Water Analysiss. Solutions for photometry

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Water Analysiss Reag gents OR Reag NANOCOLOR OR Solutions for photometry Bar coded tube tests with pre-dosed reagents For highest accuracy and sensitivity in water analysis NANOCONTROL for analytical quality control

NANOCOLOR reagents are analytical reagents for photometric water analysis. They are particularly suitable for precalibrated NANOCOLOR photometers from MACHEREYAGEL. Calibration data for evaluation with photometers from other manufacturers are listed in the product leaflets or are available on request. Clear step-by-step instructions guide you through the test procedures of all NANOCOLOR tests. Thus even operators with basic analytical experience can be confident in getting reliable results in no time. However, NANOCOLOR reagents are also fully recognized and appreciated by qualified analysts, who look for time saving procedures with no loss of accuracy. The instruction leaflets provide additional information on storage, interferences, analytical quality control and safety precautions. NANOCOLOR tube tests Bar code cuvette identification Precisely pre-dosed reagents in 16 mm tubes Accurate reagent dosage with NANOFIX capsules Measurement directly in the test tube Minimal exposure to chemicals Reduced reagent consumption No preparation of blank values necessary Time saving and easy procedures Fast and reliable results 20 tests per pack NANOCOLOR standard tests Measurement in 10, 20 or 50 mm cuvettes Extreme sensitivity due to large cuvette size Outstanding accuracy due to large sample volume Ready-to-use reagents Exact sample dosage in volumetric flasks Variable measuring ranges due to different cuvette sizes Easy dilutions for analysis of higher concentrations Low costs Up to 440 tests per pack NANOCONTROL standards In many labs, reagents, measuring equipment and personal handling are already subject to validation from frequent internal or external control. Therefore, numerous customers rely on our NANOCONTROL standards to obtain objective proof of the NANOCOLOR systems accuracy. NANOCONTROL standards permit easy analytical quality control, simplify the corresponding documentation and give operators confidence in their measured results. Ready-to-use standard solutions, containing one or several substances in known concentrations. Separate spiked-solutions detect possible interferences in the sample. Composition and concentrations of multistandards tailored to specific user groups e.g. waste water treatment, drinking water production or others. The standards are supplied with a document, in which the expected concentration and given tolerance range are stated for each parameter. There is also plenty of space for documentation of quality control procedures performed by the operator. Production control based on DIN/EN standards ensures reproducible accuracy of NANOCONTROL standards.

