www.isotope.com To place an order please contact CIL at: envsales@isotope.com l 978-749-8000 l 800-322-1174 ( N.America) Cambridge Isotope Laboratories, Inc. www.isotope.com POPs Pesticides and Priority Pollutant Standard Mixtures POPs Pesticides Dirty Dozen Mixtures Priority Pollutant Standard Mixtures HCH Standard Mixtures Toxaphene Standard Mixtures Cambridge Isotope Laboratories has long been the leader in development of isotopically labeled standards for use in trace and ultra-trace analysis of environmental pollutants. CIL continues this leading role by introducing the first ever comprehensive POPs Pesticides standard mixtures for use in Isotope Dilution Mass Spectrometry analysis. On May 17th, 2004, the Stockholm Convention on Persistent Organic Pollutants entered into force with the objective to eliminate and/or restrict production and use of POPs of interest to the global community. The convention has defined 12 POPs of highest concern, called The Dirty Dozen. This list currently includes: Dioxins and Furans PCBs and Hexachlorobenzene Pesticides: Aldrin, Dieldrin, Endrin, Chlordane, Heptachlor, Mirex, DDT, and Toxaphene. While CIL has offered individual dioxin, furan, and PCB standards and standard mixtures for many years as well as individual pesticide standards, our new POPs Pesticides standard mixtures are designed to allow laboratories to use consistent, high quality, pre-formulated mixtures for analysis of these highest priority pollutants. CIL also offers extended Priority Pollutants standard mixtures, incorporating all the POPs Pesticides plus several other major pollutants of concern. For specific testing purposes, CIL also offers HCH-only, and Toxaphene-only standard mixes.
Cambridge Isotope Laboratories, Inc. POPs Pesticides and Priority Pollutant Standard Mixtures POPs Pesticides Standard Mixtures ES-5348 POPs Pesticides Calibration Solutions CS1-CS6 (unlabeled/ C, 99%) 6 x 0.2 ml nonane Unlabeled analyte CS1 CS2 CS3 CS4 CS5 CS6 Hexachlorobenzene 0.4 2 10 40 200 800 Aldrin 0.4 2 10 40 200 800 Dieldrin 0.4 2 10 40 200 800 Endrin 0.4 2 10 40 200 800 4,4 -DDT 0.4 2 10 40 200 800 4,4 -DDE 0.4 2 10 40 200 800 4,4 -DDD 0.4 2 10 40 200 800 2,4 -DDT 0.4 2 10 40 200 800 2,4 -DDE 0.4 2 10 40 200 800 2,4 -DDD 0.4 2 10 40 200 800 trans-chlordane (gamma) 0.4 2 10 40 200 800 cis-chlordane (alpha) 0.4 2 10 40 200 800 trans-nonachlor 0.4 2 10 40 200 800 cis-nonachlor 0.4 2 10 40 200 800 Oxychlordane 0.4 2 10 40 200 800 Heptachlor 0.4 2 10 40 200 800 trans-heptachlor Epoxide 0.4 2 10 40 200 800 cis-heptachlor Epoxide 0.4 2 10 40 200 800 Mirex 0.4 2 10 40 200 800 alpha-bhc 0.4 2 10 40 200 800 beta-bhc 0.4 2 10 40 200 800 Lindane 0.4 2 10 40 200 800 delta-bhc 0.4 2 10 40 200 800 Cleanup Spike Hexachlorobenzene- C 6 Aldrin- Dieldrin- Endrin- 4,4 -DDT- 4,4 -DDE- 4,4 -DDD- 2,4 -DDT- 2,4 -DDE- 2,4 -DDD- trans-chlordane (gamma)- trans-nonachlor- cis-nonachlor- Oxychlordane- Heptachlor- cis-heptachlor Epoxide- Mirex- alpha-bhc- C 6 beta-bhc- C 6 Lindane- C 6 delta-bhc- C 6 Syringe Spike 4,4 -DiCB- (PCB-15) 2,3,4,5-TetraCB- (PCB-70) 01 02
