Sec MATERIAL SAFETY DATA SHEET tion 1 ISOVALERALDEHYDE 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MSDS Name: Synonyms: Company Identification: Isovaleraldehyde Isovaleric aldehyde; Isovaleral; Isopentaldehyde; Isoamyl aldehyde; 3-Methylbutanal;3-Methylbutyraldehyde. Sisco Research Laboratories Pvt. Ltd. Andheri (East), Mumbai 400 099. Tel : +91 22 2687 2601 Fax : +91 22 2687 8241 Website : www.srlchem.com 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name: % EINECS# 590-86-3 Isovaleraldehyde 98% 209-691-5 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Warning! Flammable liquid and vapor. Causes respiratory tract irritation. Air sensitive. Causes eye and skin irritation.stench. Target Organs: Eyes, skin, mucous membranes. Potential Health Effects Eye: Causes eye irritation. Causes skin irritation. Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Inhalation: May cause respiratory tract irritation. Vapors may cause dizziness or suffocation. Chronic: No information found. 4 - FIRST AID MEASURES Eyes: Ingestion: Inhalation: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician: 5 - FIRE FIGHTING MEASURES General Information: Extinguishing Media: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air. Vapors can travel to a source of ignition and flash back. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water. 6 - ACCIDENTAL RELEASE MEASURES General Information: Spills/Leaks: Use proper personal protective equipment as indicated in Section 8. Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. 7 HANDLING AND STORAGE Handling: Storage: Wash thoroughly after handling. Use only in a wellventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing.empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Store in a tightly closed container.store in a cool, dry, wellventilated area away from incompatible substances. Flammables-area.
8 EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Exposure Limits Personal Protective Equipment Eyes: Clothing: Respirators: 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Specific Gravity/Density: 0.769-0.797 Molecular Formula: C 5 H 10 O Molecular Weight: 86.14 10 - STABILITY AND REACTIVITY Chemical Stability: Conditions to Avoid: Incompatibilities with Other Materials : Hazardous Decomposition Products : Hazardous Polymerization : Has not been reported. 11 - TOXICOLOGICAL INFORMATION Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Wear appropriate protective gloves to prevent skin exposure. Wear appropriate protective clothing to prevent skin exposure. Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Stable under normal temperatures and pressures. Light, ignition sources, exposure to air, excess heat. Strong oxidizing agents, reducing agents, strong bases. Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. RTECS#: LD50/LC50: CAS# 590-86-3: ES3450000 RTECS: CAS# 590-86-3: Dermal, guinea pig: LD50 = >8 gm/kg; Draize test, rabbit, eye: 100 mg/24h Moderate; Draize test, rabbit, skin: 500 mg/24h Mild; Inhalation, mouse: LC50 = 50770 mg/m3; Inhalation, mouse: LC50 = 47700 mg/m3/2h;
Other: Carcinogenicity: Other: Inhalation, rat: LC50 = 42700 mg/m3/4h; Inhalation, rat: LC50 = 30860 mg/m3; Oral, mouse: LD50 = 4750 mg/kg; Oral, rat: LD50 = 5600 mg/kg; Oral, rat: LD50 = 5165 mg/kg; Skin, rabbit: LD50 = 3180 ul/kg; Rabbit LD50 - Route: Skin Dose: 3180 ul/kg = 2512 mg/kg. 3-Methylbutyraldehyde - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65. 12 - ECOLOGICAL INFORMATION 13 - DISPOSAL CONSIDERATIONS 14 - TRANSPORT INFORMATION IATA IMO RID/ADR Shipping Name: Valeraldehyde Valeraldehyde Valeraldehyde Hazard Class: 3 3 3 UN Number: 2058 2058 2058 Packing Group: II II II 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN F Risk Phrases: R 11 Highly flammable.r 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 16 Keep away from sources of ignition - No smoking. S 29 Do not empty into drains.s 33 Take precautionary measures against static discharges. WGK (Water Danger/Protection)CAS# 590-86-3: 1 Canada CAS# 590-86-3 is listed on Canada's DSL List US Federal TSCA Health & Safety Reporting List CAS# 590-86-3 is listed on the TSCA Inventory. None of the chemicals are on the Health & Safety Reporting List. Chemical Test Rules None of the chemicals in this product are under a Chemical Test Rule. Section 12b None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule CERCLA Hazardous Substances and corresponding RQs SARA Section 302 Extremely Hazardous Substances SARA Codes None of the chemicals in this material have a SNUR under TSCA. None of the chemicals in this material have an RQ. None of the chemicals in this product have a TPQ. CAS # 590-86-3: acute, flammable. Section 313 No chemicals are reportable under Section 313. Clean Air Act: This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors. Clean Water Act: California Prop 65 Risk Level: 16 - ADDITIONAL INFORMATION None of the chemicals in this product are listed as Hazardous Substances under the CWA.None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA. California No Significant None of the chemicals in this product are listed. SISCO RESEARCH LABORATORIES provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.