NANOCOLOR tube tests and standard tests Test Measuring ranges Wavelength No of tests Aluminium 0.01 1.00 mg/l Al 3 540 nm 200 918 02 Aluminium 07 0.02 0.70 mg/l Al 3 540 nm 19 985 098 Ammonium 0.01 2.0 mg/l NH 4 0.01 2.5 mg/l NH 4 690 nm 100 918 05 Ammonium 3 0.04 2.30 mg/l NH 4 0.05 3.00 mg/l NH 4 690 nm 20 985 003 Ammonium 10 0.2 8.0 mg/l NH 4 0.2 10.0 mg/l NH 4 690 nm 20 985 004 Ammonium 50 1.0 40.0 mg/l NH 4 1.0 50.0 mg/l NH 4 690 nm 20 985 005 Ammonium 100 4 80 mg/l NH 4 5 100 mg/l NH 4 585 nm 20 985 008 Ammonium 200 30 160 mg/l NH 4 40 200 mg/l NH 4 585 nm 20 985 006 AOX 3 0.1 3.0 mg/l AOX 0.01 0.30 mg/l AOX 470 nm 20 985 007 BOD 5 2 3000 mg/l O 2 436 nm 25 50 985 822 BOD 5 -TT 2 3000 mg/l O 2 436 nm 22 985 825 Cadmium 2 1) 0.05 2.00 mg/l Cd 2 520 nm 10 19 985 014 Carbonate hardness 15 1.0 15.0 d 0.4 5.4 mmol/l H 436/585 20 985 015 nm Chloride 0.2 125 mg/l Cl 470 nm 220 918 20 Chloride 50 0.5 50.0 mg/l Cl 470 nm 20 985 021 Chloride 200 5 200 mg/l Cl 470 nm 20 985 019 Chlorine 0.02 10.0 mg/l Cl 2 540 nm 250 918 16 Chlorine/Ozone 2 0.05 2.50 mg/l Cl 2 0.05 2.00 mg/l O 3 540 nm 20 985 017 Chlorine dioxide 0.04 4.00 mg/l ClO 2 540 nm 50 918 163 Chlorine dioxide 5 0.15 5.00 mg/l ClO 2 540 nm 20 985 018 Chromate 0.01 3.0 mg/l Cr(VI) 2 0.01 6.0 mg/l CrO 4 540 nm 250 918 25 Chromate 5 0.05 2.00 mg/l Cr(VI) 2 0.1 4.0 mg/l CrO 4 540 nm 20 985 024 2 0.005 0.500 mg/l Cr(VI) 0.01 1.00 mg/l CrO 4 Cobalt 0.002 0.70 mg/l Co 2 540 nm 220 918 51 COD 40 2 40 mg/l O 2 345 nm 20 985 027 COD 60 5 60 mg/l O 2 345 nm 20 985 022 COD 160 15 160 mg/l O 2 436 nm 20 985 026 COD 160 Hg-free 15 160 mg/l O 2 436 nm 20 963 026 COD 300 50 300 mg/l O 2 436 nm 20 985 033 COD 1500 100 1500 mg/l O 2 620 nm 20 985 029 COD 10000 1.00 10.00 g/l O 2 620 nm 20 985 023 COD 15000 1.0 15.0 g/l O 2 620 nm 20 985 028 COD 60000 5.0 60.0 g/l O 2 620 nm 20 985 012 Colour (Hazen/DIN) 6) 5 500 mg/l Pt (Hazen) 0.2 20.0 436 nm Test 1-39 org. Complexing agents 10 0.5 10.0 mg/l I BiK 540 nm 10 19 985 052 (screening test) Copper 8) 0.01 10.0 mg/l Cu 2 585 nm 250 918 53 Copper 7 0.10 7.00 mg/l Cu 2 585 nm 20 985 054 Cyanide 0.001 0.50 mg/l CN 585 nm 250 918 30 Cyanide 08 0.01 0.80 mg/l CN 0.002 0.100 mg/l CN 585/ 20 985 031 605 nm DEHA 1 0.05 1.00 mg/l DEHA 540 nm 20 985 035 Ethanol 1000 0.10 1.00 g/l EtOH 0.013 0.130 Vol.% EtOH 620 nm 23 985 838 Fluoride 0.05 2.00 mg/l F 585 nm 200 918 142 Fluoride 2 0.1 2.0 mg/l F 620 nm 20 985 040 Formaldehyde 8 0.1 8.0 mg/l HCHO 585 nm 20 985 041 Formaldehyde 10 0.20 10.00 mg/l HCHO 0.02 1.00 mg/l HCHO 412 nm 4) 20 985 046 Hardness 20 1.0 20.0 d 5 50 mg/l Mg 2 540 nm 20 985 043 0.2 3.6 mmol/l 10 100 mg/l Ca 2 residual Hardness 1 0.02 1.00 d 0.004 0.180 mmol/l 540 nm 20 985 084 HC 300 0.5 5.6 mg/l HC 30 300 mg/kg HC 436 nm 20 985 057 (Hydrocarbons) Hydrazine 0.002 1.50 mg/l N 2 H 4 436 nm 220 918 44 Iron 8) 0.01 15.0 mg/l Fe 470 nm 250 918 36 Iron 3 0.10 3.00 mg/l Fe 0.02 1.00 mg/l Fe 540 nm 20 985 037 Lead 5 1) 0.10 5.00 mg/l Pb 2 520 nm 20 985 009 Manganese 8) 0.01 10.0 mg/l Mn 470 nm 250 918 60 Manganese 10 0.1 10.0 mg/l Mn 0.02 2.00 mg/l Mn 470 nm 20 985 058 Methanol 15 0.2 15.0 mg/l MeOH 620 nm 23 985 859 Molybdenum 40 1.0 40.0 mg/l Mo(VI) 2 1.6 65.0 mg/l MoO 4 345/ 20 985 056 365 nm Nickel 4) 0.01 10.0 mg/l Ni 2 436 nm 250 918 62 Nickel 7 0.10 7.00 mg/l Ni 2 0.02 1.00 mg/l Ni 2 470 nm 20 985 061 Nitrate 0.9 30.0 mg/l NO 3 4 140 mg/l NO 3 365/ 100 918 65 Nitrate Z 0.02 1.0 mg/l NO 3 0.1 5.0 mg/l NO 3 520 nm 440 918 63 REF

