Aerospace and Automotive Seat Frames from Carbon and PPS Thermoplastic Tape. Bob Newill Ticona Engineering Polymers

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Aerospace and Automotive Seat Frames from Carbon and PPS Thermoplastic Tape Bob Newill Ticona Engineering Polymers 1

Outline Background Aerospace and Automotive Seat Frames Trends Supporting Change Composites Benefits and Challenges New Thermoplastic Composite Offset PPS/Carbon Tape Preform Processing Options Award-Winning Seat Design Summary 2

Background Aviation and automotive seat frames Most are multi-piece aluminum designs Frames represent a significant proportion of Total seat weight Total vehicle weight Both industries face significant pressure To reduce vehicle mass and improve fuel efficiency To maintain or reduce production costs 3

Background New materials and processes that offer opportunities to reduce weight and cost, and add functionality are welcome, but Unit cost vs. aluminum remains a key issue that must be overcome in order for change to occur 4

Background Composites could be a good alternative because they offer the opportunity to Reduce weight Reduce or eliminate assembly operations Add functionality (molded-in features, more complex geometry with better ergonomics, less buzz, squeak and rattle (BSR) etc.) 5

Background But Costs must be competitive with aluminum Materials must meet cabin requirements for Fire / smoke / toxicity (aerospace) Emissions / fogging (automotive) 6

Background High-performance composite alternatives to aluminum seat frames Continuous carbon fiber reinforcement High-temperature matrix options Thermosets: epoxy, urethane, polyimide Thermoplastics: PEEK, PEKK, PPS, and PEI Each system offers challenges and opportunities 7

Background High-performance thermoset resins Lower base resin but higher prepreg and production costs Lighter than metals with excellent mechanicals and thermal performance Most require halogenated additives to meet flame retardance requirements (achieved at the expense of smoke and toxicity) VOC emissions can also be an issue Scrap and end-of-life parts not easy to recycle 8

Background High-performance thermoset processes Tooling can be low cost depending on process Many processes are slow, hard to automate, and require skilled labor Post-mold finishing can add significant time and expense 9 Thermosets Offer Definite Benefits vs. Aluminum but Can be Improved Upon

Background High-performance thermoplastic resins Higher base resin costs but lower prepreg and production costs Lighter and more damage tolerant than metals or thermosets Some resins inherently flame retarded with low smoke and toxicity All thermoplastics are melt-reprocessable, facilitating in-plant and end-of-life recycling 10

Background High-performance thermoplastic processes Tooling can be more costly but most processes are fast and highly automated, which can lower production costs for mediumto-high volume programs Much less post-mold finishing and more decorating options VOC emissions lower (processing and use) 11 Thermoplastics Offer Great Benefits but Need Lower Production Costs

Background If you could combine Low cost but rapid manufacturing process that allows high-performance assemblies to be produced even at low volumes, with Performance benefits of thermoplastics (lighter, more damage tolerant, recyclable, low VOCs, faster processing, inherent flame resistance with low smoke and toxicity) 12 That would be a Game-Changing Seat Frame Technology for both Aerospace and Automotive

New Thermoplastic Composite Offset High-performance thermoplastic matrix Linear polyphenylene sulfide (PPS) Semi-crystalline for excellent and broad chemical resistance (no known solvent at rm. Temp.) High thermal performance (tg =90 C, tm=285 C) Produces stiff but lightweight parts (SG=1.34 g/cm 3 ) with performance similar to aluminum Inherently flame retardant (UL 94 V-0; LOI >40) Easy to process; viscosity tunable to different production methods 13

New Thermoplastic Composite Offset High-performance thermoplastic composites PPS offers good wetout of reinforcement Glass, aramid, or carbon fiber Tow or fabric weaves Processable via Hand layup with oven/autoclave consolidation Resin infusion Thermoforming / thermostamping / compression molding 14

New Thermoplastic Composite Offset Developing a low-cost process for thermoplastic composites Must produce high-quality parts in a repeatable process Must be cost effective for small and large parts at low as well as high production volumes Must work with a variety of reinforcements Must be able to produce prepreg / semipreg or preform 15

New Thermoplastic Composite Offset Cost-effective composite form factors PPS / carbon films, tapes, and sheet products Melt PPS and produce crystal film Join PPS film with carbon fiber tow or fabric, consolidate under heat and pressure Form thin films that subsequently are slit and braided Form thick sheets that are cut into blanks and subsequently molded Automated processes with excellent control over fiber positioning 16

Step 1: PPS Film Production Linear PPS Pellets Starting product: Linear PPS pellets Temperature stability High level of hardness and impact strength Excellent resistance to chemicals Broad temperature range Inherent flame resistance Film production Station 1 PPS pellets are converted into films with a thickness of 50 to 200 µm. The film is wound onto rolls of 100 kg in a flawless state, crystal clear and with the required characteristics with regard to strength and dimensional stability. 17

