CCUS Major Demonstrations Program Overview

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U.S. Department of Energy Carbon Capture and Sequestration CCUS Major Demonstrations Program Overview Andrew Hlasko, P.E. andrew.hlasko@hq.doe.gov September 18, 2017 Senior Program Manager Large Carbon Management Projects U.S. Department of Energy, Office of Fossil Energy Washington, DC 1

U.S. DOE CCS Major Demonstration Projects CCPI ICCS Archer Daniels Midland (ADM) CO 2 Capture from Ethanol Plant CO 2 Stored in Saline Reservoir SALINE ~0.9 MM TPY; Started Operations: April 2017 Southern Company Kemper County IGCC Project Transport Gasifier w/ Carbon Capture Startup Suspended: June 2017 Petra Nova W.A. Parish Generating Station Post Combustion CO 2 Capture EOR ~1.4 MM TPY; Started Operations: January 2017 Air Products and Chemicals, Inc. CO 2 Capture from Steam Methane Reformers EOR in Eastern TX Oilfields Over 3.7 MMT already stored as of May 2017! Started Operations: March 2013 2

Petra Nova NRG Energy W.A. Parish, CCPI-3 Advanced Post Combustion CO 2 Capture Project at NRG s W.A. Parish power plant near Houston TX Retrofit of Existing Coal Plant to process flue gas from W.A. Parish Unit 8 - Post-Combustion CO2 capture World s largest post-combustion CO 2 capture system Project was completed On-Budget and On-Schedule Delivering and permanently storing around 1.4 million metric tons of CO 2 per year for EOR. 240 MWe slipstream scaled up to improve project economics 90% CO 2 capture from supplied flue gas (KM CDR Process ) Technology applicable to retrofit of existing coal plants EOR at the Hilcorp West Ranch oil field. Total Project Cost: ~$1 billion (DOE Cost Share: $190 MM) NRG Equity - $300 million JX Nippon Equity $300 million JBIC Project Financing - $250 million MHI Technology Provider Key Dates: Project Awarded: May 2010 NEPA Record of Decision: May 2013 Financial Close: July 2014 Construction Complete: December 2016 Construction Completed On-Budget and On-Schedule Started Operations: January 10, 2017 Ribbon Cutting Ceremony: April 13, 2017 Petra Nova project demonstrates that clean coal technologies can have a meaningful and positive impact on the Nation s energy security and economic growth. U.S. DOE Secretary Rick Perry, April 13, 2017 3

Air Products & Chemicals Inc., ICCS Area 1 Steam Methane Reforming with CO 2 Capture Built and operated by Air Products and Chemicals Inc. and located at Valero Oil Refinery in Port Arthur, TX. CO2 capture added to 2 existing Steam-Methane Reformers (SMRs) used for Hydrogen Production Project achieves 90+% CO 2 capture sing Vacuum Swing Adsorption (VSA) for CO2 separation Capturing ~925,000 tonnes CO 2 /year ~30 MWe cogeneration unit makeup steam to SMRs and power to VSA and Compressors CO 2 to Denbury Green pipeline for EOR in Texas at the West Hastings oil field Total Project cost: $431 MM; DOE Share: $284 MM (66%) Project was executed on time and under budget Project has operated >100% of design when needed Key Dates: Phase 2 Awarded: June 15, 2010 Construction started: Aug. 2011 Started Operations: March 2013 1 MM Tons of CO2 delivered Apr 2014 2 MM Tons of CO2 delivered May 2015 3 MM Tons of CO2 delivered May 2016 4 MM Tons of CO2 expected Sep. 2017 4

Archer Daniels Midland Co., ICCS Area 1 CO 2 Capture from Biofuel Plant CCS project built and operated by Archer Daniels Midland (ADM) at their existing biofuel plant located in Decatur, IL CO 2 is a direct by-product from production of fuelgrade ethanol via anaerobic fermentation Up to 90% CO 2 capture (with >99% CO2 purity), dehydration (via tri-ethylene glycol) & compression ~900,000 tonnes CO 2 /year captured and stored CO2 Sequestration in Mt. Simon Sandstone deep saline formation. ADM is the first project to use the new EPA UIC Class VI well permit for CO2 sequestration Total Project Cost: $208 MM DOE Cost Share: $141 MM (68%) Key Dates: FEED Completed: April 2011 Construction started: May 2011 Two monitoring wells drilled: Nov. 2012 UIC Class VI Injection Well Permit: Sept. 2014; Injection well drilled and completed: Sept. 2015 Construction complete Apr. 2016 Started Commercial Operations: April 7, 2017 Project Opening Ceremony: September 22 2017 5

Kemper County Southern Company Services, Inc., CCPI-2 Advanced IGCC with CO 2 Capture Project Background: New Built Coal Plant In Kemper County, MS First Base Load Unit Built in 30 years and Located Away from the Coast after Hurricane Katrina Mississippi Power is a PSC Regulated Utility Generation: 582 MWe (net) with duct firing 2 TRIG TM gasifiers developed by Southern Co. and KBR Fuel: Local Mississippi Lignite 67+% CO 2 capture (Selexol process) ~3,000,000 metric tons CO 2 /year EOR: Denbury Onshore LLC Current Status: Over 200 days of gasifier operation accomplished before start-up operations were suspended. Plant will continue to produce electricity using Natural Gas Negotiations with Mississippi PSC continuing Key Dates: Project Awarded: Jan. 30, 2006 Project moved to MS: Dec. 5, 2008 NEPA Record of Decision: Aug. 19, 2010 Initiate excavation work: Sept. 27, 2010 CC operation on Nat Gas: August 2014 First Syngas production initiated: July 14, 2016 Project Startup Suspended: June 28, 2017 6