NANOCOLOR tube tests and standard tests Test Measuring ranges Wavelength No of tests SiO Nitrat 8 0.30 8.00 mg/l NO 3 470 nm 20 985 061 Nitrate 50 0.3 22.0 mg/l NO 3 2 100 mg/l NO 3 365 nm 20 985 064 Nitrate 250 4 60 mg/l NO 3 20 250 mg/l NO 3 365/ 20 985 066 Nitrite 8) 0.002 0.30 mg/l NO 2 0.005 1.00 mg/l NO 2 520 nm 220 918 67 Nitrite 2 0.003 0.460 mg/l NO 2 0.02 1.50 mg/l NO 2 540 nm 20 985 068 Nitrite 4 0.1 4.0 mg/l NO 2 0.3 13.0 mg/l NO 2 540 nm 20 985 069 total Nitrogen TN b 22 0.5 22.0 mg/l N 365/ 20 985 083 total Nitrogen TN b 220 5 220 mg/l N 365/ 20 985 088 Organic acids 3000 30 3000 mg/l CH 3 COOH 0.5 50.0 mmol/l CH 3 COOH 470 nm 20 985 050 Oxygen 12 0.5 12.0 mg/l O 2 436 nm 22 985 082 Peroxide 2 0.03 2.00 mg/l H 2 O 2 620 nm 10 19 985 871 ph 6.5 8.2 3) ph 6.5 8.2 436 nm 100 918 72 540 nm Phenol 0.01 7.0 mg/l Phenol 470 nm 440 918 75 Phenolic index 5 1) 0.2 5.0 mg/l 520 nm 20 985 074 ortho-phosphate 0.04 6.5 mg/l PO 4 -P 0.1 20.0 mg/l PO 4 690 nm 440 918 77 ortho-phosphate 8) 0.2 17 mg/l PO 4 -P 0.5 50 mg/l PO 4 436 nm 440 918 78 ortho- and total-phosphate 1 0.05 1.50 mg/l P 0.2 5.0 mg/l PO 4 690 nm 19 985 076 0.010 0.800 mg/l P 0.03 2.50 mg/l PO 4 ortho- and total-phosphate 5 0.20 5.00 mg/l P 0.5 15.0 mg/l PO 4 690 nm 19 985 081 ortho- and total-phosphate 15 0.30 15.00 mg/l P 1.0 45.0 mg/l PO 4 690 nm 19 985 080 ortho- and total-phosphate 45 5.0 50.0 mg/l P 15 150 mg/l PO 4 690 nm 19 985 055 ortho- and total-phosphate 50 10.0 50.0 mg/l P 30 150 mg/l PO 4 436 nm 19 985 079 POC 200 20 200 mg/l POC 2 40 mg/l KWI 436 nm 20 985 070 (polyoxycarboxylic acids) Potassium 50 2 50 mg/l K 690 nm 20 985 045 Silica 8) 0.01 5.00 mg/l Si 0.02 10.0 mg/l 690 nm 250 918 48 2 0.002 0.100 mg/l Si 3) 0.005 0.200 mg/l SiO 7) 2 800 nm Silver 3 0.20 3.00 mg/l Ag 620 nm 20 985 049 Starch 100 5 100 mg/l Starch 540 nm 19 985 085 Sulphate 200 2 10 200 mg/l SO 4 436 nm 20 985 086 Sulphate 1000 2 200 1000 mg/l SO 4 436 nm 20 985 087 Sulphide 0.01 3.0 mg/l S 2 620 nm 250 918 88 660 nm Sulphide 3 0.05 3.00 mg/l S 2 620 nm 20 985 073 2 Sulphite 10 0.2 10.0 mg/l SO 2 3 0.05 2.40 mg/l SO 3 436 nm 20 985 089 2 Sulphite 100 5 100 mg/l SO 3 470 nm 19 985 090 anionic Surfactants 4 0.20 4.00 mg/l MBAS 620 nm 20 985 032 cationic Surfactants 4 0.20 4.00 mg/l CTAB 620 nm 20 985 034 nonionic Surfactants 15 0.3 15.0 mg/l Triton X-100 610 nm 20 985 047 620 nm Thiocyanate 50 0.5 50.0 mg/l SCN 470 nm 20 985 091 Tin 3 1) 0.10 3.00 mg/l Sn 520 nm 18 985 097 TOC 25 2.0 25.0 mg/l C 585 mn 10 985 093 TOC 60 10 60 mg/l C 585 nm 10 985 094 TOC 600 40 