coatings. Tremendous toughness and durability in extreme environments and high temperatures. Excellent for 3D printing (additive manufacturing) of highly durable parts. PA 10.10 and PA 6.10 also available. Biobased Orgasol PA powder additives have tightly controlled particle size distributions. Their characteristic spherical shape offers extreme surface protection and appearance modification ( soft touch, matte finish, and fine texture), and controlled absorption/ release. Rilsamid PA 12 and 6.12 high performance polyamide resins designed for a combination of flexibility, toughness and chemical resistance. Orgalloy low permeability PE/PA alloys. Platamid high efficiency plasticizerfree thermoplastic hot melt adhesives for both woven and non-woven substrates. Also soluble in select solvents for highly effective barrier coatings. 6

TYPICAL PERFORMANCE PROPERTIES Properties of Technical Polymers grades Kynar Kynar Flex PVDF Pebax TPE Rilsan Polyamides Density (g/cm 3 ) 1.76-1.82 1.01~1.03 1.02-1.05 Tm o C 90 ~170 134 ~175 170-260 Tensile modulus MPa 241~2310 200 ~ 1400 Tensile elongation % 20 ~1000 >750 ~ >300 >200 ~ >300 Strength at break MPa 14 ~ 55 32 ~ 55 40 ~ 55 Flexural modulus MPa 76 ~ 6895 12 ~ 850 150-1800 Charpy impact (RT, notched) 60 ~ NB 15 ~ NB NB Charpy impact (-30 o C, notched) 5 ~10 10 ~ NB 5 ~ NB Chemical Resistance Strong acid Strong alkaline Oil Alcohol Water X X X Very resistant Somewhat resistant X Not resistant Flexural Modulus vs Melt Temperature 7

GLOBAL MANUFACTURING AND R&D Arkema continues its commitment to large scale investments in world class manufacturing and research centers. Integrated Manufacturing We want to be close to our customers and we have a large team of technical experts ready to engage in joint development projects, co-marketing programs, and exploratory missions. Castor Oil Polyamide Resin Fluorspar Fluoropolymer Changshu R&D center in China 8

TODAY S VEHICLES HAVE EVOLVED AUTOMOTIVE & TRANSPORTATION There are over a billion cars on the road today. Within the next couple of decades the number is expected to double! FUEL, LIQUID MANAGEMENT HEAVY TRUCK AIR BRAKE TUBING METAL COATING (INCLUDING POWDER COATINGS) INTERIOR, EXTERIOR PARTS (AIR BAGS, TEXTILE ADHESIVES, ANTISTATICS) CONNECTORS, FITTINGS, COMPONENTS EMISSION CONTROL SYSTEMS ALTERNATIVE FUEL SYSTEMS (LNG, CNG, H2) ELECTRICAL, ELECTRONIC COMPONENTS (LI ION BATTERIES, CABLES) We offer a wide range of solutions to make vehicles lighter, more fuel efficient, lower emitting, and longer lasting. Replacing metal and rubber is a common theme for our developments, and our biobased options are among the world s leading technologies when it comes to a lower carbon footprint. From heavy truck airbrake tubing to low-permeation multi-layer fuel lines, Arkema offers a wide range of enabling resins, tie layer alloys and patented combinations. Our high heat resistant flexible polyamide offerings make us an excellent partner for the extreme challenges of under-the-hood design. Speak to us today about our enormous range of solutions for the extreme challenges of today s market. We also offer complementary solutions, such as extreme durability powder coatings and high performance flame and smoke resistant cable 9

