Dichlorvos (2,2-dichlorovinyl dimethyl phosphate) Northlands Business Park Newmarket Road North Riding 2162

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Acorn Products (PTY) Ltd. SAFETY DATA SHEET Version 1.0 Revision Date: May 2014 Date of issue: May 2009 1. IDENTIFICATION OF THE SUBSTANCE Product name: Brand: Active: Synonyms: Product type: Recipe: Company: Physical Address: Postal address: P.O. Box 82 Strubens Valley 1735 Telephone: +27 11 704 6100 Vapona Agricultural Strip Vapona Dichlorvos (2,2-dichlorovinyl dimethyl phosphate) DDVP VP (Vapour Releasing Product) TTV103 Acorn Products (PTY) Ltd. Units 13 and 14 Corner Mini s Northlands Business Park Newmarket Road North Riding 2162 Fax: +27 11 704 6099 Emergency Phone #: +27 83 251 2262 contact Mrs. Gail Downing 2. PHYSICAL/CHEMICAL CHARACTERISTICS Form: Odour: Colour: Vapour Pressure: ph: Density: Solubility: Viscosity: Boiling range: Melting range: Impregnated strip with aromatic odour Aromatic Yellow plastic strip Vapona is hydrolyzed in aqueous solution 3. FIRE HAZARD AND CONTROL Flash point: Ignition Temperature: Explosive limits: Extinguishing media: Non-flammable strip CO2, Dry powder Vapona Agricultural Strip Page 1 of 4

Combustion gases: Hazardous decomposition: Thermal decomposition: Incompatibility: Protection against fire: Harmful fumes may be emitted if involved in sufficient burning or external heat. Dimethyl hydrogen phosphate, dichloroacetaldehyde, dichlorvos vapour may be formed. Vapour is volatile and decomposes at elevated temperatures. Vapona reacts to alkaline products (Bordeaux mixture, lime sulphur), plain mild steel or tinplate containers, plastic bottles. Wear protective clothing and self-contained breathing apparatus. Confine the use of water spray to cooling unaffected stock. 4. COMPOSITION/INFORMATION ON INGREDIENTS Dichlorvos: Plasisiser: Stabiliser: Inerts: 221 g 675 g 53 g to 1.0 Kg 5. FIRST AID MEASURES Signs and symptoms of poisoning: Skin contact: Eye contact: Ingestion: Emergency antidote: Inhalation: Excessive sweating, salivation, headache, weakness, giddiness, nausea, stomach pains, blurred vision, muscle twitching, coma, respiratory arrest. Remove contaminated clothing immediately and wash affected skin with soap and water. Obtain medical attention. Flush eyes thoroughly with water and obtain medical attention. Poisonous if ingested. Do not induce vomiting Atropine sulphate. Remove to fresh air. If poisoning symptoms occur, obtain medical attention immediately. Medical advice: VAPONA is a cholinesterase inhibitor. Atropine is the emergency antidote. In all cases of sever intoxication and as early as possible inject, preferably IV atropine sulphate 2-4 mg for adults (0.04 mg/kg to 0.08 mg/kg body weight for children), every 3-10 minutes until adequately atropinised, as shown by dilated pupils, flushing of the skin, dry mouth. If the IM route has to be used, take care not to overdose. If available also administer, preferably within 48 hours, an oxime, e.g. 2-PAM, P2S (CONTRATHION) or TOXOGONIN, according to manufactures instructions. Morphine or other contraindications: Keep airway clear and watch respiration. Artificial respiration may be required. Observe patient in hospital for at least 24 hours. Diagnosis should be confirmed by estimating the cholinesterase activity in the blood. Vapona Agricultural Strip Page 2 of 4