600 mg/l C 585 nm 10 985 099 TTC / Sludge activity 150 5 150 µg TPF 0.050 2.300 E 470 nm 20 985 890 Turbidity (formazine/din) 5) 1 100 TE/F (= FAU) 0.5 40.0 1 / m 620 nm 860 nm Test 1-92 Turbidity 5) 6) 1 1000 NTU Test 9-06 Zinc 0.02 3.0 mg/l Zn 2 620 nm 250 918 95 Zinc 4 0.10 4.00 mg/l Zn 2 620 nm 20 985 096 1) This test cannot be evaluated with the NANOCOLOR 250 D a more sensitive measuring range is possible by using 50 mm semi-micro cuvettes (REF 919 50) 3) without bar code 4) special filter necessary 5) evaluation only possible with NANOCOLOR UV / VIS 6) A NANOCOLOR standard test is not required. The original sample has to be measured without additional reagents. 7) High sensitivity measurement 8) Simplified procedure in a beaker is possible. Please ask for special instructions! REF

Application areas Test Aluminium Ammonium AOX BOD 5 Cadmium Carbonate hardness Chloride Chlorine Chlorine dioxide Chromium/ Chromate Cobalt COD Colour Org. complexing agents Copper Cyanide Detergents DEHA Ethanol Fluoride Formaldehyde Hardness, Calcium, Magnesium Hydrocarbons Hydrazine Iron Lead Manganese Methanol Molybdenum Nickel Nitrate Nitrite Total Nitrogen Organic Acids Oxygen Ozone Peroxide ph Phenol Phosphate POC Potassium Residual hardness Silica Starch Sulphate Sulphide Sulphite Surfactants Thiocyanate Tin TOC Turbidity TTC Zinc Municipal waste water Drinking water Industrial waste water Boiler feed water Cooling water Surface water Breweries Paper industry Textile industry Leather industry Chemical industry Metal processing industry Photo industry Electroplating industry Food and beverages industry Dairy industry Aquaculture and fish farming Sea water analysis Pharmaceutical industry Concrete and cement production Leakage from garbage dumps Swimming pools Disinfetion

COD 40 Cat. No. 985 027 COD 60 Cat. No. 985 022 COD 160 Cat. No. 985 026 COD 1500 Cat. No. 985 029 Hereby we confirm, that the above mentioned tube tests from MACHEREYAGEL fully comply with the Water quality - Determination of the chemical oxygen demand index (ST-COD) - Small-scale sealed tube method. MACHEREYAGEL ISO 15705 Reagents Sulphuric acid Sulphuric acid Potassium dichromate Potassium dichromate Silver sulphate Silver sulphate Mercury sulphate Mercury sulphate Sample volume 2,00 ml 2,00 ± 0,02 ml Digestion Temperature: 148 C Temperature: 150 ± 5 C Time: 2 h Time: 2 h ± 10 min Wavelengths for 2-40 mg/l O 345 nm to 50 mg/l O 348 ± 15 nm photometric 2-60 mg/l O 345nm to 50 mg/l O 348 ± 15 nm determination 15-160 mg/l O 436 nm to 150 mg/l O 440 ± 20 nm 100-1500 mg/l O 620 nm to 1000 mg/l O 600 ± 20 nm MACHEREYAGEL GmbH & Co. KG i. A. Dr. Reinhardt, Head of QA Dept. - A G E L NANOCOLOR Reagents for photometric water analysis Legal acceptance The chemistry of our NANOCOLOR test kits is based on international norms and regulations for the analysis of water, waste water and sludge (DIN, EN, ISO, APHA and EPA, e.g. ISO 15705 Water quality Determination of the chemical oxygen demand