SEPCARB 3D CARBON/CARBON COMPOSITE FIXTURING AND EQUIPMENT FOR HIGH-TEMPERATURE PROCESSES

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FIXTURING AND EQUIPMENT FOR HIGH-TEMPERATURE PROCESSES

SAFRAN IS A LEADING INTERNATIONAL HIGH-TECHNOLOGY GROUP WITH THREE CORE BUSINESSES: AEROSPACE; DEFENCE; AND SECURITY. OPERATING IN SEVERAL COUNTRIES, SAFRAN EMPLOYS MORE THAN 55,000 PEOPLE WORLDWIDE. For more than 40 years, Snecma Propulsion Solide, a SAFRAN subsidiary, has developed and manufactured a broad range of high-temperature composite materials for the aerospace, energy, automotive and other industries. Sepcarb is our high-performance 3D carbon/carbon composite material. Sepcarb tooling is used for high-temperature processing of aerospace and automotive components. Over 500 tons of Sepcarb are produced annually in our European and North American plants. Sepcarb is the ideal tooling material for brazing, annealing, carburizing and quenching of high-performance metals in vacuum or inert atmosphere furnaces. Snecma Propulsion Solide is your partner in the design and fabrication of tooling and equipment for high-temperature applications. Choose Sepcarb to improve your productivity.

CONTENTS SEPCARB Thermal solutions 2 Technology 3 Properties 4 Benefits 5 SEPCARB THERMAL PRODUCTS Tooling for heat treatment 6 Tooling for carburizing 7 Furnace bases 8 Specialized hardware 8

THERMAL SOLUTIONS The exceptional characteristics of Sepcarb carbon/carbon composite make it the ideal material for tooling used in heat treatment, low-pressure carburizing, annealing and brazing applications of metals. Sepcarb significantly outperforms graphite and refractory alloys in these very demanding thermal processes. > SEPCARB EQUIPMENT PROVIDES THESE MAJOR BENEFITS: Higher-efficiency and more secure processing Reduction of rejected parts and production quality improvements No tooling deformation, allowing robotic automation Zero creep, providing extended service life High temperature capability, allowing higher processing temperatures and shorter cycle times Reduced maintenance costs High resistance to fatigue and to mechanical and thermal shock Low mass for easier handling Low thermal inertia, reducing power consumption and cycle duration, and decreasing production costs High resistance to corrosive chemicals Large range of dimensions available One-piece plate Ø 2200 mm / 86 2

TECHNOLOGY > Sepcarb is a composite of carbon fibers and a carbon matrix which bonds the fibers together and distributes the load evenly. Both the carbon fibers and the carbon matrix are resistant to extremely high temperatures. The precise distribution and combination of these components provides Sepcarb with exceptional lightness, outstanding resistance to thermal shock, and stability of mechanical properties at temperatures up to 2700 C. The result is perfectly consistent operational behavior, unmatched reliability and extended service life. These properties make Sepcarb the ideal tooling material for a very wide range of applications. > In contrast with 2-dimensional (2D) carbon/carbon products, Sepcarb H01 is highly delamination-resistant. This results from its patented 3D architecture, combined with the chemical vapor infiltration (CVI) process used in its manufacture. > The CVI process enables the formation of an extremely pure and homogeneous carbon matrix within the fiber architecture. This process yields an optimal matrix-to-fiber cohesion, providing excellent mechanical properties and thermal stability. Materials and parts are manufactured using proven industrial processes. Manufacturing capabilities exceed 2 meters x 3 meters (80 x 120 ). A wide variety of geometries can be fabricated including (but not limited to) plates, cylinders, tubes, discs, cones and beams, as well as complex shapes with thicknesses of less than one millimeter to several centimeters. > With an average density of 1.5, Sepcarb is the ideal material for heat treatment fixturing to be used in vacuum and inert atmosphere furnaces operating up to 1300 C (2370 F) or higher. CARBON FIBERS FIBER REINFORCEMENT (1D, 2D, 3D, 4D, ND ARCHITECTURE) LIQUID ROUTE GASEOUS ROUTE Liquid route densification process IMPREGNATION POLYMERIZATION CARBONIZATION MACHINING INFILTRATION MACHINING SEPCARB Chemical Vapor Infiltration (CVI) process 3

PROPERTIES > The main properties of Sepcarb include its exceptionally low density, outstanding resistance to thermal shock and corrosion, stability of mechanical properties at temperatures up to 2700 C (4890 o F), high resistance to fatigue and total absence of creep. > The following tables compare the mechanical properties of Sepcarb with those of graphite and refractory alloy. COMPARATIVE TABLE OF SPECIFIC ULTIMATE STRENGTH (ULTIMATE STRENGTH / DENSITY) COMPARATIVE TABLE OF SPECIFIC YOUNG S MODULUS (YOUNG S MODULUS / DENSITY) > The properties of standard-grade Sepcarb 3D carbon/carbon material are provided below as indicative values. Density 1.5 Temperature C 25 1000 1500 Tensile strength σt,r (MPa) 100 120 120 εt,r (%) 0.6 0.5 0.5 Eo (GPa) 30 30 30 Interlaminar shear strength T r (MPa) 22 30 31 V (%) 1.3 1.1 1.1 G (GPA) 5 5 5 Thermal expansion (%) 0.2 0.3 Heat capacity (J.Kg- 1.K- 1 ) 800 1900 2100 4

