SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name Product Use Description Synonyms Fungicide TERRAZOLE 350 WP SOIL FUNGICIDE Company Chemtura Corporation 199 Benson Road Middlebury, CT 06749 United States of America Telephone (US) +1 866-430-2775 Emergency telephone number CHEMTREC (24 hours) 800-424-9300 Chemtura Corporation Emergency Response CHEMTURA 800-292-5898 For additional emergency telephone numbers see section 16 of the Safety Data Sheet. Prepared by 02/16/2012 Product Safety Department (US) +1 866-430-2775 MSDSRequest@chemtura.com SECTION 2. HAZARDS IDENTIFICATION Emergency Overview CAUTION! Form powder Colour clear grey Odour pungent Hazard Summary OSHA Hazards May be harmful if swallowed, in contact with skin or if inhaled. May cause eye and skin irritation. May cause liver effects Limited evidence of a carcinogenic effect. COMBUSTIBLE DUST TOXIC BY INHALATION. MODERATE EYE IRRITANT CARCINOGEN SAP 6.0 1 / 9 SDS Number 400000003983
Carcinogenicity IARC OSHA NTP ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components Component / CAS-No. 2593-15-9 sodium 2-[methyloleoylamino]ethane-1-sulphonate 137-20-2 Weight percent 35 % < 10 % SECTION 4. FIRST AID MEASURES First aid procedures Inhalation Skin contact Remove to fresh air. Give oxygen or artificial respiration if needed. Call a POISON CENTER or doctor/ physician. Remove contaminated clothing and shoes. Wash off immediately with plenty of water for at least 15 minutes. Call a POISON CENTER or doctor/ physician. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after 5 minutes, then continue rinsing eye. Call a POISON CENTER or doctor/ physician. Ingestion Call a physician or poison control centre immediately. If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. SECTION 5. FIREFIGHTING MEASURES Flammable properties Flash point > 230 F (> 110 C) Ignition temperature 671 F (355 C) SAP 6.0 2 / 9 SDS Number 400000003983
Fire fighting Suitable extinguishing media Unsuitable extinguishing media Extinguishing media - large fires Alcohol-resistant foam Small fires Carbon dioxide (CO2) Dry chemical Water spray Water spray jet Do not discharge extinguishing waters into streams, rivers and lakes. Protective equipment and precautions for firefighters Specific hazards during Burning produces noxious and toxic fumes. firefighting Special protective equipment Body covering protective clothing, full "turn-out" gear. for firefighters Self-contained breathing apparatus. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Methods for containment / Methods for cleaning up Evacuate unnecessary personnel. Avoid all contact with material. Wear suitable protective equipment. Prevent leaks and prevent soil / water pollution caused by leaks. Sweep up and collect in a suitable container for disposal. Avoid dust formation. In accordance with local and national regulations. SECTION 7. HANDLING AND STORAGE Handling Handling procedures Wear suitable protective equipment. Warn personnel about the dangers of the product. Keep container tightly closed. Avoid formation of dust and aerosols. Storage Requirements for storage areas and containers Keep in a dry, cool place. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Components with workplace control parameters SAP 6.0 3 / 9 SDS Number 400000003983
Components / CAS-No. Value / Basis / Update silica gel TWA 112926-00-8 OSHA P0 1989-01-19 TWA OSHA Z3 2007-01-01 Control parameters 6 mg/m3 20 million particles per cubic foot Engineering measures Personal protective equipment Eye protection Safety glasses Hand protection Impervious butyl rubber gloves Replace when worn. Respiratory protection Respirator with a dust filter SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form Colour Odour powder clear grey pungent Safety data Flash point > 230 F (> 110 C) Ignition temperature 671 F (355 C) ph 8 Vapour pressure 0.0143 hpa (1.430 mmhg) at 77 F (25 C) Bulk density Water solubility Partition coefficient n- octanol/water 0.3 kg/m3 Note dispersible log Pow 3.37 SAP 6.0 4 / 9 SDS Number 400000003983
