FARM DIGESTERS AND MANURE PHOSPHORUS MANAGEMENT

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FARM DIGESTERS AND MANURE PHOSPHORUS MANAGEMENT March 18, 2014 Becky Larson Assistant Professor and Extension Specialist Department of Biological Systems Engineering

Gilbert, 2009. Nature.

PHOSPHORUS PRODUCTION 2.50E+08 2.00E+08 1.50E+08 1.00E+08 5.00E+07 0.00E+00 Year 1910 1921 1932 1943 1954 1965 1976 1987 1998 2009 Production Apparent consumption World production

PRICE OF PHOSPHORUS $/ton $150 $100 $50 $0 Year 1906 1913 1920 1927 1934 1941 1948 1955 1962 1969 1976 1983 1990 1997 2004 Year

ESTIMATED MANURE PHOSPHORUS PRODUCTION FROM CONFINED LIVESTOCK

WHY MANURE? 95% of phosphate rock mined in the US was used to make fertilizers and animal supplements Debate on reserves and estimated supply Increasing demand as population grows Significant amount is more difficult to extract than current sources US to see significant drop in production in 25 years Recovery and recycling have great potential Initial interest in wastewater treatment plant recovery 5 times more phosphorus in livestock waste than human waste Livestock population greater than 10 times the human population

WISCONSIN MANURE 1.26 million dairy cows (NASS 2010) Over 8 billion gallons of manure annually ~7 pounds P 2 O 5 per1,000 gallons of manure Many agricultural sources with potential for environmental impact Need for solutions which make economic sense Potential benefits to agricultural operations, environment, economics, and the public

P SUSTAINABILITY Reuse = limit purchase of P Reduce losses to environment Meet regulatory requirements

PHOSPHORUS REMOVAL MECHANISMS Chemical removal Aluminum sulfate, aluminum chloride Ferric chloride, ferric sulfate Lime Physical Separation Biological

ANAEROBIC DIGESTION No phosphorus removal!

NUTRIENTS & ANAEROBIC DIGESTION Total Phosphorus Total Phosphorus Concentration (mg/kg) 900 800 700 600 500 400 300 200 100 0 AA DDI FA ML* NH Input Output Facility Wright, et al. 2004. Preliminary Comparison of Five Anaerobic Digestion Systems on Dairy Farms in New York State

SOLID LIQUID SEPARATION Can produce multiple products of various strengths of phosphorus Must examine entire manure handling system to see benefits Numerous technologies Screw press Centrifuge Settling basins Varying cost and complexity

SOLIDS SETTLING & PHOSPHORUS Dependent upon influent solids concentration Dependent upon particle size (smaller particles are more difficult to separate)

SETTLING BASINS/STORAGE Removal of approximately 28% TP in settling basins with no addition (initial TS of ~4%)

SOLID LIQUID SEPARATION Midwest Plan Service, 2001

SEPARATOR - SCREW PRESS

SEPARATOR - CENTRIFUGE Centrifuge - Dane County Digester; Clear Horizons

SEPARATOR - BEDDING RECOVERY UNIT

PHOSPHORUS 100 80 60 40 20 0 Liquid % Solid %

PHOSPHORUS 100 80 60 40 20 0 Screw Press w/ Digester Screw Press w/o Digester Liquid % Solid %

N-P-K Concentration N (g/kg) P 2 O 5 (g/kg) K 2 O (g/kg) Manure 50 18 41 Liquid 101 27 75 Solid 15 14 8 Ratio N P 2 O 5 K 2 O Manure 3 1 2 Liquid 4 1 3 Solid 2 2 1

SCREENS

SCREENS WITH POLYMERS

DISSOLVED AIR FLOTATION Air is dissolved in the waste water stream and injected at bottom of unit R. Sheffield Fine solids are carried or floated to surface Chemical addition of polymers and flocculent is needed for optimum efficiency

CHEMICAL PRECIPITATION More effective for dissolved phosphorus Requires regular additions, large doses for manure Can be costly Can pose issues in soils Typically require polymer additions for application Significant amount of sludge production

CHEMICAL & POLYMER P SEPARATION Significant additions of chemical and polymer 80-90% TP removal Dairy manure at 0.87% & 1.5% TS Chemical additions alone cost $0.01

BIOLOGICAL ADDITION Phosphorus uptake by microorganisms L4DB microbial treatment used for study in Texas Found some decreases in TP but not dissolved reactive phosphorus Reduction of ~50% S. Rahman & S. Mukhtar, Texas A&M University

EFFICIENCY COMPARISON Technology Initial TS (%) TP Removal (%) Settling Basin ~4 28 Screw Press variable 15-24 Centrifuge variable 60 Dewatering using Geotextiles 0.71 46 Inclined Plane 53 Screens 0.4-3.2 <17 Screens with Polymers 0.4-3.2 34-65 Chemical Precipitation 0.87-1.5 80-90

COSTS Separation systems are highly variable on cost to implement Really it all comes down to end use If you are land applying, the cost of these systems has to primarily be from savings in application How far away are your fields that are not P limited? When markets begin to develop for solids this may change Possible to sell solids as bedding, compost, etc.

THANK YOU! Becky Larson ralarson2@wisc.edu (608) 890-3171