BENEFITS > The following table provides a qualitative comparison of SepCarb carbon/carbon, graphite, and refractory alloy. In addition to usage guidelines, the table illustrates the benefits and advantages of carbon/carbon. Sepcarb carbon/carbon Graphite Refractory metal Carbon/carbon benefit Weight Density 1.5 Density 1.8 Density 5 to 10 times higher than c/c - Easy handling, - Increased worker safety, - Easier storage, - Lighter loads yield reduced maintenance costs, less down-time. Thermal resistance (but mechanical strength is 4 times less than c/c) Performance characteristics reduced at 1000 o C (1832 o F); completely lost above 1100 o C (2012 o F) Permits a lighter, more robust design. Creep Poor No deformation permits robotic automation of loading / unloading. Thermal shock resistance Fair Poor Stands up to shorter heat/quench cycles; increases productivity. Mechanical shock resistance Very Good Very Poor Due to its composite make-up, c/c is not brittle (as are graphite and ceramic). It is therefore very suitable for intensive use. Energy saving Fair Poor Carbon/carbon fixturing has much less thermal inertia than graphite and metal. Up to 3 times less energy is required for heating. Heating and cooling cycles are shortened. Safety Fair to Poor Fair to Poor Lighter carbon/carbon fixturing makes handling easier, faster and safer. Protecting the environment Poor Poor Less energy used = reduced environmental impact. 5

THERMAL PRODUCTS HEAT TREATMENT FIXTURES 900 x 600 x 600 mm 3 36 x 24 x 24 900 x 600 x 600 mm 3 36 x 24 x 24 600 x 450 x 600 mm 3 24 x 18 x 24 1000 x 450 x 400 mm 3 40 x 18 x 16 Ø 400 mm - H 610 mm Ø 16 - H 24 Ø 1180 mm - H 1460 mm Ø 47 - H 58 Ø 650 mm - H 1220 mm Ø 26 - H 48 Ø 1150 mm - H 1200 mm Ø 45 - H 48 6 Additional applications, designs, geometry and dimensions upon request

THERMAL PRODUCTS CARBURIZING FIXTURES 600 x 450 x 600 mm 3 24 x 18 x 24 900 x 600 x 600 mm 3 36 x 24 x 24 Ø 500 mm - H 900 mm Ø 20 - H 36 Ø 500 mm - H 900 mm Ø 20 - H 36 400 x 200 x200 mm 3 16 x 8 x 8 Additional designs, geometry and dimensions upon request 7

THERMAL PRODUCTS FURNACES BASES Ø 600 mm / 24 Ø 600 mm / 24 Ø 1200 mm / 47 Additional designs, geometry and dimensions upon request SPECIALIZED HARDWARE Temperature Uniformity Survey (TUS) fixture Spring shapers Bolts & nuts Ø 1500 mm - H 1500 mm Ø 60 - H 60 8 Additional applications, designs, geometry and dimensions upon request

DISCLAIMERS 1 - BROCHURE CONTENTS DISCLAIMER All information in this brochure is based on Snecma Propulsion Solide data that were currently available at the time of production. The brochure provides general information on Snecma Propulsion Solide products and product applications. The product data given in this brochure are typical values and are not guaranteed. The product applications in this brochure are examples only. In addition to using your own discretion and judgment, please consult with Snecma Propulsion Solide in order to establish the appropriateness of our products for your applications before use, and follow up with an assessment of product performance, behavior and safety. The information in this brochure is subject to change without notice, based on the judgment of Snecma Propulsion Solide 2 - INTELLECTUAL PROPERTY RIGHTS DISCLAIMER There is no guarantee that the product application examples in this brochure do not infringe on the intellectual property rights of a third party. No information in this brochure may be used or reproduced without the prior consent of Snecma Propulsion Solide. 3 - PRODUCT USAGE DISCLAIMER Before using our products, please read the corresponding Material Safety Data Sheet issued by Snecma Propulsion Solide. 9

CONTACTS SNECMA PROPULSION SOLIDE Aeronautics & Composites Division Les Cinq Chemins - 33187 Le Haillan Cedex - France Phone: +33 5 56 55 86 82 sps.industry@snecma.fr - www.sps-industry.com DISTRIBUTION NORTH AMERICA KROEM TECHNOLOGIES INC. 1540 SALZBOURG BROSSARD, QC, CANADA J4X 1W1 Phone: (450) 671-1543 - Fax: (450) 671-0545 Mobile: (514) 576-0420 info@kroem.com - www.kroem.com ITALY SILCO SRL QUINTA STRADA, 9 - INTERPORTO S.I.TO. - 10040 RIVALTA (TO) Italy Phone: + 39 011 3972930 info@silco.ws - www.silco.ws ROUMANIE ARTEM GROUP TRADE & CONSULT Calea Rahovei n 266-268, Corp 3, Subsol, Cam. 26, Sector 5, cod 050912 - Bucarest, Roumanie www.artemgroup.eu Mobile: +40 751 010 102 radu.nedelcu@artem.ro Mobile: + 40 742 031 156 lacombemichel49@yahoo.fr Crédit photos : Snecma Propulsion Solide - Fotolia SNECMA PROPULSION SOLIDE Les Cinq Chemins - 33187 Le Haillan Cedex Tél. +33 (0)5 56 55 30 00 - Fax : +33 (0)5 56 55 30 01 communication.bordeaux@snecma.fr - www.snecma-propulsion-solide.com