A HEALTHY LIFE, A BEAUTIFUL LIFE SPORTS, OPTICS, CONSUMER GOODS & HEALTHCARE SPORTS SHOES - CLEATED & NON CLEATED SPORTS APPAREL & CONNECTED FITNESS SPORTS EQUIPMENT PEBAX POWERED has become a world famous sports brand synonymous with premium performance and ultra light weight. SKIS & SKI BOOTS OPTICS, EYEWARE HOME APPLIANCE COMPONENTS MEDICAL CATHETER & MASK TUBES, BAGS, BREATHABLE GOWNS & WOUND CARE SENSORIAL ADDITIVES FOR COSMETIC FORMULATIONS Arkema offers several Pebax, Rilsan and Kynar grades for medical applications 1. Catheters, tubes, bags, gowns are among the more popular uses. Athletes across the globe continue to stretch their limits with Pebax Powered shoes, boots, skis, and ski boots. World records along with the definition of what can be achieved are being re-written day after day. Pebax resins have become the gold standard for lightweight and outstanding energy return regardless of temperature. And for those athletes who want to commit themselves to a lower carbon footprint, biobased Pebax Rnew grades offer the same premium performance while being manufactured in part from oils derived from the castor bean plant. Similarly, our biobased Rilsan Clear resins offer extreme lightweight and resistance properties for the optics/eyewear market. For wearable and/or connected fitness & health devices, Pebax resins again shine due to their outstanding lightness and flexural fatigue resistance. For even more durability, chemical and UV resistance, consider Kynar flexible fluoropolymers. 1 Visit ark.ma/medpolicy to see our medical device policy. 10

CLEVER CHOICES FOR SMART DEVICES ELECTRICAL & ELECTRONIC SOLUTIONS There are more smart devices than there are people in the world. The number of wearable devices on the planet is expected to triple in the next few years driven mainly by new applications in healthcare, military, homeland security and sports. Globally, 30,000 patents have been filed between 2012 and 2015. CABLES - AUTOMOTIVE, MILITARY, ELECTRONICS, PLENUM, SPECIALTY, HFFR, INDUSTRIAL STRUCTURAL & FLEXIBLE COMPONENTS FOR SMART DEVICES PERMANENT ANTISTATIC ADDITIVES DURABLE COMPONENTS FOR WEARABLE DEVICES HOT MELT ADHESIVES FOR CIRCUITRY The rapid development of electronic devices is further accelerated by breakthroughs in big data, cloud computing, and materials science. Designers ask for materials that do things that until recently, seemed impossible. They look to Pebax resins - the ultimate "polymers in motion" - for an outstanding combination of flexural fatigue resistance and lightness. Designers also ask for outstanding durability resistance to long-term weathering, resistance to chemicals, and resistance to wear and tear. Few polymers in the world can match these requirements more than Kynar fluoropolymers. Their long legacy of performance in some of the world s most extreme and most corrosive environments makes them well suited for the new challenges of tomorrow s technology. Their ease of processing and their outstanding flame and smoke properties further exemplifies them as world leading candidates for the most demanding applications. The electronics market also has strong requirements for antistatic stability. An unwanted spark can destroy the most sensitive components. Designers look to our Pebax resins (specific grades) for permanent antistatic properties. With a wide portfolio of compatible resins and the ability to offer colors other than black, these additives can make a huge difference. 11

INDUSTRIAL STRENGTH SOLUTIONS CHEMICAL INDUSTRY & GENERAL INDUSTRIAL The Pebax elastomer family includes several grades that are breathable i.e. permeable to water vapor while acting as a permanent barrier to liquid water. They achieve this breathability by channeling water vapor on a molecular level through microscopic hydrophilic channels. CHEMICAL PROCESS INDUSTRY - STOCK SHAPES, TOWER PACKING, FITTINGS, PIPES FLUOROPOLYMER PROCESSING AIDS (PPA) TUBING & HOSE BREATHABLE FILMS FILAMENTS & YARNS ROTOMOLDING CONVEYOR BELTS & PULLEYS NYLON FILM MODIFICATION PERMANENT ANTISTATIC SOLUTIONS Design engineers in chemical plants demand it all ease of processing, extreme chemical resistance, ultra high purity, radiation resistance, and long service life. Kynar fluoropolymers have been specified in such applications throughout the world. Whether processing water or aggressive chemicals such as halogenated acids, Kynar resins offer an excellent solution for fittings, pipes, stock shapes, filaments, foams and many other forms. At the other end of the spectrum, Kynar resins are chosen as processing aids for the extrusion of high volume commodity resins. Their selective compatibility allows them to act as die lubricants, which enables higher throughput speeds and significantly higher quality. All three polymer families are used in an enormous variety of tubing and hose applications for food and beverage, fuel management, high purity water, chemical transport, and paint spray applicators. The list is almost endless. Our range of permanent antistatic solutions offers an uncompromised combination of static dissipation and broad compatibility with other resins. 12

