RAID MAX HOME INSECT KILLER (REG NO P.C.P. ACT)

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Material Safety Data Sheet

M A T E R I A L S A F E T Y D A T A

RAID YARD GUARD MOSQUITO FOGGER

M A T E R I A L S A F E T Y D A T A

Version 2 Revision Date 02/01/2010 Print Date 02/01/2010

Page 1 of 6 MSDS # Date Issued: 18Jun1997 Supersedes: 08Aug1994

Transcription:

1. PRODUCT AND COMPANY IDENTIFICATION Product information Trade name : RAID MAX HOME INSECT KILLER (REG NO 29322 P.C.P. ACT) Use of the : Insecticide Substance/Mixture Company : S.C. Johnson and Son, Limited 1 Webster Street Brantford ON N3T 5R1 Emergency telephone : 24 Hour Transport & Medical Emergency Phone (866) 231-5406 24 Hour International Emergency Phone (952) 852-4647 24 Hour Canadian Transport Emergency Phone (CANUTEC) (613) 996-6666 2. HAZARDS IDENTIFICATION Emergency Overview Appearance / Odor : colourless / aerosol / characteristic Immediate Concerns : Caution Contents under pressure. Do not puncture or incinerate. Do not store at temperatures above 120 Deg. F (50 Deg C), as container may burst. Keep away from heat, sparks and flame. Avoid contact with skin, eyes and clothing. Avoid prolonged or repeated breathing of vapor. Potential Health Effects Exposure routes : Eye, Skin, Inhalation, Ingestion. Eyes : May cause: Mild eye irritation Skin : May be harmful if absorbed through skin. Inhalation : May be harmful if inhaled. Ingestion : None known. Aggravated Medical Condition : None known. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No. Weight percent 1/8

Water 7732-18-5 60.00-100.00 Isobutane 75-28-5 10.00-30.00 Propane 74-98-6 1.00-5.00 Distillates (petroleum), 64742-47-8 hydrotreated light 1.00-5.00 Piperonyl butoxide 51-03-6 1.01 Pyrethrins 8003-34-7 0.25 4. FIRST AID MEASURES Eye contact : Flush immediately with plenty of water for at least 15 to 20 minutes. Get medical attention if irritation develops and persists. Skin contact : Flush immediately with plenty of water for at least 15 to 20 minutes. Get medical attention if irritation develops and persists. Inhalation : Remove to fresh air. If breathing is affected, get medical attention. Ingestion : Drink 1 or 2 glasses of water. Never give anything by mouth to an unconscious person. Get medical attention immediately. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Specific hazards during fire fighting : Alcohol foam, carbon dioxide, dry chemical, water fog : Aerosol Product - Containers may rocket or explode in heat of fire. Further information : Cool and use caution when approaching or handling fireexposed containers. Wear full protective clothing and positive pressure self-contained breathing apparatus. Fight fire from maximum distance or protected area. Flash point : < 20 F Method: Tag Closed Cup (TCC) Flash point : < -7 C Method: Tag Closed Cup (TCC) Lower explosion limit : Note: no data available Upper explosion limit : Note: no data available NFPA Classification : NFPA Level 1 Aerosol 2/8

6. ACCIDENTAL RELEASE MEASURES Personal precautions : Remove all sources of ignition. Use personal protective equipment. Environmental precautions : Use appropriate containment to avoid environmental contamination. Methods for cleaning up : Soak up with inert absorbent material. Dike large spills. Sweep up and shovel into suitable containers for disposal. 7. HANDLING AND STORAGE Handling Advice on safe handling : Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS. Do not puncture or incinerate. Avoid breathing vapors, mist or gas. Avoid contact with skin, eyes and clothing. Advice on protection against fire and explosion Storage Requirements for storage areas and containers : Keep away from heat and sources of ignition. : Keep in a dry, cool and well-ventilated place. Do not freeze. Do not store at temperatures above 120 Deg. F (50 Deg C), as container may burst. 3/8

8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits Components CAS-No. mg/m3 ppm Nonstandard Basis units Isobutane 75-28-5-1,000 ppm - ACGIH TWA Propane 74-98-6-1,000 ppm - ACGIH TWA Distillates (petroleum), hydrotreated light 64742-47-8 1,200 mg/m3 152 ppm - SUPPLIER Personal protective equipment Respiratory protection Hand protection Eye protection Industrial setting : Substantial amounts of mist/vapors can be controlled with local exhaust ventilation or respiratory protection. Household setting : No personal respiratory protective equipment normally required. Industrial setting : For prolonged or repeated contact use protective gloves. Household setting : not required under normal use Industrial setting : If prolonged or repeated contact is possible: Safety glasses with side-shields Household setting : No special requirements. Hygiene measures : Use only with adequate ventilation. Wash thoroughly after handling. Wear suitable protective clothing. Keep away from food, drink and animal feedingstuffs. 9. PHYSICAL AND CHEMICAL PROPERTIES Form : aerosol 4/8

Color : colourless Odor : characteristic ph : not applicable Boiling point : no data available Flash point : < 20 F Method: Tag Closed Cup (TCC) Flash point : < -7 C Method: Tag Closed Cup (TCC) Evaporation rate : no data available Lower explosion limit : no data available Upper explosion limit : no data available Vapour pressure : not applicable Density : 0.804 g/cm3 not applicable Water solubility : partly soluble Viscosity, kinematic : not applicable 10. STABILITY AND REACTIVITY Conditions to avoid : Heat, flames and sparks. Materials to avoid : Do not mix with oxidizing agents. Hazardous decomposition products : When exposed to fire, produces normal products of combustion. Hazardous reactions : Stable 11. TOXICOLOGICAL INFORMATION Acute oral toxicity : LD50 estimated > 5,000 mg/kg Acute inhalation toxicity : LC50 > 9.2 mg/l 5/8

Acute dermal toxicity : LD50 estimated > 2,000 mg/kg Chronic effects Carcinogenicity : no data available Mutagenicity : no data available Reproductive effects : no data available Teratogenicity : no data available Sensitisation : no data available 12. ECOLOGICAL INFORMATION Ecotoxicity effects : Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 13. DISPOSAL CONSIDERATIONS Industrial setting : Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal. Household setting : Consumer may discard empty container in trash, or recycle where facilities exist. 14. TRANSPORT INFORMATION Land transport U.S. DOT and Canadian TDG Surface Transportation: UN-Number 1950 Proper shipping name Aerosols, flammable Class: 2.1 Packaging group: None. Note: SC Johnson ships this product as Consumer Commodity ORM-D (non-bulk packages) 6/8

Sea transport IMDG: Class: 2.1 Packaging group: None. Proper shipping name Aerosols, flammable UN-Number: 1950 Note: SC Johnson ships this product as "Limited Quantity" when the container quantity value is 1 Liter or less. Air transport ICAO/IATA: Class: 2.1 Packaging group: None. Proper shipping name Aerosols, flammable UN/ID No.: UN 1950 Note: SC Johnson typically does not ship products via air, therefore it has not been determined if the product container meets current IATA/ICAO package criteria. Refer to IATA/ICAO Dangerous Goods Regulations for detailed instructions when shipping this item by air. 15. REGULATORY INFORMATION Notification status : All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA). Canada Regulations : This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. 16. OTHER INFORMATION HMIS Ratings Health 1 Flammability 4 Reactivity 0 NFPA Ratings Health 1 7/8

Fire 4 Reactivity 0 Special Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. Prepared by: SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA) 8/8