6. TOXICOLOGICAL INFORMATION Acute toxicity LD50 Rat oral (mg/kg): 160 Rat Dermal (mg kg): 300 Inhalation LC% Rate (4hr) mg/l): > 0.2 Occupational exposure limits: Dichlorvos skin: ACGIH-TLV/TWA: 1 mg/m³ 7. HANDLING AND STORAGE Handling: Application: Leaks/Spills: Storage: Avoid contact with skin, eyes, nose and mouth. Wear rubber gloves when handling. Wash hands with soap and water after handling and before eating, drinking or smoking. Do not open sachet until immediately before use. Clean contaminated surfaces with a detergent solution Store below 25 C away from direct sunlight. Keep out of reach of children. Store away from food and feedstuffs. 8. REACTIVITY DATA Stability: 2 year shelf life from date of manufacture 9. ECOLOGICAL INFORMATION Degradability: Hazards: Other effects: Disposal: Readily biodegradable. Can be decomposed chemically, especially under alkaline conditions Highly toxic to fish, mammals, birds and bees Toxic to aquatic invertebrates and wildlife Open dumping is prohibited 10. DISPOSAL CONSIDERATIONS Never re-use the empty container for any purpose but destroy it and dispose of it in a safe manner. Burn contaminated waste material in a proper incinerator or bury in an approved dump where there is no risk of contaminating ground or surface water. Before burying, mix with sodium carbonate (washing soda) crystals, to assist in the product s decomposition. 11. TRANSPORT INFORMATION None dangerous cargo Keep dry Keep separated from food and feedstuffs Vapona Agricultural Strip Page 3 of 4

12. REGULATORY INFORMATION Falls under the Department of Agriculture South Africa act 36 of 1947 registration no. L1785. 13. OTHER INFORMATION The data here is based on current knowledge and experience. The purpose of this document is to describe the product in terms of safety requirements. The data does not signify any warrant to the product properties. Vapona Agricultural Strip Page 4 of 4

Acorn Products (PTY) Ltd. SAFETY DATA SHEET Version 1.0 Revision Date: May 2014 Date of issue: May 2009 1. IDENTIFICATION OF THE SUBSTANCE Product name: Brand: Active: Synonyms: Product type: Recipe: Company: Physical Address: Postal address: P.O. Box 82 Strubens Valley 1735 Telephone: +27 11 704 6100 Vapona Cupboard Exterminator Vapona Dichlorvos (2,2-dichlorovinyl dimethyl phosphate) DDVP VP (Vapour Releasing Product) TTV104 Acorn Products (PTY) Ltd. Units 13 and 14 Corner Mini s Northlands Business Park Newmarket Road North Riding 2162 Fax: +27 11 704 6099 Emergency Phone #: +27 83 251 2262 contact Mrs. Gail Downing 2. PHYSICAL/CHEMICAL CHARACTERISTICS Form: Odour: Colour: Vapour Pressure: ph: Density: Solubility: Viscosity: Boiling range: Melting range: Impregnated strip with aromatic odour Aromatic Yellow plastic strip Vapona is hydrolyzed in aqueous solution 3. FIRE HAZARD AND CONTROL Flash point: Ignition Temperature: Explosive limits: Extinguishing media: Non-flammable strip CO2, Dry powder Vapona Cupboard Exterminator Page 1 of 3

Combustion gases: Hazardous decomposition: Thermal decomposition: Incompatibility: Personal Protective Equipment: Harmful fumes may be emitted if involved in sufficient burning or external heat. Smoke and fumes are hazardous through inhalation or absorption through the skin. Dimethyl hydrogen phosphate, dichloroacetaldehyde, dichlorvos vapour may be formed. Vapour is volatile and decomposes at elevated temperatures. Vapona reacts to alkaline products (Bordeaux mixture, lime sulphur), plain mild steel or tinplate containers, plastic bottles. 4. COMPOSITION/INFORMATION ON INGREDIENTS Dichlorvos: Plasisiser: Stabiliser: Inerts: 221 g 675 g 53 g to 1.0 Kg 5. FIRST AID MEASURES Ingestion: Poisonous if ingested. Do not induce vomiting. 6. TOXICOLOGICAL INFORMATION Poisonous if ingested. 7. HANDLING AND STORAGE Hand protection: Application: Leaks/Spills: Storage: Store below 25 C away from direct sunlight. Keep out of reach of children. Store away from food and feedstuffs. 8. REACTIVITY DATA Stability: 2 year shelf life from date of manufacture. 9. ECOLOGICAL INFORMATION Degradability: Readily biodegradable. Ecologically friendly. Vapona Cupboard Exterminator Page 2 of 3

