Chemistry/Science Unit C1: Chemistry in Our World

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Write your name here Surname Other names Edexcel GCSE Centre Number Chemistry/Science Unit C1: Chemistry in Our World Candidate Number Wednesday 9 November 2011 Morning Time: 1 hour You must have: Calculator, ruler Foundation Tier Paper Reference 5CH1F/01 Total Marks Instructions Use black ink or ball-point pen. Fill in the boxes at the top of this page with your name, centre number and candidate number. Answer all questions. Answer the questions in the spaces provided there may be more space than you need. Information The total mark for this paper is 60. The marks for each question are shown in brackets use this as a guide as to how much time to spend on each question. Questions labelled with an asterisk (*) are ones where the quality of your written communication will be assessed you should take particular care with your spelling, punctuation and grammar, as well as the clarity of expression, on these questions. P40176A 2011 Edexcel Limited. 1/1/1/1/ Advice Read each question carefully before you start to answer it. Keep an eye on the time. Try to answer every question. Check your answers if you have time at the end. *P40176A0120* Turn over

The Periodic Table of the Elements 1 2 3 4 5 6 7 0 Key 1 H hydrogen 1 4 He helium 2 7 Li lithium 3 9 Be beryllium 4 relative atomic mass atomic symbol name atomic (proton) number 11 B boron 5 12 C carbon 6 14 N nitrogen 7 16 O oxygen 8 19 F fluorine 9 20 Ne neon 10 23 Na sodium 11 24 Mg magnesium 12 27 Al aluminium 13 28 Si silicon 14 31 P phosphorus 15 32 S sulfur 16 35.5 Cl chlorine 17 40 Ar argon 18 39 K potassium 19 40 Ca calcium 20 45 Sc scandium 21 48 Ti titanium 22 51 V vanadium 23 52 Cr chromium 24 55 Mn manganese 25 56 Fe iron 26 59 Co cobalt 27 59 Ni nickel 28 63.5 Cu copper 29 65 Zn zinc 30 70 Ga gallium 31 73 Ge germanium 32 75 As arsenic 33 79 Se selenium 34 80 Br bromine 35 84 Kr krypton 36 85 Rb rubidium 37 88 Sr strontium 38 89 Y yttrium 39 91 Zr zirconium 40 93 Nb niobium 41 96 Mo molybdenum 42 [98] Tc technetium 43 101 Ru ruthenium 44 103 Rh rhodium 45 106 Pd palladium 46 108 Ag silver 47 112 Cd cadmium 48 115 In indium 49 119 Sn tin 50 122 Sb antimony 51 128 Te tellurium 52 127 I iodine 53 131 Xe xenon 54 133 Cs caesium 55 137 Ba barium 56 139 La* lanthanum 57 178 Hf hafnium 72 181 Ta tantalum 73 184 W tungsten 74 186 Re rhenium 75 190 Os osmium 76 192 Ir iridium 77 195 Pt platinum 78 197 Au gold 79 201 Hg mercury 80 204 Tl thallium 81 207 Pb lead 82 209 Bi bismuth 83 [209] Po polonium 84 [210] At astatine 85 [222] Rn radon 86 [223] Fr francium 87 [226] Ra radium 88 [227] Ac* actinium 89 [261] Rf rutherfordium 104 [262] Db dubnium 105 [266] Sg seaborgium 106 [264] Bh bohrium 107 [277] Hs hassium 108 [268] Mt meitnerium 109 [271] Ds darmstadtium 110 [272] Rg roentgenium 111 Elements with atomic numbers 112-116 have been reported but not fully authenticated * The lanthanoids (atomic numbers 58-71) and the actinoids (atomic numbers 90-103) have been omitted. The relative atomic masses of copper and chlorine have not been rounded to the nearest whole number. 2 *P40176A0220*

Answer ALL questions. Some questions must be answered with a cross in a box. If you change your mind about an answer, put a line through the box and then mark your new answer with a cross. Problems caused by acids 1 (a) Hydrochloric acid is produced in the stomach. When too much acid is produced it can cause indigestion. (i) Give a reason why hydrochloric acid is present in the stomach. (ii) Complete the sentence by putting a cross ( ) in the box next to your answer. The formula of hydrochloric acid is A HCl B H 2 Cl C HCl 2 D HCl 2 *P40176A0320* 3 Turn over

(iii) Which of these hazard symbols should be used on a container of dilute hydrochloric acid to show that it is an irritant? Put a cross ( ) in the box next to your answer. A B C D (b) Indigestion can cause pain in the chest. Indigestion tablets can be taken to relieve this pain. (i) Explain how indigestion tablets relieve this pain. 4 *P40176A0420*

(ii) Complete the sentence by putting a cross ( ) in the box next to your answer. Some indigestion tablets contain magnesium carbonate. When magnesium carbonate is added to dilute hydrochloric acid, a salt is formed. The name of the salt formed is A magnesium oxide B magnesium nitrate C magnesium chloride D magnesium sulphate (c) Waste gases from coal-fired power stations can be acidic. These waste gases can be passed through calcium carbonate. Explain how the calcium carbonate helps to reduce the amount of acid rain. (Total for Question 1 = 8 marks) *P40176A0520* 5 Turn over