www.isotope.com To place an order please contact CIL at: envsales@isotope.com l 978-749-8000 l 800-322-1174 ( N.America) POPs Pesticides Standard Mixtures Cont... ES-5399 POPs PAR Solution (unlabeled) 1.2 ml nonane ES-5399-10X-0.5 POPs PAR Solution (unlabeled) 0.5 ml nonane ES-5399 ES-5399-10X-0.5 Hexachlorobenzene 200 2000 Aldrin 200 2000 Dieldrin 200 2000 Endrin 200 2000 4,4 -DDT 200 2000 4,4 -DDE 200 2000 4,4 -DDD 200 2000 2,4 -DDT 200 2000 2,4 -DDE 200 2000 2,4 -DDD 200 2000 trans-chlordane (gamma) 200 2000 cis-chlordane (alpha) 200 2000 trans-nonachlor 200 2000 cis-nonachlor 200 2000 Oxychlordane 200 2000 Heptachlor 200 2000 trans-heptachlor Epoxide 200 2000 cis-heptachlor Epoxide 200 2000 Mirex 200 2000 alpha-bhc 200 2000 beta-bhc 200 2000 Lindane (gamma-bhc) 200 2000 delta-bhc 200 2000 ES-5349 POPs Pesticides HRMS Clean-Up Spike ( C,99%) 1.2 ml nonane ES-5400 POPs Pesticides Clean-Up Spike ( C,99%) 1.2 ml nonane ES-5349-L POPs Pesticides LRMS Clean-Up Spike ( C,99%) 0.5 ml nonane ES-5349 ES-5400 ES-5349-L Hexachlorobenzene- C 6 Aldrin- Dieldrin- Endrin- 4,4 -DDT- 4,4 -DDE- 4,4 -DDD- 2,4 -DDT- 2,4 -DDE- 2,4 -DDD- trans-chlordane (gamma)- trans-nonachlor- cis-nonachlor- Oxychlordane- Heptachlor- cis-heptachlor Epoxide- Mirex- alpha-hch- C 6 beta-hch- C 6 gamma-hch (Lindane)- C 6 delta-hch- C 6 03 02
Cambridge Isotope Laboratories, Inc. POPs Pesticides and Priority Pollutant Standard Mixtures POPs Pesticides Standard Mixtures Cont... EC-5350 POPs Pesticides HRMS (PCB) Syringe Spike ( C, 99%) 1.2 ml nonane EC-5350-L POPs Pesticides LRMS (PCB) Syringe Spike ( C, 99%) 1.2 ml nonane EC-5350 EC-5350-L 4,4 -DiCB- (PCB-15) 100 1000 2,3,4,5-TetraCB- (PCB-70) 100 1000 POPs Pesticides Alternative Spiking Mixtures ES-5021 Persistent Pesticide Spiking Solution ( C, 99%) 2.5 ml nonane ES-5177-500X-N-0.5 Persistent Pesticide Spiking Solution ( C, 99%) 0.5 ml nonane ES-5021 ES-5177-500X-N-0.5 Hexachlorobenzene- C 6 Dieldrin- beta-hch- C 6 gamma-hch (Lindane)- C 6 cis-heptachlor Epoxide- Oxychlordane- trans-nonachlor- Mirex- 2,4 -DDT- 4,4 -DDT- 4,4 -DDE- 250 12,500 ES-5261-1.2 Persistent Organic Pollutants Clean-Up Spike ( C, 99%) 1.2 ml nonane C 6 -Hexachlorobenzene 1000 C 6 -α-hch 1000 C 6 -β-hch 1000 C 6 -Lindane (γ-hcch) 1000 -Aldrin 1000 -Dieldrin 1000 -Endrin 1000 -trans-chlordane 1000 -Oxychlordane 1000 -trans-nonachlor 1000 -Heptachlor 1000 -cis-heptachlor Epoxide 1000-2,4 -DDT 1000-4,4 -DDT 1000-4,4 -DDE 1000 03 04
www.isotope.com To place an order please contact CIL at: envsales@isotope.com l 978-749-8000 l 800-322-1174 ( N.America) Priority Pollutant Standard Mixtures ES-5364 CDC Priority Pollutant Calibration Solutions CS1 - CS10 (unlabeled/ C, 99%) 10 x 0.5 ml nonane Unlabeled Analyte CS1 CS2 CS3 CS4 CS5 CS6 CS7 CS8 CS9 CS10 Parlar 26 0.2 0.5 1 2.5 10 75 100 500 Parlar 50 0.2 0.5 1 2.5 10 75 100 500 Parlar 62 0.2 0.5 1 2.5 10 75 100 500 Hexachlorobenzene 0.2 0.5 1 2.5 10 75 100 500 beta-bhc 0.2 0.5 1 2.5 10 75 100 500 Lindane 0.2 0.5 1 2.5 10 75 100 500 Aldrin 0.2 0.5 1 2.5 10 75 100 500 cis-heptachlor Epoxide 0.2 0.5 1 2.5 10 75 100 500 Oxychlordane 0.2 0.5 1 2.5 10 75 100 500 trans-nonachlor 0.2 0.5 1 2.5 10 75 100 500 4,4 -DDE 0.2 0.5 1 2.5 10 75 100 500 3000 7500 Dieldrin 0.2 0.5 1 2.5 10 75 100 500 Endrin 0.2 0.5 1 2.5 10 75 100 500 Isodrin 0.2 0.5 1 2.5 10 75 100 500 2,4 -DDT 0.2 0.5 1 2.5 10 75 100 500 4,4 -DDT 0.2 0.5 1 2.5 10 75 100 500 Mirex 0.2 0.5 1 2.5 10 75 100 500 alpha-bhc 0.2 0.5 1 2.5 10 75 100 500 cis-chlordane (alpha) 0.2 0.5 1 2.5 10 75 100 500 trans-chlordane (gamma) 0.2 0.5 1 2.5 10 75 100 500 2,4 -DDE 0.2 0.5 1 2.5 10 75 100 500 cis-nonachlor 0.2 0.5 1 2.5 10 75 100 500 Methoxychlor 0.2 0.5 1 2.5 10 75 100 500 