ENERGIZING MATERIALS ENERGY / RENEWABLE ENERGIES Building on our reputation as a supplier of extreme materials for traditional energy production, Arkema is well positioned as a leading supplier of specialty materials for the next generation of energy creation, storage and delivery. SUBSEA UMBILICALS, RISERS, FLOWLINES PHOTOVOLTAIC BACKSHEET FILMS ANTI WEAR TAPES COMPOSITE PIPES LITHIUM ION BATTERY BINDERS, SEPARATOR COATINGS FUEL STORAGE (INCLUDING LNG, CNG, H2) GAS PIPE / FITTINGS Deep sea oil production has been a key traditional market for both Kynar fluoropolymers and Rilsan polyamide 11. Arkema is a global leader in the supply of technical polymers for the traditional and renewable energy markets. For several decades, we have been a global leader in subsea umbilicals, risers and flow lines. We are the unique manufacturer of both Kynar fluoropolymers and Rilsan polyamide 11 solutions for these extremely demanding applications. Arkema complements this subsea market with a robust portfolio of specialty polyamide resins designed for onshore gas distribution pipe and associated fittings, valves, and storage tanks. And we offer a wide array of polyamide and fluoropolymer grades suited for next generation composite pipes and multilayer tubing. Our patented Kynar film is a highly engineered multilayer construction with a characteristic 100% fluoropolymer outer layer. This film is world famous as a critical component of KPK solar backsheet constructions for outstanding exterior durability. Further, our Kynar HSV and Kynar LBG resins are among the world leaders in binders and separator coatings for lithium ion batteries. 13

COAT IT, STICK IT, 3D PRINT IT POWDER COATINGS, ADHESIVES, ADDITIVES AND 3D PRINTING INDUSTRIAL POWDER COATINGS SPHERICAL POWDER ADDITIVES FOR TEXTURING & SOFT TOUCH Rilsan Fine Powders are used in several state-of-theart 3D printing processes where they are favored for their improved strength and structural properties. TRANSFER PAPER INKS PLASTICIZER-FREE HOT MELT ADHESIVES 3D PRINTING / ADDITIVE MANUFACTURING OIL & GAS LINE COATINGS BARRIER COATINGS Arkema supplies a wide array of finished powder coatings based on our Rilsan biobased polymer range. These highly durable coatings may be applied by fluidized bed (dip), electrostatic spray or minicoat processes. Durability and wear resistance are generally superior to competitive polyester and epoxy coatings. Rilsan Fine Powders coatings offer tremendous resistance to acids, bases, salts, oils, hydraulic fluids, and an assortment of fuels. They are commonly used in the coating of spline shafts, automotive door rails, small parts, wire goods, racks, baskets (such as dishwasher), pipes and fittings for water handling, as well as undergarment clips and fasteners. Orgasol spherical powders are added to coatings to provide abrasion resistance, texture, and soft touch properties. They are also used as the primary vehicle for highly durable transfer paper inks. Our Platamid hot melt adhesive resins and powders offer tremendous laundry/dry cleaning resistance. They are widely used in garment interlining and automotive headliner adhesion. 14

50 YEARS OF PROOF CONSTRUCTION COATINGS FACTORY APPLIED COIL & EXTRUSION COATINGS FIELD APPLIED WATERBORNE DURABLE COATINGS DECORATIVE FILMS The Kynar 500 and Kynar Aquatec trademark licensed coatings have become synonymous with quality and high performance. For over 50 years, coatings based upon Kynar 500 PVDF resin have been protecting some of the world s most iconic buildings. From Chicago to Shanghai and beyond, these coatings have gained widespread recognition by the global community of architects and specifiers due in large part to Arkema s strict trademark licensing program. These coatings are factory applied by coil coating or spray and baked to form highly durable finishes that offer tremendous long-term resistance to the harmful rays of the sun. To complement Kynar 500 technology, Arkema also offers a range of aqueous emulsion resins under the Kynar Aquatec brand name. Waterborne coatings based upon Kynar Aquatec emulsions allow the formulation of low VOC field or factory applied coatings that offer essentially the equivalent weather resistance as Kynar 500 PVDF but without the need for baking. Typical applications include restoration coatings, cool roof coatings, and coatings applied on cementitious, plastic and wood substrates. 15