Step 2: PPS / Carbon Film / Sheet Production Linear PPS Film e. g. Carbon Fiber Starting product: Basic Matrix of Linear PPS / Carbon Fiber Fabric Laminate production Step 2 The carbon fiber fabric and linear PPS film are bonded together in a press, under high pressure and high temperature, into high-strength, dimensionally stable and resistant films or sheet products in the desired thickness for the molding process selected. 18

Step 3a: PPS / Carbon Braided Preform PPS / carbon film is Slit and braided Used in bladder molding, resin infusion or other tape layup processes Braided preform variables Braid angle Braid diameter Spacing 19

Step 3b: PPS / Carbon Molding Processes Positive Side of Tool Composite Sheet Starting product: Composite sheets (blanks) cut to the required size Negative Side of Tool Thermoforming (1- or 2-sided tooling, with or without plug or vacuum assist) Shaping / Molding Step 3 The composite sheets are preheated and subsequently shaped into the desired form under pressure and high temperature. 20

Step 3c: Other PPS / Carbon Molding Processes Automated Dynamics Fiber Placement 21 Lingol Thermoforming FiberForge Compression Molding

Award-Winning Seat Design Owing to versatility of preform and molding technologies available for PPS/carbon, many different seat components can be produced To demonstrate the versatility of the technology, a demonstration modular composite seatback and top seat frame were developed 22

Award-Winning Seat Design Developmental seatback partners Cutting Dynamics, Inc. (CDi) Ticona Engineering Polymers TenCate Advanced Composites A&P Technology (A&P) Work began in 2009 23

Award-Winning Seat Design (Top) seat frame Early challenges (A&P and CDi) Identify a thin tape that would run through a braiding machine Develop design tools to predict type of braid required to meet geometry of seatback Modify braiding equipment to manipulate the PPS / carbon tape into a preform Identify preform configuration Develop innovative tooling 24

Typical Tool for Tubular TP Composite Braided Preform Silicone Sleeve Split Mandrel Heating and/or Cooling Channels 25 Matched metal tool for rapid, quality parts Split mandrel for ease of removal Silicone sleeve for additional expansion of tool from ID Heating/cooling channels to reduce process time

Award-Winning Seat Design (Top) seat frame Proprietary CDi forming process Uses braided PPS/carbon tape High speed (capable of production volumes of 400,000 annually) Excellent repeatability and reproducibility (R&R) Produces complex geometry, hollow-section parts 26

Award-Winning Seat Design Version One Seatback Sourced from recycled content PPS and chopped carbon fiber, which in turn is recyclable 27

Award-Winning Seat Design Version 2 Version High-speed production process developed to produce seat frame Seatback molded from recycled PPS and carbon fiber Seatback drilled for rivets and joined to frame Hollow braided frame (formed from PPS / carbon braided tapes) behind seatback 28

Award-Winning Seat Design System won the JEC Thermoplastic Composites award in April 2011 Currently in production for aerospace seat suppliers by Cutting Dynamics using a commercial viable process. Thermoplastics 29

Award-Winning Seat Design Benefits of modular seatback system vs. Aluminum 30% lighter Meets functional mechanical performance Cost competitive vs. Thermosets Lighter parts Non-toxic manufacturing process Fully recyclable (in-plant and post-consumer) Much faster manufacturing process with less post-mold finishing Eliminates fasteners and adhesives with welding process 30

Award-Winning Seat Design Benefits of modular seatback system Meets aerospace industry s strict flame/smoke/toxicity requirements without halogenated flame retardants Lower cost vs thermoset due to high throughput process Significant weight reduction per aircraft 31 Addresses Needs of Both Aerospace and Automotive Industries

Summary Both aerospace and automotive need seat options that Offer comparable or better mechanical performance while lowering weight and costs Comply with cabin safety requirements Meet production volumes Reduce VOCs, carbon emissions, energy use Improve passenger comfort New thermoplastic PPS/carbon modular seatback system answers these needs and more 32

NOTICE TO USERS: Information is current as of September 13, 2011 and is subject to change without notice. The information contained in this publication should not be construed as a promise or guarantee of specific properties of our products. Any determination of the suitability of a particular material and part design for any use contemplated by the user is the sole responsibility of the user. We strongly recommend that users seek and adhere to the manufacturer s current instructions for handling each material they use. Any existing intellectual property rights must be observed. 2011 Ticona. Except as otherwise noted, trademarks are owned by Ticona or its affiliates. Fortron is a registered trademark of Fortron Industries, LLC. 33

Thank You For more information, please contact: Bob Newill Ticona Engineering Polymers Tel (248) 377-6870 Cell (248) 766-5048 robert.newill@ticona.com 34