Sustainable valorisation of (biomass) residue in industry leads to a Biobased Economy. Ir. Kees W. Kwant

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Sustainable valorisation of (biomass) residue in industry leads to a Biobased Economy Ir. Kees W. Kwant

Contents Biobased Economy Industrial approach Present use of biomass in the Netherlands The Biorefinery approach Examples of projects 2

Global Biomass Resources [EJ] Photosynthesis Above Ground Total Extracted For human use Total Deployed Edible Crop Harvest Nutritianal Need 3

World Carbon based Resources (2010) [EJ] [EJ] Fossil Biobased Primary use End Use Primary use End Use Extracted 432 342 Deployed 426 222 Harvest 187 30 Feed 124 El.&Heat 152 57 30 na Fuels/others nonenergy 275 235 6 na 33 na na 4 Ref: van Beeck, N., Moerkerken, A., Kwant, K.W., Stuij B. (2014). "An innovative perspective: Transition towards a bio-based economy". In: Bundschuh, J. and Chen, G. (Editors). Sustainable Energy Solutions in Agriculture, Taylor & Francis Books, UK

Vision Biobased Economy Sustainable Production and Use of Biomass: People: food security, land rights, prosperity Planet: soil, water, air, GHG, biodiversity Profit: businesscases Proven Sustainable Biomass does not come automatically

Biomass Valorisation Pharma Farma Fine chemicals Gezondheid Health and en lifestyle Added value Food Voeding Food Feed performancematerialen Performance materials Fermentation, Fermentatie, commoditychemicaliën chemicals Chemicals Chemie Fertilizer, bulk chemicaliën chemicals Fuel, transportbrandstoffen transportfuels Energie Energy Fire, electriciteiten electricity and warmte heat Volume 6

Sustainable Biobased Solutions 7 Integrated Food & Materials production Smart agriculture Increased prodution Sustainable and Rural Development Local Resources and local use Tapping unused or abandoned land Smart use of biomass Circular Economy, Cascading Biorefinery Ref: http://www.sahyog-europaindia.eu/images/d2_3_strategic_advise_on_biobased_research_based_on_sahyog_inventory_v3.pdf

Principles to improve the use of Energy and Biomass Trias Energetica Energy Savings Renewable Energy Efficient Use Trias Biologica Decarbonise resources Replace fossil with Biobased Cascading, Circular chains 8

Biobased Economy part of Bioeconomy A Biobased Economy is a sustainable Economy, optimising Economic value and Natural value of biomass Bioeconomy Biobased Economy B Bioenergy by Replacing Fossil Resources 9

Results: About 70% realised with Bioenergy PJ

Bioenergy implementation Netherlands PJ

Industrial Approach Sector Integration Biorefinery

Biorefineries in the Netherlands

Biorefinery pilots the Netherlands 2010-2013 1. Dutch Crops 2. Residues 3. Import in harbours 4. aquatic biomass 14

Unbeatable beat Biorefinery - Create value for farmer - 22 25 ton/ha - Use beat, leaf, root -Pilot products for chemical industry http://www.cosun.com/en/ 15

Sugar Beet for Biobased Economy

Cosun Biobased Products ->Carboxyline CMI (Carboxy Methyl Inulin), a green antiscalant for various industries; ->Betafib MCF, natural fibers used in many different industrial products; ->CATIN (Cationic Inulin); ->Betawell special sugars, for application in cosmetic and personal care products; ->Biobased chemical building blocks, e.g. furane di-carboxylic acid; Biobased plasticizers http://cosunbiobased.com

Biomass Cascading and Valorisation Biomass cascading Suiker Unie products of sugar beet A D D E D V A L U E V O L U M E pharma, fine chemicals/ cosmetics food & feed final consumption commodity and bulk chemicals, fertilizers (transport) fuel, electricity, heat Sugar for direct use (e.g., in coffee) Sugar as ingredient (raw material for food) Beet pulp for animal feed Betacal (lime fertilizer for agricultural purposes Beet soil (soil attached to the beet) for roads, dykes Molasses for the production of yeast Beet tails and washing water for biogas (via digestion) http://cosunbiobased.com

