Powder River Basin Underground Coal Gasification WY EORI CO2 Conference June 23-24, 2009

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Powder River Basin Underground Coal Gasification WY EORI CO2 Conference June 23-24, 2009 James R. Covell, RDS-EG&G Technical Services Washington Division, URS Oil Shale Symposium, Golden, CO, October 14-15, 2008

What is Underground Coal Gasification (UCG)? In Situ Coal Gasifier Expanding Natural Reactor Does Not Require Mining / Requires Wells and Well Connection (Horizontal Drilling or Reverse Combustion) Uses Air or Steam / Oxygen Injection To React With Coal and Groundwater Produces Syngas the Same as Surface Gasifiers Major Gases: CO, H 2, CH 4, CO 2, and H 2 O Basic Building Blocks for SNG and Liquid Fuels Production Syngas Can Directly Fuel Electric Generation 2

UCG Process I > 2500 0 F I 2500 1000 0 F I 1000 600 0 F I UCG Major Reactions Coal + O 2 + H 2 O > Ash + Gases + Tars + Heat (General) C + O 2 > CO 2 (Combustion) C + H 2 O > CO + H 2 (Steam-Char) C + CO 2 > CO (Reduction) CO + H 2 O > CO 2 + H 2 (Shift) 3

UCG Process Schematic From UK DTI, 2004 4

UCG Advantages Vast Resources for UCG Targets Deep Coals Requires No Mining, Ash Handling, and Surface Gasifiers Lower Capital Costs (Reduced 30%) and Overall Costs ($1.50 - $2.00/Million BTU) Reduced Human Risks Environmentally Friendly Contrary to Some Perceptions Most Testing Conducted with No or Little Environmental Impacts Small Footprint 5

UCG History and Reemergence Russians Began UCG Development in 1928 (2 Commercial Plants Still Operating) USA Testing and Development 1946-1996 33 Trials Most Successful Test, Rocky Mountain I Trials Also in Europe (1982-1999) and Australia (1999- Present) Global Reemergence of UCG China, South Africa, and Australia Conducting Advanced Demonstrations or Commercial Development USA Being Considered for Pre-Commercial and Commercial Development (3 Projects Planned in Wyoming, 2 in PRB) 6

Fossil Energy Reserves (2007) 17% Economically Minable Coal 16% Oil NG Coal 67% Source: BP, 2007 7

2007 Fossil Energy {Reserves + Resources} Oil NG Coal 96% Source: AAPG and BP, 2007 8

World Coal Reserves/Resources Proven world coal reserves (economic) of 909 billion tons (BP, 2007). Cover Wyoming in 8 feet of coal Estimated total world coal resources (identified, not necessarily economic) of up to 18 trillion tons (AAPG) Only 5% of resources are economically extractable as reserves Most resources are simply too deep known but too deep Underground Coal Gasification (UCG) Converts Coal Resources to Coal Reserves From GasTech 2008 EORI Presentation 9

Powder River Basin From GasTech 2008 EORI Presentation 10

Powder River Basin Coal Resource 510 Billion tons coal in-place (USGS, 1999) Seams up to 250 feet thick Energy content equal to 20 times the world s total annual energy consumption One ton of PRB coal has 300 times the energy content of the CBM gas in that same ton of coal 307 billion tons amenable to UCG (this study) Seams >500 ft deep to top of seam Seams > 30 feet thick From GasTech 2008 EORI Presentation 11

GasTech PRB UCG Data Base Excerpt from database: 50 feet+ coal seams, 100 feet immediate mudstone overburden 12

UCG Issues Groundwater Contamination Subsidence Resolution of Conflicting Resources or Resource Extraction Coal Mining Coal Bed Methane UCG Carbon Dioxide Management Enhanced Oil Recovery Carbon Capture Sequestration (CCS) 13

UCG Groundwater Contamination Issue - Challenge Perceived as Dirty Technology Groundwater Contamination Based on Hoe Creek Actual US Experience Relatively Clean Technology Most U.S. UCG Operations Resulted in Limited or No Groundwater Contamination Groundwater Contamination Caused by Gas Losses (Human Error) Dynamic Process-Consumes Deposited Contamination Sources Mitigation Site Selection Operation Constraints Clean-Cavity Concept 14

