Next Generation SAGD Produced Water Treatment Technology Development. ESAA Watertech 2012 Banff, Alberta April 12, 2012

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Next Generation SAGD Produced Water Treatment Technology Development ESAA Watertech 2012 Banff, Alberta April 12, 2012

Energy and water are co-dependent Energy is required for making water and water is required in the production of energy.

Water & energy needs are interlinked Power production Oil Sands Unconventional Gas Mining 90% for once through cooling 90% water recycle 30%+ process water reuse >70% in water scarce regions Energy production is thirsty

Upstream oil sands value chain Synthetic Crude Oil for Refining Bitumen Upgrader Extraction Facility Bitumen/Sand Mine Sites Dilbit Dilbit SAGD Facility Exploitation Methods Produced Emulsion from Wells SAGD Well Pads Steam for Reservoir Injection Oil Sands Reservoir 4

It has only been 24 years since SAGD came off the paper and 12 years at commercial scale in the field SAGD facilities today Survive Operate Optimize Thrive SAGD Production Capacity 1.0 MBPD 0.5 2000 2005 2010 2015 0 2015 5

Optimizing SAGD Facilities SAGD Facility Efficiency and Reliability Step Change Improvement Facilities of the Future Downtime Energy Use Water Use Carbon Intensity CAPEX OPEX Today s Process Designs 6 8 year project cycles Incremental Improvement 30 years to commercialize SAGD technology Time 6 4/17/2012

Key SAGD Produced Water Issues Discharge Ccmposition & Qqality Water to meet 1B wells, reduced ph and silica concentration Evaporator capex & opex Energy usage, CO2 emissions, capital cost Water usage recycle, discharge, intake Minimize discharge volume, site make-up volume, increase recycle Deoiling efficiency Oil-Water separation, plant operability, boiler reliability Installation cost and time Minimize on-site construction thru modularization 7

SAGD facility unit processes Water Side Sludge to disposal Conventional De-oiling Oil Side Centrifuge WLS Filter De-oiled Water 5 ppm oil WSF IGF Slop Oil Tank Skim Tank Oily Water 1 5 k ppm Softened, brackish make-up water IX Steam Generation BFW Tank OTSG Treater FWKO O/W Separation Reservoir Production from well pads 80:20 water/oil emulsion Dilbit Sales $/Bbl Conventional Water Recycle Blowdown to disposal Separator Diluent Tank 99% steam quality to well pads 8

NEXTGEN SAGD PILOT PROGRAM

Program objectives 1 Deoiling field pilot - 6 months @ 20 gpm deliver treated water with no more than ~1ppm oil-in-water @ 90 0 C establish optimum system design, recovery rate and operating conditions for deoiling system across a broad range of SAGD produced water inlet conditions determine options available for control and monitoring the efficiency of oil separation validate total lifecycle cost model and value proposition for existing and nextgen SAGD deoiling unit operations identify most promising pathways for future technology development 2 Pre-concentration field pilot - 4 months @ 20 gpm deliver boiler feed water quality and concentrate stream compatible with evaporator treatment @ 90 0 C and ph >10 design and build robust, high temp/high ph tolerant RO membrane establish optimum system design, recovery rate and operating conditions for pre-concentration system determine options available for control and monitoring the pre-concentration process validate total lifecycle cost model and value proposition for combined deoiling & pre-concentration system Identify most promising pathways for future technology development 3 Demonstration plant with best technology - 6 months @ 100 gpm Demonstrate the achievement of the above criteria at a scale sufficient to support commercialization Validate total lifecycle cost model and value proposition for best combined deoiling & preconcentration system 10

Field testing erector set approach Phase 1: De-oiling Pilot Phase 2: Pre-concentration Pilot Skim Tank Chemistry Coarse Treatment Physical Separator A Voraxial Separator Physical Separator B Aquial Separator Physical Separator C Polishing Sorbent Heat Exchange Advanced Treatment Ceramic A Ceramic B Polymeric Innovox ä TOC Analyzer Analyzer Advanced Treatment Silica Removal A Silica Removal B Boiler Feed Water Tank 60% HT Reverse Osmosis 40% Evaporator Operation Chemical Pre-treatment Physical Separation Sorbent Ceramic/Spiral Membrane Silica Removal TDS Removal Goal Break oil for subsequent removal in a physical separator Remove oil/solids from process fluids Remove dissolved and other organic components Provide absolute barrier to emulsified oils Remove silica at ph <10, 90 0 C Provide high purity boiler feed water Phase 3 Scale up best performing technologies to 100 gpm demo plant 11

Deoiling pilot layout Controls Deoiled Filtrate CIP Chemical Addition Membranes Reject Physical Separators Controls Sump 12

Value proposition 40% Concentrated Brine De-oiling Unit Smaller evap system to remove salt from brine: Lower CAPEX lower OPEX lower CO 2 emissions 100% More effective de-oiling + pre-concentration system to remove oil and salt: Deoiled Water higher CAPEX higher OPEX BFW < 3 ppm BFW BFW 60% Protect OTSG/Boiler from oil/fouling: Increase up-time Lower OPEX Increase boiler efficiency Oily Water 1000-5000 ppm O/W Separation Water Recycle Unit Steam Generation Diluent Increase plant availability and decrease overall CAPEX/OPEX 13

Value proposition Establishment of an efficient deoiling process offers the potential for RO systems to be used in conjunction w/ thermal evaporators to reducetotal energy and cost required for SAGD produced water recycling Direct Benefits: 40% smaller evaporator required 26% lower capital cost 29% lower annual operating cost 30% lower CO 2 emissions Indirect Benefits: Reduced risk of boiler issues/tube failures barrier to oil Smaller areal footprint Improved plant availability - down time costs ~ $2.4M/day Conventional Deoiling ($M) Equip. CAPEX OPEX/yr Skim tank No change IGF 6.8 2.0 WSF 4.5 0.6 Evaporator 76.0 6.7 Boiler No change Total 87.4 9.4 NextGen Deoiling ($M) Equip. CAPEX OPEX/yr Skim tank No change Deoiling 15.4 2.1 HT RO 11.0 1.8 Evaporator 38.0 2.7 Boiler No change Total 64.4 6.6 * Estimates based on 30,000 BOPD SAGD facility 14

Produced Water Treatment Total Life-cycle Costs Finding the saddle point Further improvements in water quality have marginal affect on cost reduction Steam Generation Water Treatment Increasing Boiler Feed Water Quality What is the optimum combination for lowest overall life-cycle cost? 15