100% ACRYLIC POLYMER FOR INTERIOR AND EXTERIOR PAINTS SUMMARY acrylic emulsion has been designed for the formulation of environmentally friendly, low odour, interior wall paints. It has exceptional pigment binding capacity which permits formulation of flat wall paints at high pigment volume concentration while maintaining good scrub resistance. Thus, Primal SF-016 can be formulated economically in solvent free flat paints compared to competitive technologies. High PVC wall paints based on exhibit excellent wet colour rub, particularly observable in deep tones, which further distinguish it from other solvent free products and allow the formulation of superior coatings. In addition, allows the manufacture of interior sheen paints with good resistance to block and dirt pick up. Its all acrylic composition permits use in exterior coatings for mineral substrates such as masonry and on wood. Environmental Properties: Film formation without the need for coalescents and solvents Ammonia free Formaldehyde free Alkyl phenol ethoxylate free Low residual monomer levels and low odour Characteristics of the Product: High pigment binding capacity affording economical interior wall paints Excellent mechanical stability under high shear conditions Excellent scrub resistance Easy removal of stains Exterior durability Typical Physical Properties (Not to be used as specifications) Solids Content % 50-51 ph 8.0-9.0 Viscosity (Brookfield LV spindle 3 at 60rpm) <500 mpa.s Minimum Film Formation Temperature 1 C 50531 / 02-04-01 1
FORMULATIONS SOFT SHEEN PAINT Formulation SS-16-1 Ingredients Kilograms Litres Level Grind Orotan 963 (47%) Kathon LX 1.5% Nopco NXZ AMP-90 150.76 4.16 1.99 1.61 1.59 150.76 3.62 1.95 1.77 1.70 0.75% Disp Ti-Pure R-706 166.61 41.65 15.00% PVC Durcal 5 45.86 16.66 6.00% PVC Talc AT-1 48.32 16.66 6.00% PVC Acrysol RM-12W 1.98 1.90 82.03 80.09 15.00% PVC Grind Sub-Total 504.91 316.77 Letdown 357.84 339.51 Ammonia (28%) Acrysol DR-73 Acrysol DR-72 2.95 10.71 6.35 117.24 3.20 10.08 5.99 117.24 Total: 1000.00 792.78 42.00% PVC Levels without Additives: 40.989% Density 1.2614 56.063% Solvent 0.026% VOC 0.49 Dispersant 0.75% Levels with Additives: 43.370% 57.861% 50531 / 02-04-01 2
INTERIOR FLAT PAINT Formulation IF-16-1 Ingredients Kilograms Litres Level Grind Orotan 731N Natrosol 250 MHR (2.5%) Kathon LX 1.5% Tego Foamex 1495 KOH 1M Triton CF-10 82.69 17.49 124.91 0.69 2.78 2.08 1.39 82.69 15.83 124.91 0.68 2.78 1.90 1.32 1.00% Disp Tioxide TR-92 133.93 32.67 11.77% PVC Talc AT-1 53.71 18.52 6.67% PVC P-820 27.80 12.63 4.55% PVC Durcal 10 221.75 80.64 29.06% PVC Grind Sub-Total 669.22 374.56 Letdown 151.08 143.34 Acrysol RM-2020 Acrysol TT-615 128.16 16.02 1.04 34.47 125.14 15.37 0.98 34.47 23.45% PVC Total: 1000.00 693.86 75.50% PVC Levels without Additives: 40.989% Density 1.4412 56.063% Solvent 0.026% VOC 0.49 Dispersant 1.00% Levels with Additives: 43.370% 57.861% 50531 / 02-04-01 3
EXTERIOR FLAT MASONRY PAINT Formulation EM-16-50/OP Natrosol 250 MR One molar KOH Orotan 731 Byk 035 Ingredients Kilograms Litres Level 157.14 157.14 0.77 0.56 2.64 2.64 13.51 12.23 6.35 7.22 Acrysol SCT-275 43.86 42.51 108.01 104.77 15.00% PVC Tioxide TR-92 177.16 43.74 15.00% PVC Talc AT-1 41.48 15.36 5.27% PVC Durcal 5 39.49 14.35 4.92% PVC Calibrite SL 77.27 28.62 9.81% PVC Byk 035 Texanol Skane M-8 6.35 315.40 5.70 4.88 7.22 303.27 5.99 4.68 Total: 1000.01 750.29 50.00% PVC Levels without Additives: 38.900% Density 1.333 52.550% Solvent 0.009% VOC 29.8 g/l Dispersant 1.000% Coalescent 3.000% Levels with Additives: 42.100% 55.100% Other Measurements: ph KU ICI 8.5 >140 1.9-2.6 50531 / 02-04-01 4