UCG Subsidence Serious Issue Gas Losses Interconnection of Water Bearing Units Surface Disruption Water Influx Mitigation Site Selection Depth Module Design Planned Subsidence Hoe Creek III, WDEQ Hoe Creek III, WDEQ 15

Conflicting Recovery Technologies Coal Mining, CBM, and UCG No Definitive Regulations - Evolving Conflict in PRB of Wyoming Between Mining and CBM BLM Addressing Issue CBM New Technology After Mining Leases Issued Lease Seniority (Oil-Gas Senior to Mining Leases) Advantage to New technologies Incentives to Recover CBM Near Coal Mines to Free Mine leases First Approach is Negotiations Between Lease Holders Prompted BLM to Issue HR 2952, the Powder River Basin Development Act of 2001 Additional Guidance Issued in May 2006 Wyoming CBM Clearinghouse Wyoming CBM Clearinghouse Rocky Mountain 1 UCG Site 16

Conflicting Recovery Technologies Coal Mining, CBM, and UCG (Continued) See Following for Details of Conflict Resolutions http://www.blm.gov/nhp/news/legislative/pages/2001/te011011.htm http://www.blm.gov/nhp/news/legislative/pages/2003/te030712.htm http://www.blm.gov/nhp/efoia/wo/fy06/im2006-153.htm UCG Conflicts with Coal Mining and CBM Has Not Been Addressed - UCG not Commercial Similar Lease Position as Coal Mine Lease UCG Development in PRB Will Likely Be in CBM Depleted Areas Not Much of a Problem Because of the Maturity of CBM Development and the Time Lag for Commercial UCG Development UCG Conflicts More Likely with CBM Than Coal Mining UCG Resources Deeper Than Coal Mining Resources 17

UCG and EOR in the PRB 200 Mwe UCG-IGCC power plant will produce 1 million tons (Mt) CO2/yr UCG syngas is 15% CO2 (air blown) to 30% CO2 (O 2 blown) Rocky Mountain Area Transmission Study (2006) predicts 700 Mwe new generating capacity from coal in the PRB; if UCG, produces 3.5 Mt CO2/yr PRB demand for CO2 for 168 reservoirs is 236 to 354 Mt (Wo, 2007) UCG is viable source of CO2 for EOR Energy Penalty for CO 2 Removal: 6-9% (LLNL 2007) GasTech 2008 EORI Presentation 18

Carbon Capture Sequestration (CCS) If CCS desired, use oxygen-blown system CCS in the PRB Tertiary oil recovery, as Salt Creek, Hartzog Draw Extinct UCG cavities as dense phase Deep marine formations; PRB has numerous candidates for receiver formations: Mesa Verde, Sussex, Shannon, Frontier, Muddy, Morrison, Tensleep Possible carbon credits Energy penalty economically acceptable GasTech 2008 EORI Presentation 19

CCS in Powder River Coals PRB Coal Seams too Shallow for Super Critical Storage (Depths > 2,500 feet) Dense Phase (Gas) CO 2 Storage Possible in Exhausted UCG Cavities PRB Coals May React Different than Other Coals for CCS Coals Lose Permeability with CO 2 Injection PRB Coals Reported to Gain Permeability (McLendon, NETL 2009) CO 2 Injection May Mobilize Contaminants in Coal Groundwater 20

Permeability Decrease in Coal Seams From CO 2 Injections (N. Dakota Lignite) 4 3.5 Permeability, μd 3 2.5 2 1.5 1 aspike sine6 NETL, UWV, UND Report 2008 0.5 0 0 50 100 150 200 250 Time, hours 21

UCG in the PRB Conclusions UCG is a Viable, Cost-Effective, and Environment- Friendly Technology for Electrical Generation and Synthetic Fuels Production Coal Gasification Provides the Basic Building Blocks for SNG, Transportation Fuels, and Other Products (e.g. Fertilizers) UCG Development in the PRB is Coming Spearheaded by GasTech and Others Significant Global Interest UCG Would Provide an Economical Source of CO 2 for EOR in the PRB and Surrounding Basins CCS in the PRB May Be Feasible in Marine Formations; May Be Feasible in Coal Seams as Dense Gas Phase 22