Disposal: Open dumping is prohibited. For large quantities use a suitable incineration plant in accordance with official regulations. 10. DISPOSAL CONSIDERATIONS Never re-use the empty container for any purpose but destroy it and dispose of it in a safe manner. 11. TRANSPORT INFORMATION None dangerous cargo Keep dry Keep separated from food and feedstuffs 12. REGULATORY INFORMATION Falls under the Department of Agriculture South Africa act 36 of 1947 registration no. L1785. 13. OTHER INFORMATION The data here is based on current knowledge and experience. The purpose of this document is to describe the product in terms of safety requirements. The data does not signify any warrant to the product properties. Vapona Cupboard Exterminator Page 3 of 3

Acorn Products (PTY) Ltd. SAFETY DATA SHEET Version 1.0 Revision Date: May 2014 Date of issue: May 2009 1. IDENTIFICATION OF THE SUBSTANCE Product name: Brand: Active: Synonyms: Product type: Recipe: Company: Physical Address: Postal address: P.O. Box 82 Strubens Valley 1735 Telephone: +27 11 704 6100 Vapona Room Exterminator Vapona Dichlorvos (2,2-dichlorovinyl dimethyl phosphate) DDVP VP (Vapour Releasing Product) TTV105 Acorn Products (PTY) Ltd. Units 13 and 14 Corner Mini s Northlands Business Park Newmarket Road North Riding 2162 Fax: +27 11 704 6099 Emergency Phone #: +27 83 251 2262 contact Mrs. Gail Downing 2. PHYSICAL/CHEMICAL CHARACTERISTICS Form: Odour: Colour: Vapour Pressure: ph: Density: Solubility: Viscosity: Boiling range: Melting range: Impregnated strip with aromatic odour Aromatic Yellow plastic strip Vapona is hydrolyzed in aqueous solution 3. FIRE HAZARD AND CONTROL Flash point: Ignition Temperature: Explosive limits: Extinguishing media: Non-flammable strip CO2, Dry powder Vapona Room Exterminator Page 1 of 3

Combustion gases: Hazardous decomposition: Thermal decomposition: Incompatibility: Personal Protective Equipment: Harmful fumes may be emitted if involved in sufficient burning or external heat. Smoke and fumes are hazardous through inhalation or absorption through the skin. Dimethyl hydrogen phosphate, dichloroacetaldehyde, dichlorvos vapour may be formed. Vapour is volatile and decomposes at elevated temperatures. Vapona reacts to alkaline products (Bordeaux mixture, lime sulphur), plain mild steel or tinplate containers, plastic bottles. 4. COMPOSITION/INFORMATION ON INGREDIENTS Dichlorvos: Plasisiser: Stabiliser: Inerts: 221 g 675 g 53 g to 1.0 Kg 5. FIRST AID MEASURES Ingestion: Poisonous if ingested. Do not induce vomiting. 6. TOXICOLOGICAL INFORMATION Poisonous if ingested. 7. HANDLING AND STORAGE Hand protection: Application: Leaks/Spills: Storage: Store below 25 C away from direct sunlight. Keep out of reach of children. Store away from food and feedstuffs. 8. REACTIVITY DATA Stability: 2 year shelf life from date of manufacture. 9. ECOLOGICAL INFORMATION Degradability: Readily biodegradable. Ecologically friendly. Vapona Room Exterminator Page 2 of 3

Disposal: Open dumping is prohibited. For large quantities use a suitable incineration plant in accordance with official regulations. 10. DISPOSAL CONSIDERATIONS Never re-use the empty container for any purpose but destroy it and dispose of it in a safe manner. 11. TRANSPORT INFORMATION None dangerous cargo Keep dry Keep separated from food and feedstuffs 12. REGULATORY INFORMATION Falls under the Department of Agriculture South Africa act 36 of 1947 registration no. L1785. 13. OTHER INFORMATION The data here is based on current knowledge and experience. The purpose of this document is to describe the product in terms of safety requirements. The data does not signify any warrant to the product properties. Vapona Room Exterminator Page 3 of 3