Pentachloroanisole 0.2 0.5 1 2.5 10 75 100 500 Octachlorostyrene 0.2 0.5 1 2.5 10 75 100 500 Labeled Compound 1,2,3,4-TCDD- C 6 25 25 25 25 25 25 25 25 25 25 2,2,3,3,4,5,5,6,6 -NonaCB- 100 100 100 100 100 100 100 100 100 100 3,3,4,4 -TetraBDE- 2,2,3,4,4,6-HexaBDE- Hexachlorobenzene- C 6 beta-bhc- C 6 Lindane- C 6 Aldrin- cis-heptachlor Epoxide Oxychlordane- trans-nonachlor- 4,4 -DDE- 150 150 150 150 150 150 150 150 150 150 Dieldrin- Endrin- Isodrin- 2,4 -DDT- 4,4 -DDT- Mirex- alpha-bhc- C 6 trans-chlordane (gamma)- 2,4 -DDE- cis-nonachlor- Methoxychlor- Pentachloroanisole- C 6 Octachlorostyrene- C 8 05 04
Cambridge Isotope Laboratories, Inc. POPs Pesticides and Priority Pollutant Standard Mixtures ES-5365 CDC Priority Pollutant Spiking Standard ( C, 99%) 10 ml methanol Hexachlorobenzene- C 6 beta-bhc- C 6 Lindane- C 6 Aldrin- cis-heptachlor Epoxide Oxychlordane- trans-nonachlor- 4,4 -DDE- 15 Dieldrin- Endrin- Isodrin- 2,4 -DDT- 4,4 -DDT- Mirex- alpha-bhc- C 6 trans-chlordane (gamma)- 2,4 -DDE- cis-nonachlor- Methoxychlor- Pentachloroanisole- C 6 Octachlorostyrene- C 8 Hexachlorocyclohexanes (HCH) Standard Mixtures While Lindane (γ-hexachlorocyclohexane, γ-hch, or γ-bhc) is the predominant HCH isomer, α-, β-, and δ-hch are also produced during synthesis of Lindane, and demonstrate bioaccumulative tendencies. The following mixes allow independent analysis of this class of compounds. ES-5343 POPs HRMS HCH Calibration Solutions CS1-CS5 5 x 0.2 ml nonane Unlabeled Analytes CS1 CS2 CS3 CS4 CS5 alpha-bhc 0.1 0.3 1 3 10 beta-bhc 0.1 0.3 1 3 10 Lindane 0.1 0.3 1 3 10 delta-bhc 0.1 0.3 1 3 10 Surrogate alpha-bhc- C 6 2 2 2 2 2 beta-bhc- C 6 2 2 2 2 2 Lindane- C 6 2 2 2 2 2 delta-bhc- C 6 2 2 2 2 2 ES-5344 POPs HRMS HCH Clean-Up Spike 1.2 ml nonane ES-5344-50X-0.5 POPs HRMS HCH Clean-Up Spike (50x Stock) * 0.5 ml nonane ES-5344 ES-5344-50X-0.5 alpha-bhc- C 6 20 1000 beta-bhc- C 6 20 1000 Lindane- C 6 20 1000 delta-bhc- C 6 20 1000 05 06
www.isotope.com To place an order please contact CIL at: envsales@isotope.com l 978-749-8000 l 800-322-1174 ( N.America) Toxaphene Standard Mixtures Toxaphene, a technical mixture of polychlorinated Camphenes, is an inexpensive and potent insecticide. The following mixtures allow analysis of the three commonly analyzed congeners of Toxaphene. ES-5351 POPs Toxaphene Calibration Solutions CS1-CS6 6 x 0.2 ml nonane Unlabeled Analytes CS1 CS2 CS3 CS4 CS5 CS6 Parlar-26 0.4 2 10 40 200 800 Parlar-50 0.4 2 10 40 200 800 Parlar-62 0.4 2 10 40 200 800 Surrogate Standard trans-chlordane (gamma)- ES-5345 POPs Toxaphene Calibration Solutions CS1-CS5 5 x 0.2 ml nonane Unlabeled Analytes CS1 CS2 CS3 CS4 CS5 Parlar-26 10 30 100 300 1000 Parlar-50 10 30 100 300 1000 Parlar-62 10 30 100 300 1000 Surrogate Standard trans-chlordane- 1 1 1 1 1 ES-5353 Predominant Bioaccumulative Toxaphene Congeners 1.2 ml nonane Parlar-26 2,000 Parlar-50 2,000 Parlar-62 2,000 ES-5346 POPs Toxaphene HRMS Surrogate Solution 1.2 ml nonane ES-5352-L POPs Toxaphene LRMS Surrogate Solution 1.2 ml nonane ES-5346 ES-5352-L trans-chlordane (gamma)- 100 1000 The mixtures listed in the preceding pages represent only part of the wide range of CIL related to Pesticides testing. For more information, or to request alternative mixtures, please contact CIL s Environmental Contaminant division at envsales@ isotope.com. 07 06
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