SECTION 10. STABILITY AND REACTIVITY Conditions to avoid Materials to avoid Hazardous decomposition products Hazardous reactions Remarks Contamination Remarks Oxidizing agents Note Carbon oxides nitrogen oxides (NOx) None known. SECTION 11. TOXICOLOGICAL INFORMATION Acute oral toxicity LD50 3,300 mg/kg Species rat Acute inhalation toxicity LC50 > 2.8 mg/l Exposure time 4 h Species rat Acute dermal toxicity LD50 > 2,000 mg/kg Species rabbit Skin irritation Species rabbit Result No skin irritation Eye irritation Species rabbit Result Moderate eye irritation Sensitisation Species guinea pig Classification May cause sensitization by skin contact. Result Causes sensitization. Toxicology Assessment CMR effects Carcinogenicity Limited evidence of a carcinogenic effect. Acute Health Hazard Chronic Health Hazard SAP 6.0 5 / 9 SDS Number 400000003983
12. ECOLOGICAL INFORMATION Toxicity to fish LC50 2.4 mg/l Exposure time 96 h Species Oncorhynchus mykiss (rainbow trout) Toxicity to daphnia and other aquatic invertebrates EC50 3.1 mg/l Exposure time 48 h Species Daphnia magna (Water flea) Toxicity to algae IC50 0.39 mg/l Exposure time 72 h Species Algae Elimination information (persistence and degradability) Biodegradability Remarks Not readily biodegradable. on ecology Additional ecological Avoid release to the environment. information SECTION 13. DISPOSAL CONSIDERATIONS Dispose of as hazardous waste in compliance with local and national regulations. Dispose of wastes in an approved waste disposal facility. SECTION 14. TRANSPORT INFORMATION DOT UN number 3077 Description of the goods Environmentally hazardous substances, solid, n.o.s. () Class 9 Packing group III ERG Code 171 IATA UN number 3077 Description of the goods Environmentally hazardous substance, solid, n.o.s. SAP 6.0 6 / 9 SDS Number 400000003983
() Class 9 Packing group III Labels 9 Environmentally hazardous yes IMDG UN number 3077 Description of the goods ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. () Class 9 Packing group III EmS Number 1 F-A EmS Number 2 S-F Marine pollutant Environmentally hazardous yes yes Not subject to ADG code when transported by road or rail when shipped in individual packs less than 500kg or litres (ADG7, Special Provision AU01) SECTION 15. REGULATORY INFORMATION OSHA Hazards CERCLA Reportable Quantity SARA 302 Reportable Quantity SARA 311/312 Hazards Combustible dust, Toxic by inhalation., Moderate eye irritant, Carcinogen Acute Health Hazard Chronic Health Hazard EPCRA - EMERGENCY PLANNING COMMUNITY RIGHT - TO - KNOW SARA 302 Reportable Quantity SARA 304 Components This material does not contain any components with a section 304 EHS RQ. SAP 6.0 7 / 9 SDS Number 400000003983
California Prop. 65 Components WARNING! This product contains a chemical known to the State of California to cause cancer. 2593-15-9 The components of this product are reported in the following inventories US.TSCA Not On TSCA Inventory DSL This product contains the following components that are not on the Canadian DSL nor NDSL lists. AICS NZIoC ENCS KECI PICCS IECSC CH INV The formulation contains substances listed on the Swiss Inventory SAP 6.0 8 / 9 SDS Number 400000003983
SECTION 16. OTHER INFORMATION HMIS Classification Health hazard 2 Chronic Health Hazard * Flammability 3 Physical hazards 0 PPIAsk supervisor or safety specialist for handling instructions NFPA Classification 3 Health hazard 2 Fire Hazard 3 Reactivity Hazard 0 2 0 Other Emergency Phone Number Latin America Brazil +55 113 711 9144 All other countries +44 (0) 1235 239 670 Mexico +52 555 004 8763 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. SAP 6.0 9 / 9 SDS Number 400000003983