INTERIOR SILK PAINT FORMULATION BASED ON PRIMAL SF-016 Formulation IS-16-1 Orotan 963 Byk 024 Aqueous ammonia Tioxide TR-92 Durcal 2 Kathon LX 1.5% Aqueous ammonia Acrysol DR-73 Acrysol DR-72 Ingredients Parts by Weight 49.8 3.0 1.6 0.9 154.7 21.0 59.8 391.4 63.2 1.7 2.0 231.0 8.0 12.0 Total: 1000.0 PROPERTIES Viscosity at equilibrium Gel strength 5 ICI cone and plate 1.2 Krebs Stormer (KU) 106 Brookfield (spindle 4, 6 rpm) 14.900 Syneresis No % 30.0 % 39.5 PVC % 30.0 Density 1.20 Scrub resistance (cycles at 50% weight loss) 2.525 50531 / 02-04-01 5
SOFT SHEEN PAINT FORMULATION BASED ON PRIMAL SF-016 Formulation SS-16-2 Ingredients Parts by Weight 80.0 Byk 024 1.2 Orotan 963 2.1 NaOH (20%) 9.6 Tioxide TR-92 188.5 Micro Mica 71.7 429.4 Kathon LX 1.5% 1.6 Densil P 1.0 75.7 Acrysol DR-73 16.5 122.7 Total: 1000.0 PROPERTIES Viscosity at equilibrium ICI cone and plate Krebs Stormer (KU) Brookfield (spindle 4, 6 rpm) 1.5 93 11.600 % 38.5 % 50.5 PVC % 35.8 Density 1.24 Gloss 60 23.5 Gloss 85 57.5 Scrub (abrasive - cycles at 50% weight loss) 3.370 50531 / 02-04-01 6
NOTES 50531 / 02-04-01 7
ROHM AND HAAS IN EUROPE AUSTRIA Rohm and Haas Austria Ges.m.b.H Diefenbachgasse 35-41 A-1150 Vienna Austria Tel: 43 (0) 1 894 17 600 Fax: 43 (0) 1 894 18 69 BENELUX Rohm and Haas Belgium N.V. Ankerrui 9 B-2000 Antwerpen Belgium Tel: 32 (0) 3 543 61 81 Fax: 32 (0) 3 541 77 69 SAFE HANDLING INFORMATION Rohm and Haas Company maintains comprehensive and up-to-date material safety data sheets (MSDS) on all of its products. These sheets contain pertinent information that you may need to protect your employees and customers against any known health or safety hazards associated with our products. Rohm and Haas Company recommends that you obtain copies of our material safety data sheets from your local Rohm and Haas representative on each of our products prior to its use in your facilities. We also suggest that you contact your supplier of other materials recommended for use with our products for appropriate health and safety precautions prior to their use. FRANCE Rohm and Haas France S.A.S. La Tour de Lyon 185, rue de Bercy F-75579 Paris Cedex 12 France Tel: 33 (0) 1 40 02 50 00 Fax: 33 (0) 1 43 45 28 19 ITALY Rohm and Haas Italia S.r.l. Via Trieste 25 I-22076 Mozzate (CO) Italy Tel: 39 0331 839111 Fax: 39 0331 821314 SWEDEN Rohm and Haas Nordiska A.B. Osterleden 165, Box 45 S-261 22 Landskrona Sweden Tel: 46 (0) 418 450 400 Fax: 46 (0) 418 450 499 ROHM AND HAAS EUROPEAN LABORATORIES 371, rue Ludwig van Beethoven Sophia Antipolis F-06565 Valbonne Cedex France Tel: 33 (0) 4 93 95 53 53 Fax: 33 (0) 4 93 65 30 16 GERMANY Rohm and Haas Deutschland GmbH In der Kron 4 D-60489 Frankfurt Germany Tel: 49 (0) 69 78 99 60 Fax: 49 (0) 69 789 53 56 SPAIN Rohm and Haas España S.a. Provenza 216, 3rd Floor E-08036 Barcelona Spain Tel: 34 (0) 9 3 227 19 00 Fax: 34 (0) 9 3 323 40 43 UNITED KINGDOM Rohm and Haas (UK) Limited Lennig House 2 Mason's Avenue Croydon CR9 3NB United Kingdom Tel: 44 (0) 20 8774 5300 Fax: 44 (0) 20 8774 5301 Rohm and Haas website: www.rohmhaas.com These suggestions and data are based on information we believe to be reliable. They are offered in good faith, but without guarantee, as conditions and methods of use of our products are beyond our control. We recommend that the prospective user determines the suitability of our materials and suggestions before adopting them on a commercial scale. Suggestions for uses of our products or the inclusion of descriptive material from patents and the citation of specific patents in this publication should not be understood as recommending the use of our products in violation of any patent or as permission or license to use any patents of the Rohm and Haas Company. Subsidiaries of Rohm and Haas Company, Philadelphia, USA Acrysol, Drycryl, Elastene, Fastrack, Maincote, Orotan, Paraloid, Primal, Ropaque, Rovace and Skane are trademarks of Rohm and Haas Company, Philadelphia, USA 2001 Rohm and Haas Company, Philadelphia, USA 50531 / 02-04-01 8