Crude oil products 2 Crude oil is separated into fractions. Crude oils from different oil wells contain different percentages of the fractions. The table shows the percentages of the fractions in crude oils from three different oil wells. percentage of fraction in crude oil from fraction oil well A oil well B oil well C gases 1 6 9 petrol 2 15 24 kerosene 6 14 20 diesel oil 7 10 16 fuel oil 26 28 30 bitumen 58 27 1 (a) Give the name of the process that is used to separate crude oil into fractions. (b) Crude oil from which oil well contains the most petrol? (c) Which fraction is present in almost the same percentage in the crude oils from all three oil wells? 6 *P40176A0620*

(d) Complete the sentence by putting a cross ( ) in the box next to your answer. Kerosene is used as a fuel for A cars B large ships C jet aircraft D power stations (e) Petrol fractions contain the hydrocarbon octane, C 8 H 18. Explain what is meant by the term hydrocarbon. (f) One product obtained when hydrocarbons burn in air is carbon dioxide. Describe a test to show that a gas is carbon dioxide. (Total for Question 2 = 9 marks) *P40176A0720* 7 Turn over

3 (a) Ethene is an unsaturated hydrocarbon. Ethene and poly(ethene) State what is meant by the term unsaturated. (b) Complete the sentences by putting a cross ( ) in the box next to your answer. (i) When bromine water is shaken with ethene, it changes colour. The bromine water becomes A orange B brown C colourless D clear (ii) The formula of ethene is A CH 4 B C 2 H 4 C C 2 H 6 D C 3 H 8 8 *P40176A0820*

(c) A gas containing ethene can be produced from liquid paraffin using this apparatus. ceramic wool soaked in liquid paraffin porous pot gas heat heat water Describe how liquid paraffin becomes ethene in this experiment. (3) (d) Ethene is used to make poly(ethene). Describe how ethene molecules form poly(ethene) molecules. *P40176A0920* 9 Turn over

(e) Waste poly(ethene) can cause problems. Explain the problems caused by waste poly(ethene). (Total for Question 3 = 10 marks) 10 *P40176A01020*

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The atmosphere 4 (a) The bar chart shows the percentage of gases in the Earth s atmosphere. percentage 100 90 80 70 60 50 40 30 20 10 0 gas A oxygen carbon dioxide + other gases (i) Give the name of gas A. (ii) Which of the gases listed below is naturally present in the atmosphere? Put a cross ( A argon B carbon C chlorine D hydrogen ) in the box next to your answer. (b) (i) Complete the sentence by putting a cross ( ) in the box next to your answer. The gases in the Earth s earliest atmosphere were thought to originate from A plants B the ocean C volcanoes D ice caps 12 *P40176A01220*

(ii) Explain how the growth of primitive plants changed the percentage of oxygen and carbon dioxide in the Earth s early atmosphere. *(c) Experiments can be carried out to find the volume of oxygen in a given volume of air. When hot, copper reacts with oxygen. In one experiment the following apparatus is used. At the start of the experiment, 100 cm 3 of air is in gas syringe A. The air is passed backwards and forwards over the heated copper. air copper gas syringe A heat gas syringe B Describe how the apparatus can be used to show that the 100 cm 3 of air contained 21 cm 3 of oxygen. (6) (Total for Question 4 = 11 marks) *P40176A01320* 13 Turn over

Calcium carbonate 5 The picture shows a piece of limestone rock containing fossils. (a) (i) Complete the sentence by putting a cross ( ) in the box next to your answer. Limestone is a form of calcium carbonate. The elements present in calcium carbonate are A calcium and oxygen only B calcium and carbon only C calcium and carbonate only D calcium, carbon and oxygen only (ii) Limestone is a sedimentary rock. Explain how fossils are formed in limestone. (3) 14 *P40176A01420*

(b) Marble is also a form of calcium carbonate. It is a metamorphic rock. Explain how marble is formed from limestone. (c) (i) Complete the sentence by putting a cross ( ) in the box next to your answer. When calcium carbonate is heated it reacts to form calcium oxide and carbon dioxide. This reaction is an example of A electrolysis B incomplete combustion C cracking D thermal decomposition (ii) Write the word equation for this reaction. (d) Describe what you would see when water is added drop by drop to a sample of cold calcium oxide. (Total for Question 5 = 10 marks) *P40176A01520* 15 Turn over

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6 The pie chart shows the main uses of copper. Metals as electrical wiring other uses in motors and generators for pipes and plumbing materials (a) Use the pie chart to give the biggest use for copper. (b) Copper can be extracted from a naturally occurring substance called malachite. State the name given to naturally occurring substances from which metals are extracted. *P40176A01720* 17 Turn over

(c) Overhead power cables supported on pylons are used to carry electricity. The table shows information about three metallic substances. metallic substance density cost per / kg m 3 tonne / relative strength relative ability to conduct electricity relative resistance to corrosion copper 8920 5279 high very good good aluminium 2700 1425 high good good steel 7820 505 very high good poor (i) The pylons are made of steel. Use information from the table to explain which properties of steel make it the most suitable of these three metals for the pylons. 18 *P40176A01820*

(ii) Use information from the table to explain which properties of aluminium make it more suitable than copper for making overhead power cables. *(d) Iron for making steel, copper and aluminium is obtained from substances found in the Earth s crust. The metals are made into many useful things. When no longer required the metal articles are thrown away as waste or recycled. Explain why it is important to recycle these metals rather than put them in general household waste. (6) (Total for Question 6 = 12 marks) TOTAL FOR PAPER = 60 MARKS *P40176A01920* 19

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