Solvay s composites consist of a thermoplastic matrix of poly (ether-ketone-ketone) commonly referred to as PEKK-FC polymer with aligned, continuous unidirectional fiber reinforcement. The tapes are fully impregnated with a tailored fiber-matrix interface for optimal performance. Solvay also supplies custom laminates made from the tapes. The polymer is semi-crystalline with a glass transition temperature of 318 F (159 C). composites possess outstanding flame, smoke, and toxicity performance. They also have high toughness and damage tolerance. Laminates and parts can be fabricated from using a wide range of techniques including autoclave and press molding. Typical applications for Solvay s include aircraft structure, space components, and other transportation & structural engineering components. Features and Benefits Semi-crystalline, thermoplastic matrix Fully impregnated, unidirectional tape High toughness and damage tolerance Structural properties Tg of 318 F (159 C) Low moisture uptake ( <0.3 % by wt. 1 ) Manufacture parts using affordable non-autoclave processes Outstanding FST 2 and OSU 3 heat release properties Good resistance to a wide range of fluid environments Indefinite shelf life at room temperature Recyclable 1 Equilibrium, 85% Relative Humidity, 160 F (71 C) 2 FST: Flame, Smoke, and Toxicity 3 OSU: Ohio State University RESIN CHARACTERISTICS Table 1 Nominal Neat Resin Properties of DMA Tg dry, F ( C) 318 (159) Density, pcf (g/cc) 81.8 (1.31) (%crystalline = 30%) 79.9(1.28) (%crystalline = 0%) Melting Temperature, Tm, F ( C) 639 (337) Tensile Strength at Tensile Modulus at Tensile Elongation at % Thermal Heat of Fusion With 100% Crystalline 14.8 (102) 0.65 (4.5) 4 THERMOPLASTIC POLYMER PREPREG
After cooling 35.5 F/min (20 C/min) kcal/lb (J/g) Flammability Properties Heat Release Rate (OSU,Peak/Total) kw/m 2, kw-min/m 2 Flammability Rating, UL-94 Limiting Oxygen Index 14.1 (130) 4.21 (38.8) < 65, < 65 V-0 40 PREPREG CHARACTERISTICS Table 2 Product Availability and Nominal Physical Properties of Form 12 inch (30.5 cm) Unidirectional Tape Fiber AS4D 12K S2 Glass Resin Content, wt. % 34 30 Areal Weight, psf (gsm) 0.030 (145) 0.039 (190) CPT, in (mm) 0.0055 (0.140) 0.0054 (0.137) Table 3 Composite Thermal Properties at RT, Melting Temperature, Tm 1 Glass Transition Temperature, Tg Crystallization Temperature, Tc 2 639 F (337 C) 318 F (159 C) 534 F (279 C) 1 Determined by DSC. 2 Cooling Rate: 18 F/min (10 C/min) Table 4 Composite Flammability Properties at RT, Vertical Burn Drip time sec Vertical Burn Extinguishing time sec No Drip OSU heat release peak kw/m 2 OSU heat release total kw-min/m 2 NBS smoke density @ 4 minutes D s 0 THERMOPLASTIC POLYMER PREPREG
PROPERTIES Table 5 Mechanical Properties: High Strength (>650 ksi/ 4480 MPa) Standard Modulus (33 Msi/ 228 GPa) Carbon Fiber Reinforced Unidirectional Tape Test Condition 0 Tensile Strength 0 Tensile Modulus 90 Tensile Strength 90 Tensile Modulus 0 Compression Strength 0 Compression Modulus 0 Compression Strength 0 Flexural Strength 0 Flexural Modulus In-Plane Shear 0.2% Offset Shear Stress In-Plane Shear Modulus Open Hole Tensile Strength Open Hole Tensile Modulus Open Hole Compression Strength Open Hole Compression Modulus Compression After Impact Strength after 1500 in-lb/in (6.67 J/mm) * values listed are typical for laminates with 60% fiber volume. **Wet = Water immersion for 14 days at 160 F (71 C). 372 (2560) 357 (2460) 20.4 (141) 20.1 (139) 8.9 (61) 6.8 (47) 1.5 (10.3) 1.2 (8.2) 217 (1490) 187 (1290) 163 (1130) 18.4 (127) 18.5 (128) 18.9 (130) 36.8 (254) 27.6 (190) 26.1 (180) 248 (1710) 200 (1380) 18.4 (127) 18.3 (126) 7.6 (52.4) 5.0 (34.5) 3.6 (24.8) 0.76 (5.2) 0.56 (3.9) 0.40 (2.8) 68 (469) 66 (455) 8.1 (55.8) 7.8 (54.8) 48 (332) 40 (275) 7.6 (52.4) 7.5 (51.7) 47 (324) PROCESSING THERMOPLASTIC POLYMER PREPREG
Typical Autoclave Consolidation Cycle 20 Figure 1 Consolidation Cycle Apply minimum 24 inches (610 mm) Hg vacuum to bagged assembly and maintain throughout the entire cycle. Heat from RT,, to 710 F ± 10 F (377 C ± 5.5 C) at any available rate based on part temperature. Ensure material/laminate is equilibrated at process temperature using lagging thermocouple. Apply 100 psi ± 5 psi (689 kpa ± 34 kpa) autoclave pressure when temperature reaches 710 F (377 C). Hold at to 710 F (377 C) for 20 +10/-5 minutes. Cool down at a rate of 20 F/min (11 C/min). Maintain pressure until below. * Time at temperature is based on lagging thermocouple ** Press consolidation cycle may vary depending on equipment parameters THERMOPLASTIC POLYMER PREPREG
Lay-Up/ Bagging PRODUCT HANDLING Figure 2 Recommended Vacuum Bag Scheme Solvay recommends the wearing of clean, impervious gloves when working with prepreg materials in order to reduce skin contact and to avoid contamination of the product. See the Safety Data Sheet for more information. SHIPPING APC(PEKK-FC) is typically shipped as rolls in containers at ambient temperature.standard roll form is 12 inches wide (30.5 cm) and approximately 600 linear feet (182 meter). It is not necessary to seal the material in bags. DISPOSAL OF SCRAP MATERIAL Discarded APC(PEKK-FC) is not a hazardous waste under RCRA, 40 CFR261. Disposal of material should be in accordance with local, state, and federal regulations, which may vary by location. Questions concerning the disposal should be directed to the Solvay Safety, Health, and Environmental Affairs Department in Winona, Minnesota at (507) 454-3611 for evaluation on a case-by-case basis. HEALTH & SAFETY Please refer to the product SDS for safe handling, personal protective equipment recommendations and disposal considerations. DISCLAIMER: The data and information provided in this document have been obtained from carefully controlled samples and are considered to be representative of the product described. Solvay does not express or imply any guarantee or warranty of any kind including, but not limited to, the accuracy, the completeness or the relevance of the data and information set out herein. Because the properties of this product can be significantly affected by the fabrication and testing techniques employed, and since Solvay does not control the conditions under which its products are tested and used, Solvay cannot guarantee the properties provided will be obtained with other processes and equipment. No guarantee or warranty is provided if the product is adapted for a specific use or purpose. Solvay declines any liability with respect to the use made by any third party of the data and information contained herein. Solvay has the right to change any data or information when deemed appropriate. All trademarks are the property of their respective owners. 2017, Solvay. All rights reserved. Solvay Composite Materials HQ 4500 McGinnis Ferry Rd Alpharetta, GA 30005-3914 USA TDS APC(PEKK-FC)_2017_10_11