Water Extraction from Fossil Fuel-Fired Power Plant Flue Gas

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Water Extraction from Fossil Fuel-Fired Power Plant Flue Gas ACC Users Group Workshop Las Vegas, November 12 th & 13 th 2009 Dr. Bruce Folkedahl Energy & Environmental Research Center University of North Dakota

What Does the EERC Do? The EERC is recognized as one of the world's leading developers of: Cleaner, more efficient and innovative energy technologies to guarantee clean, reliable energy supplies for the United States and the world. Environmental technologies to protect and clean our air, water, and soil. The EERC is a research, development, demonstration, and commercialization center. The EERC vigorously maintains a nonadvocacy position. The EERC enhances any guarantee.

EERC Facilities

Providing Strategic Solutions to Real-World Problems The EERC provides practical, cost-effective solutions to today's most critical energy and environmental issues and challenges. Our research portfolio includes: Clean coal technologies Coalbed methane Underground coal gasification Emission control SO x, NO x, air toxics, fine particulate, and CO 2 Mercury measurement and control CO 2 sequestration Global climate change Energy and water sustainability Energy-efficient technologies Distributed power generation various fuels Hydrogen technologies Alternative fuels Ethanol, biodiesel, biojet, and strategic fuels for the military Biomass Wind energy Water management Flood prevention Waste utilization Contaminant cleanup Advanced analytical technologies/extraction technologies Pesticides and neurological diseases

Opportunity is missed by most people because it comes dressed in overalls and looks like work. Thomas Edison

Water Permit Denied! Power Project Cancelled Water Is the Next Regulatory Frontier!

GPM Water Current State-of-the-Art 300 200 100 0-100 -200-300 -400 2700 Wet Condenser + Cooling tower Technology 250 Typical Water Consumption (2X1 501F Combined Cycle) Air- Cooled Condenser 190 Optimum Air- Cooled Condenser Even after incorporating an aircooled condenser with usage optimization, water consumption is approximately 190 gpm (273,000 gallons per day). Can Water Consumption Be Reduced to Zero? Are There Alternative Sources of Water?

What Can Be Done? Liquid Desiccant Dehumidification System Flue gas water recovery system Desiccant based Power plants can reduce or eliminate water from outside sources Fitted on any power plant that burns carbonaceous or hydrogeneous fuels Retrofit and greenfield applicable

The Liquid Desiccant Dehumidification (LDDS) Process Non- Condensables Dry Flue Gas Air Cooled Condenser Absorber Forwarding Pump Tank Recovered Water Cooler Water Rich Flue Gas Water Vapor Desiccant Treatment Weak Desiccant Weak Pump Regenerator Strong Pump Trace Contaminants Strong Desiccant

Alternative Water Source Gas-Fired Plants Across ambient range Evap. cooling adds more IGCC plus 25% 2x1 F Class NGCC

Potential Water Available (coal) Water Content of Flue Gas A 700-MW coal plant flue gas may contain approximately 1000 2400 equivalent liquid GPM of water. Varies with coal moisture. Varies with treatment.

Pilot NG Test Results

Proof of Concept Pilot Test Results Summary Pilot Test Results Complete system with regeneration demonstrated Natural gas and coal demonstrated System stability automatic operation demonstrated Desiccant carryover undetectable

Water Prices Are Rising Example: Rio Grande Is WETEX Economically Viable? $/acre foot Source: University of New Mexico

Costs of Substitute Technologies Conservative Assumptions SYSTEM Δ Capital Expense Δ Water Cost Total Wet Cooling Tower BASE BASE BASE Dry Cooling Tower $26.6 -$27 -$0.4 Air-Cooled Condenser $14.3 -$27 -$12.7 WETEX with ACC $25.3 -$46 -$20.7 In millions of dollars NPV using today s prices, 3.5% inflation, 10% discount 25-year plant life Wet cooling tower cost is $4 million Wet cooling tower water cost NPV 25 years $46 million Water cost $0.003/gal for raw water, $0.05/gal for demin. water WETEX enables $18 million. Savings on demin. water Using Rio Grande prices, the savings from WETEX with ACC would be $127 million.

SIEMENS Market Research Commercial Market Vision New Air-Cooled Power Plants Worldwide Number of New Plants 200 180 160 140 120 100 80 60 40 20 0 11 18 33 68 1980-1984 1985-1989 1990-1994 1995-1999 2000-2004 2004-2009 2010-2014 93 Number of New Plants Built with Dry Cooling

Next Steps? Subscale Demonstration at Power Plant Dried Flue Gas Exits Absorber

Conclusions 30% water recovery is achievable/50% is feasible. Potential for gas-, coal-, and syngas-fired plants. Equipment can be designed and operated to meet variable performance and cost targets. Water quality is exceptional, similar to R.O. outlet.

Thank You Whiskey is for drinking, water is for fighting -Mark Twain Energy & Environmental Research Center World Wide Web: www.undeerc.org E-Mail: bfolkedahl@undeerc.org Telephone No. (701) 777-5243 Fax No. (701) 777-5181 Dr. Bruce Folkedahl Senior Research Manager