index (ST-COD) Small-scale sealed tube method). Accuracy, precision and detection limits of test kits fulfil the requirements of specific national and international guidelines for water quality and water analysis (e.g. EC Drinking Water Directive 98/83/EC, German Drinking Water Directive, German Federal laws and State laws governing water protection and water analysis). COD tube tests in accordance to ISO 15705 ISO conformity of NANOCOLOR tube tests Düren, 03.03.2008 ISO 15705 A M C D Ü H E R E R N E Y N With the NANOCOLOR system for photometric water analysis, MACHEREYAGEL offers an environment-friendly, cost-effective and time-saving system for the determination of chemical oxygen demand in accordance with the ISO norm 15705. For the first time ever, the ISO 15705 ( Water quality - Determination of the chemical oxygen demand index (ST-COD) - Small-scale sealed tube method ) describes a photometric tube test as a standardized and internationally accepted method for the analysis of water and waste water. MACHEREYAGEL confirms, that every component of the NANOCOLOR system for photometric water analysis fulfils all requirements concerning reagents, sample volume, digestion conditions and photometric determination of the ISO 15705. Quality Assurance During production, filling and storage, NANOCOLOR reagents are constantly controlled by a quality system, which fulfils the requirements of DIN EN ISO 9001. Our routine quality assurance ensures consistent calibration accuracy, as well as highly accurate results during the entire shelf-life of NANOCOLOR test kits. Accuracy of results Ring tests among our customers and participation in external ring tests have shown that deviations of less than 5% from nominal results, given by standard methods, can be expected when using NANOCOLOR reagents. Nominal calibration values deviate less than 3% from photometers calibrations. NANOCONTROL NANOCHECK REF 925 701 NANOCONTROL NANOCHECK test solutions are suitable for the determination of photometric accuracy of MACHEREYAGEL photometers. They are secondary standards for the control of inspection, measuring and test equipment in accordance to ISO 9001 and ISO 14001. They are checked and documented with a reference photometer which is monitored with primary standards (NIST traceable standards). The results are documented. Only 2 stable colour solutions are necessary to check the wavelength accuracy and the linearity of the absorbance measure- ment. Your local distributor: KATEN100009 / NANO Reagents en6/3/0/04.10 PD Printed in Germany MACHEREYAGEL EN ISO 9001: 2008 CERTIFIED MACHEREYAGEL GmbH & Co. KG Neumanneander-Str. 6-8 D-52355 Düren Germany Germany and international: Tel.: 49 (0) 24 21 96 90 Fax: 49 (0) 24 21 96 91 99 E-mail: info@mn-net.com Switzerland: MACHEREYAGEL AG Tel.: 41 (0) 62 388 55 00 Fax: 41 (0) 62 388 55 05 E-mail: sales-ch@mn-net.com France: MACHEREYAGEL EURL Tel.: 33 (0) 3 88 68 22 68 Fax: 33 (0) 3 88 51 76 88 E-mail: sales-fr@mn-net.com