Gasification Technologies

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Concepts for clean, economic fuel and energy production Rhys Tucker, Principal Process Engineer 5th International Freiberg Conference on IGCC & XtL Technologies - IFC2012

World s largest single-train IGCC: PRENFLO Gasification Elcogas, Puertollano, Spain Feedstock: petcoke / coal with addition of biomass PRENFLO Gasifier Coal Preparation ASU New CO 2 capture Pilot Plant started-up Oct 2010 Gas Treatment Combined Cycle

Agenda Company Gasification Portfolio Joint Venture Kepco-Uhde Concepts & Projects/Plants

Facts and figures 2010/2011 History 1921 Friedrich Uhde engineering firm, Dortmund 1952 Friedrich Uhde GmbH becomes a subsidiary of Hoechst AG 1996 Acquisition of Uhde by Krupp 1997 Uhde and Krupp Koppers merge 1999 Krupp and Thyssen merge to form ThyssenKrupp AG 2011 Name changes to ThyssenKrupp Uhde GmbH Business year 2010/2011 (ThyssenKrupp Uhde Group) Order intake 1,613.3m Net sales 1,427.6m 1) Equity capital 556.6m 1) World 5,600 Workforce 2) ThyssenKrupp Uhde group (total) ~5,600 - of which ThyssenKrupp Uhde GmbH ~1,800 Europe 2,900 Germany 2,300 Engineering approx. 7.1 million capacity engineering hours/year 2) Figures incl. non-permanent staff 1) acc. to IFRS

Agenda Company Gasification Portfolio Joint Venture Kepco-Uhde Concepts & Projects/Plants

Gasification Portfolio ThyssenKrupp Uhde proprietary PRENFLO PSG PDQ Entrained-Flow HTW Fluidised Bed

PRENFLO with Steam Generation 1200 MWth, 42 bar PSG PRENFLO PSG Features dry coal/petcoke powder feed 4 horizontal co-annular burners membrane wall waste heat boiler (PSG)

PRENFLO with Direct Quench 1200 MWth, 42 bar PDQ PRENFLO PDQ Features dry coal/petcoke powder feed 4 horizontal co-annular burners membrane wall direct water quench operation pressure flexible to requirements (25-42 bar) raw gas temperature outlet of quench (200-250 C) slag lock-hopper system

Gasification Portfolio The HTW Gasifier HTW Gasification Pressurised, fluidised bed Temperature: 800-1000 C Pressure: 10-30 bar Operates below ash melting point ideal for coals with high ash melting point, biomass, lignite, waste) Refractory Lined Gasification Chamber Cyclone Recycle Line Bubbling Fluidized Bed

Gasification Portfolio ThyssenKrupp Uhde acquires HTW Gasification Technology HTW goes back to 1926 (Winkler Gasification) HTW technology was previously owned by RWE/Rheinbraun ThyssenKrupp Uhde acquires the HTW technology with all IP rights and know-how from RWE in December 2010 Main target: low-rank feedstocks, in particular: coals with high ash melting points, brown coal, lignite, wastes

Gasification Portfolio Different feedstocks require different gasification technologies PRENFLO Entrained-Flow Gasification HTW (High-Temperature Winkler) Fluidised Bed Gasification Oil Gasification

Gasification Portfolio Technology decision tree Solid Feedstock Liquid /Gas Low Rank Fuels Lignite Peat Biomass High Reactivity Low High Rank Fuels Hard Coal Petcoke Residues High Ash Content Low > 20% < 20% Normal Ash Softening Point Low H 2 -rich Product Gas CO-rich (>1200 C) (<1200 C) HTW PRENFLO PDQ PRENFLO PSG Oil gasif.

Agenda Company Gasification Portfolio Joint Venture Kepco-Uhde Concepts & Projects/Plants

Joint Venture Kepco-Uhde ThyssenKrupp Uhde and largest utility in Korea, KEPCO, form Joint Venture Company for PRENFLO PSG gasification KEPCO-Uhde Inc. established in South Korea 14 July 2011. First 2 projects launched for KEPCO-Uhde JV provides strong synergy, cost and schedule advantages Dr. Thiemann, CEO ThyssenKrupp Uhde Mr. Kim, CEO KEPCO

Joint Venture Kepco-Uhde Tasks of Kepco-Uhde Inc. Market, Design and License PRENFLO PSG for IGCC and SNG applications including CCS Research & Development Develop standard IGCC model for > 500 MW power output Improve efficiency of IGCC and SNG plants Integrate CCS solutions Combine leadership strengths of both Joint Venture partners...

Agenda Company Gasification Portfolio Joint Venture Kepco-Uhde Concepts & Projects/Plants

Concepts & Projects/Plants Example : Entrained Flow PRENFLO PDQ Integrated Process Chain for the Production of Synthetic Biofuels Feedstocks Pretreatment Gasification Gas Treatment Synthesis Wood Straw, etc. Coal Torrefaction CO-shift AGR Gasel TM Fischer- Tropsch (F-T) Synthesis and product upgrading Petcoke Milling Bio-diesel, Bio-kerosene Liquid Residues PRENFLO TM PDQ

BioTfueL a consortium of partners with complementary core businesses... R&D Technologies licensors Fuels producers From R&D to market From field to wheel Development and Demonstration of a complete B-XTL process chain

Concepts & Projects/Plants Example : Fluidised Bed HTW Integrated Process Chain for the Production of Methanol Feedstocks Pretreatment Gasification Gas Treatment Synthesis Domestic Forest Residues Grinding, Drying, Pelletising CO-Shift Methanol Synthesis Fuel Grade Methanol AGR HTW

VärmlandsMetanol, Sweden HTW Biomass to Methanol Project Uhde selected as technology supplier and EPC contractor Plant Capacity: 100,000 t/a of fuel grade methanol + district-heating 15 MWth Feedstock: Domestic forest residue, ~25 t/h Process: Fluidized bed gasification (HTW) (eq. 111 MWth)

Outlook A Cleaner Approach to Feedstocks, Fuels and Power The HTW Technology is capable to gasify a wide range of unconventional feedstocks such as: Forest and agricultural residuals; Municipal waste; Low rank and high ash content coal R&D activities in order to further increase biomass % content as feedstock; Joint Venture with KEPCO to accelarate IGCC, CCS and SNG applications; Advanced concepts for clean, economical and sustainable fuel and energy production: BioTfueL: BXTL Project, France C.GEN: IGCC with CCS in Killingholme, UK Värmlandsmethanol AB: Biomass to Methanol, Sweden Confidential Client: Licence and Services Agreement: Biomass to Liquids

Thank you for your attention Questions? ThyssenKrupp Uhde GmbH Friedrich-Uhde Strasse 15, 44141 Dortmund, Germany prenflo.uhde@thyssenkrupp.com PRENFLO Gasification Plant, Puertollano, Spain