Orgaworld, Amsterdam Recycling of organic residues (phosphates) Complete the cycle Waste heat utilization http://www.orgaworld.nl/ 19

Orgaworld: Utilisation of residues

Amsterdam Circular Economy

DSM 22

DSM 23

24

Biomass for Renewable Energy and Biobased Economy in Brasil

Study: Opportunities to increase sustainability and output in cane sector in Brasil Bagasse Fuel Fibrous products Animal feed Filter cake Fertilizer Compost Animal feed Sugar cane Cane mill Ethanol Fuel Chemical Solvent Sugar Functional foods Dextran Sweeteners Molasses Animal feed Ferm entation products Fertilizer Straw Fuel Fiber Ferm entable substrates

Present situation of sugarcane bioethanol in Brasil As far as we know - Still a large number of mills have a low efficiency of the power plant, due to limited access to grid - Existing scheme to improve CHP in mills does not cover all plants - Under utilisation of straw from the field - -> Potential to increase harvest and outputs from the mills and improve GHG balance

Potential Availability of excess biomass: Straw With increased mechanical harvesting, the tops and leaves can be collected Straw = 30% by mass of the produced sugarcane Sustainable harvesting allows for 50% straw to be removed from field (need for nutrient recycling) Based on harvest season 2008/2009 (648 Mtonne cane) Assuming 100% green harvesting (no burning) potential yield 97 Mtonne straw (mc 50%) or 870 PJ and in 2020 about ¼ could be realised: 210 PJ 28

Possibilities of additional output from existing plants By 1. improving efficiency of boiler/chp 2. Process Optimisation (Pinch analysis) Option Biomass available Mtonne Pellets PJ Efficiency improvements of boilers / CHP 107 Mtonnes bagasse 54 884 Efficiency improvements in process demand 75 Mtonnes bagasse 37 616 Or: Second Generation bioethanol; 25 liter/ton cane -> total additional 15 billion liter

Other applications of excess bagasse Bagasse can be used as a component in animal feed. Such synergies between food and energy production offer real measures for reducing the risk of indirect land-use change (ILUC) 1 Bagasse could be used as a heat source in other industrial sectors, such as the steel industry, which already uses charcoal for about a third of its energy needs (CGEE 2008). Sugargane biomass can also be used for high-value applications such as biochemistry, as is illustrated by the recent deal between European Solvay and the Brazilian National Bioethanol Science and Technology Laboratory (CTBE) to develop chemical routes for high-added value molecules => mills as bio-refineries

Netherlands: CHP experience: more than 50% of the power from CHP Total installed capacity in 2009: 13GW electrical and 19GW thermal. Centralised installations (mainly power plants): 5.4 MW (41%) Decentralized Total installed electrical installations capacity: 7.6 13GWe MW (59%) Total installed thermal capacity: 19GWth Gas turbine, 8% Others, 0% Others, 0% Gas engine, 28% Gas turbine, 18% Gas engine, 25% CCGT plant, 44% Steam turbine, 18% Steam turbine, 20% CCGT plant, 39%

MWe Netherlands: CHP plants in agriculture and industry 6000 5000 4000 Decentralized 3000 2000 Others Gas turbine CCGT plant Steam turbine Gas engine 1000 0 Centralized Agriculture Industry Other

Possibilities for cooperation Agronomic improvements in the sugarcane, recycling of nutrients Densification of the biomass through pre-treatment technologies like torrefaction and pelletisation Logistics and infrastructure development Sustainability issues and regulations that could hamper access to (European) markets (ILUC mitigation) Research and development, especially in the field of second generation ethanol and biobased chemicals Energy system analysis and implementation of CHP by matching to heat demand in greenhouses and built environment.

Conclusion

Conclusion Large volumes of unused biomass residues are available Technologies for valorisation of residues exist or are being developed Unique opportunities for collaboration between Netherlands and Brasil

Questions? Kees.Kwant@rvo.nl