Oil Production from Tight Shale Using CO 2

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U N I V E R S I T Y O F B E R G E N Department of Physics and Technology Oil Production from Tight Shale Using CO 2 Rognmo* A. U., Lysne M., Fredriksen S. B., Fernø M. A. and Graue A. Department of Physics and Technology, University of Bergen, Norway 2 nd Biennial CO 2 for EOR as CCUS Conference, Oct. 4-6, 2015 Houston, USA

Outline Motivation Experimental setup Observations and results Concluding remarks

Key numbers 37% 76% 20% 6% 10 Mb/d (EIA, 2011; DOE/EIA, 2014)

Oil production from shale-oil Hydraulic fracturing and horizontal drilling Low R f 3-10% of OOIP Estimated reserves in the US 24 billion barrels (DOE/EIA, 2014; EPA, 2010; Liu et al., 2014)

CO 2 for EOR in shale-oil formations Incentives (CCUS) Beneficial CO2 properties Miscibility Relative high density and viscosity Lower formation breakdown pressure and improved fracture network compared to water

Experiments and results

Experimental overview 22 miscible CO 2 -injection tests (shale-oil core plugs) 1 and 1.5 core plugs L 1-2 K 60 nd 3 μd φ 4-9%

Experimental setup CO 2 -injection General experimental conditions: Inlet: 220 bar (3200 psi) Outlet: 150 bar (2200 psi) O.burden: 310 bar(4500 psi) 60ºC (140ºF) 3 hours 8 days 0.2 60 PV CO 2 injected

CO 2 EOR in shale-oil samples Crude oil (multi-contact miscible)

CO 2 EOR in shale-oil samples Mineral oil (first-contact miscible)

CO 2 EOR in shale-oil samples Increased length (multi-contact miscible)

Increased system length 1 2 10 cm

Oil recovery factor - overview Average 68% OOIP Average 35% OOIP

Fluid flow capacity End-point effective permeability K` eff,co 2 = μ CO2 A Q CO 2 L P

Effect of permeability on oil recovery

Improved sweep by diffusional forces

Conclusions Oil extraction from CO 2 -injection without fracking the formation is possible in ultra-tight shale samples (59 nd 2.36 μd). Average R f for crude oil saturated cores yielded 34.9% of OOIP (19.8-50.5% of OOIP). Recovery of oil from tight shale-oil is strongly dependent on achieving miscibility between CO 2 and oil phase, corroborating the assumed importance of diffusive forces.

References DOE/EIA, 2014. Annual Energy Outlook 2014, Washington DC: DOE/EIA U.S. Energy Information Administration. EIA, 2011. Review of Emerging Resources U.S. Shale Gas and Shale Oil Plays, Washington DC: U.S. Energy Information Administration. EIA, 2013. Technically Recoverable Shale Oil and Shale Gas Resources: An Assessment of 137 Shale Formations in 41 countries outside the US, Waskington, DC: U.S. Department of Energy. EPA, 2010. Hydraulic Fracturing Research Study, Washington D.C.: EPA. Flannery, J. & Kraus, J., 2006. Integrated Analysis of the Bakken Petroleum System, U.S. Williston Basin. Houston, Texas, Saskatchewan and Northern Plains Oil & Gas Symposium, 2006. Gaswirth, S. B., Marra, K. R., Cook, T. A. Charpentier, R. R., Gautier, D. L. Higley, D. K., Klett, T. R., Lewan, M. D., Lillis, P. G., Schenk, C. J., Tennyson, M. E. & Whidden, K. J., 2013. Assessment of Undiscovered Oil Resources in the Bakken and Three Forks Formations, Williston Basin Province, Montana,North Dakota, and South Dakota, 2013, U.S. Geological Survey, Denver, CO: U.S. Geological Survey National Assessment of Oil and Gas Fact Sheet 2013-3013. Graue, A., Fernø, M. A., Bø, K., Opdal, I. K., Lysne, M. & Rognmo, A. U., 2014. EOR in Tight Rocks, Progress report Statoil, Bergen, Norway: Dept. of Physics and Technology, UoB. Liu, G., Sorensen, J. A., Braunberger, J. R., Klenner, R.; Ge, J., Gorecki, C. D., Steadman, E. N. & Harju, J. A., 2014. CO2- Based Enhanced Oil Recovery from Unconventional Reservoirs: A Case Study of the Bakken Formation. The Woodlands, Texas, USA, SPE. Tran, T., Sinurat, P. & Wattenbarger, R. A., 2011. Production Characteristics of the Bakken Shale Oil. Denver, Colorado, USA, SPE