Today s Challenges - Natural Gas a Key Factor in Projected Future US Energy Mix Low NG prices High NG prices 7 Source: EIA Annual Energy Outlook 2017 7

U.S. DOE FE is Advancing Clean Coal Technologies Making Coal Plants More Efficient Increase Efficiency at Existing U.S. Coal Plants Advanced Turbines, Advanced Combustion, Fuel Cells, 2 nd Gen Materials, Sensors, Modeling Technologies Supercritical CO2 Research, Coal Based Rare Earth Elements (RRE) Capturing More CO 2 Turning CO 2 into Valuable Products Cost-effective carbon capture for new and existing power plants Bringing it All Together Crosscutting technology development program 8 New pathways CO 2 Utilization CO 2 Utilization Safe use and permanent storage of CO 2 from power generation and industry 8

U.S. DOE Helping to Identify Efficiency Improvements at Existing U.S. Coal Power Plants U.S. coal power plants represent ~30% of all U.S. power generation Coal is a critical part of U.S. power generation fuel diversity Coal plants are competing with low cost Natural Gas DOE is helping U.S. coal power plants to improve their thermal efficiency (Plant Heat Rate) o o o o o o Increase Boiler Efficiency Examine Potential Turbine Enhancements/Retrofits Efficiency Enhancements of Condensers, Pumps, Fans, Heaters and Other Equipment Investigate Coal Beneficiation Options (Fuel Delivery and Pre-Processing of Coal to Enhance Coal Quality) Identify New Economic Opportunities (ex. CO2 for EOR potential, REE extraction, etc.) Operational Improvements (ex. Plant Cycling, Control Systems, etc.) Plant efficiency improvements translate to overall lower emissions (including CO2, SO2, NOx, Hg) Heat Rate improvements allow the coal plants to be more economical and more competitive with other fuels. 9

U.S. DOE Transformative R&D: Supercritical Carbon Dioxide (sco2) Supercritical CO 2 : A highly efficient working fluid COAL WASTE MFG. HEAT SOLAR NUCLEAR NATURAL GAS Diverse fuel/ heat sources Higher thermal efficiencies, smaller physical footprint, and lower capital costs (than conventional steam-based power generation) Cleaner, more efficient and affordable electricity 10 10

Coal-Based Rare Earth Elements (REE s) Objectives: Establishment of the Economic Production of REE s from Coal and Coal Byproducts Identify Highest Rare Earth Content Materials in the U.S. Coal Value Chain Ore-Specific Plant Designs for these Materials Financial Projections for Rare Earth Production from these Materials Economic U.S. Rare Earth Production Opportunities Strategies: Engagement of U.S. Technical Resources, Including Industry and Academia Where Required, Technology Development Future Directions: Expanded Search for High Rare Earth Assays Pilot-Scale Operations 11

U.S. DOE National Carbon Capture Center (NCCC) Operated by Southern Co. Services Hosted at Plant Gaston, AL DOE funds 80% of operations Over 91,000 test hours Technologies from U.S. and six other countries since 2008 founding of NCCC More than 40 carbon capture technologies tested 20+ Post combustion 20+ Pre-combustion Dedicated staff of plant engineers Standard design guidelines Small and Large Solvent Test Units 90+% of US developers opt for NCCC 12

Potential Policy Incentives for CCUS Tax and financial incentives to support CCUS deployment are currently under consideration The tools under consideration include: Incentives for CO 2 storage-eor including expansions of the existing 45Q tax credit provisions Investment tax credits (ITCs) CO 2 price stabilization and market creation Master Limited Partnerships (MLPs) Private Activity Bonds (PABs) Diverse stakeholder support for proposed CCUS legislation 13

Sample of State CCUS Policies Liability: How long the operator is responsible for the site post closure. Storage Fund: A fund established for the long-term management and monitoring of CCS storage sites Pore Space: Who owns the pore space into which the CO2 is injected CO 2 Owner: Post-Injection owner of CO 2 Unitization: Minimum % of landowners which must agree to project Primacy: CCS rights granted to mineral rights holders Inter-state boundary issues. Holly Javedan, Massachusetts Institute of Technology https://sequestration.mit.edu/pdf/us_state_regulations_underground_co2_storage.pdf 14

CO 2 Sources Power Plants and Industry

Potential CO2 Utilization - Oil and Gas Fields Source: Workshop on Siting and Regulating Carbon Capture and Storage (CCS) Infrastructure, April 8, 2016

Coal and CCUS Activities in the U.S. Historically Focused on Technology Development and Market Mechanisms DOE Technology Push Market Pull Domestic Oil Supplies and CO 2 Demand (Storage) Volumes from Next Generation CO 2 -EOR Technology** Develop new coal power plant technologies Improve efficiency at existing coal plant CO2 R&D focused on: cost (capture) and confidence (storage) Demos (integration and learning) Existing Market Mechanisms: Enhanced Oil Recovery (EOR) 65 million tons per year of CO 2 to produce nearly 300,000 barrels of oil per day. Regulatory Framework Financing (Tax Credits and Loan Guarantees)

For More Information Office of Fossil Energy Andrew Hlasko, P.E. andrew.hlasko@hq.doe.gov www.energy.gov/fe U.S. DOE Headquarters, Washington DC. facebook.com/fossilenergy twitter.com/fossilenergygov 18