WATER FOR A THIRSTY WORLD WATER AND ENVIRONMENT MICROFILTRATION, ULTRAFILTRATION MEMBRANES For its breakthrough high durability and hydrophilic, Kynar PVDF for filtration membranes, Arkema was awarded the prestigious Pierre Potier Award. WATER PIPES, FITTINGS, TUBES, CONNECTORS Arkema is pleased to sponsor the Sail for Water team as they sail 35,000 miles around the world promoting universal access to clean drinking water. TOWER PACKING Almost 10% of the world s population does not have access to clean drinking water. www.water.org Continued urbanization and population growth is putting more and more pressure on municipal water treatment plants and their filtration membranes. Recently, Arkema was awarded the Pierre Potier award for innovation as a result of our pioneering work with functionalized PVDF resins for high throughput, fouling resistant, hydrophilic filtration membranes. Membranes made from this PVDF technology exhibit outstanding resistance to frequent and aggressive cleaning cycles while achieving a consistent macro-void free membrane structure using both the NIPS and TIPS process. Arkema offers an array of polymers for both hollow fiber and flat sheet filtration membranes designed for microfiltration and ultrafiltration. Arkema also has a long history of supplying high purity polymers for NSF compliant potable water applications. Our Kynar, Pebax and Rilsan resins also offer durable solutions for flexible hoses, appliance and beverage tubing as well as for water distribution and delivery. Tower packing, water fittings, and connectors are also common applications where tremendous long-life durability is required. 16

LET S RUN TOGETHER Flame & Smoke Properties Flexural Fatigue Resistance Chemical Resistance AN EXTREME WORLD NEEDS EXTREME Kynar Pebax Rilsan Lightweight Durability Toughness Energy Return Electrochemical Stability 17

SYNTHESIS & CHARACTERIZATION SCALEUP JOINT DEVELOPMENT MARKETING CO-BRANDING ADVERTISING APPLICATION DEVELOPMENT NEW MARKET EXPLORATION Supported by a global R&D team with local centers in each region, we have dedicated market managers and business development managers ready to engage with you today. Let us demonstrate to you our capabilities and our commitment. From joint development projects to co-branding and co-promotional efforts, we can achieve great things together. WHAT PROBLEMS CAN WE SOLVE FOR YOU? 18

A designer of materials and innovative solutions, Arkema shapes materials and creates new uses that accelerate customer performance. Our balanced business portfolio spans high-performance materials, industrial specialties and coating solutions. Our globally recognized brands are ranked among the leaders in the markets we serve. Reporting annual sales of 7.7 billion in 2015, we employ approximately 19,000 people worldwide and operate in close to 50 countries. We are committed to active engagement with all our stakeholders. Our research centers in North America, France and Asia concentrate on advances in biobased products, new energies, water management, electronic solutions, lightweight materials and design, home efficiency and insulation. For the latest, visit www.arkema.com NA-Marcom -jr- 9-2016 ADV# 2016-006 Disclaimer - Please consult Arkema s disclaimer regarding the use of Arkema s products on http://www.arkema.com/en/products/product-safety/disclaimer/index.html Kynar, Kynar Flex, Kynar 500, FSF, Kynar Aquatec, Pebax, Pebax Powered, Rilsan, Rilsamid, Orgasol, Orgalloy, and Platamid are registered trademarks of Arkema. KPK, It's an extreme world, The world is becoming more extreme and Let's run together are trademarks of Arkema. 2016 Arkema Inc. All rights reserved Websites: kynar.com kynaraquatec.com kynar500.com pebax.com rilsan.com rilsanfinepowders.com rilsamid.com orgalloy.com orgasolpowders.com orgasolcosmetics.com Contact information: Australia: +61 392 115 000 Japan: +81 3 5251 9900 Korea: +82 2 370367000 Singapore: +65 64199199 Taiwan: +886 2 27476979 India: +91 22 66137500 Arkema Investment Co. Ltd. 6/F, Block 1, Life Hub@Daning 1868 Gonghexin Road 200072 Shanghai China Tel: (+86) 21 6147 6888 Arkema Inc. 900 First Avenue King of Prussia, PA 19606 USA Tel: (+1) 610-205-7000 Arkema France 420 rue d Estienne d Orves 92705 Colombes Cedex France Tel: +33 (0)1 49 00 80 80