Vapor Recovery & The Capture of Associated Gas

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Vapor Recovery & The Capture of Associated Gas Practical Applications & Case Studies Rome 2008 Presented by: Larry S. Richards President & CEO Hy-Bon Engineering Co.

ASSOCIATED GAS Storage Tanks Production Equipment Casinghead Gas

OIL STORAGE TANKS TANKS Vapor Recovery Systems Systems

TANK OPERATIONS OPERATIONS As the oil resides in the tanks, it gives off vapors, thereby increasing the pressure inside the tank.

Sources of Methane Losses Losses Approximately 26.6 Bcf/yr of Methane are lost from storage tanks in the U.S. alone Flash losses occur when crude is transferred from containment at a high pressure to containment at a lower pressure Working losses occur when crude levels change and when crude in the tank is agitated Standing losses occur with daily and seasonal temperature and pressure changes Source: Natural Gas STAR Partners

WHY LET $ ESCAPE INTO THE AIR? AIR? Beside des be being g an environmental hazard,, escaping vapors result in i the e loss of a major revenue source fo for the oil company. Hundreds of oil companies have added d significant money to their bottom line by b capturing this valuable able gas stream. $ $ $ $ $

VAPOR RECOVERY SYSTEMS

Standard Vapor Recovery Unit Vent Line Back Pressure Valve Control Pilot Suction Line Electric Control Panel Crude Oil Stock Tank(s) Suction Scrubber Bypass Valve Gas Sales Meter Run Gas Sales Condensate Return Check Valve Liquid Transfer Pump Electric Driven Rotary Compressor

VAPOR RECOVERY RECOVERY Typical stock tank vapor recovery unit in operation. This unit is configured to capture 90 mcfd of gas g and discharge into a 40 psig sales line.

Benefits of Vapor Recovery Units Units Capture up to 95 percent of hydrocarbon vapors that accumulate in tanks Recovered vapors have much higher Btu content than pipeline quality natural gas Recovered vapors can be more valuable than methane alone Reduce regulatory & liability exposure

Quantifying the Gas Stream IDENTIFY emission sources using the FLIR GasFinder camera QUANTIFY emmissions using chart, E&P Tank, HiFlow Sampler, bagging techniques and actual tank tests per location with turbine meters, recording manometers and mass flow meters. meters. RECTIFY emission by recommending best technical alternatives available in the industry for capturing each source and adding to the revenue stream stream camera

Estimated Volume of Tank Vapors 110 110 100 100 GOR 90 90 80 80 40 40 API API and and Over Over 70 70 30 30 API API to to 39 39 API API 60 Vapor Vented from Tanks- SCF/BBL - GOR 60 50 43 Under Under 30 30 API API 40 50 43 40 30 30 20 20 10 20 30 40 50 60 70 80 10 10 80 Pressure of Vessel Dumping to Tank (Psig) (Psig)

Estimating Tank Emissions Emissions Chart method is a quick and easy way to get a fast ballpark estimate Notice the impact of higher gravity oil, as well as higher separator pressures This method is VERY CONSERVATIVE and generally underestimates actual emission levels

Quantify Volume of Losses E&P Tank Model Computer software developed by API and GRI Estimates flash, working, and standing losses Calculates losses using specific operating conditions for each tank Provides composition of hydrocarbon losses

E&P TANK INPUT SCREEN SCREEN

E&P TANK EXAMPLE OUTPUT OUTPUT

-- Emission Composition ------------------------------------------------------------------ Component Uncontrolled [ton/yr] Uncontrolled [lb/hr] Controlled [ton/yr] Controlled [lb/hr] H2S O2 CO2 N2 C1 C2 C3 i-c4 n-c4 i-c5 n-c5 C6 C7 C8 C9 C10+ Benzene Toluene E-Benzene Xylenes n-c6 224Trimethylp Total 12.137 0.000 85.667 2.284 122.391 159.072 415.158 96.442 261.360 82.901 97.357 28.130 26.984 10.294 2.081 0.544 2.029 0.250 0.032 0.264 19.202 0.000 1424.579 2.771 0.000 19.559 0.521 27.943 36.318 94.785 22.019 59.671 18.927 22.228 6.422 6.161 2.350 0.475 0.124 0.463 0.057 0.007 0.060 4.384 0.000 325.246 0.607 0.139 0.000 0.000 85.667 19.559 2.284 0.521 6.120 1.397 7.954 1.816 20.758 4.739 4.822 1.101 13.068 2.984 4.145 0.946 4.868 1.111 1.407 0.321 1.349 0.308 0.515 0.118 0.104 0.024 0.027 0.006 0.101 0.023 0.013 0.003 0.002 0.000 0.013 0.960 0.000 71.229 0.003 0.219 0.000 16.262

-- Emission Summary ---------------------------------------------------------------------- Item Uncontrolled Uncontrolled Controlled Controlled [ton/yr] [lb/hr] [ton/yr] [lb/hr] Total HAPs 21.780 4.973 1.089 0.249 Total HC 1324.491 302.395 66.225 15.120 VOCs, C2+ 1202.100 274.452 60.105 13.723 VOCs, C3+ 1043.029 238.134 52.151 11.907 Uncontrolled Recovery Info. Vapor 71.3400 [MSCFD] HC Vapor 66.3900 [MSCFD] GOR 35.67 [SCF/bbl]

A chart recorder is set up on the tank battery for a 24-hour pressure test. The resultant chart is brought into the office for evaluation. Information such as ambient temperature, test apparatus size and orifice size is recorded and used in the calculation of volume of tank vapors. TANK TEST TEST

TANK TEST TEST Ultrasonic meters, Turbine meters and Mass flow meters are also highly effective The key is DURATION a minimum of 24 hours of emissions must be charted for accurate results

CASE STUDIES & EXAMPLES

Industry Experience: Oxy Oxy Oxy Case Study - Vapor Recovery Wasson Tank Battery (CDU 1 & 2) 2) Denver City, Texas Installed in 2004 Oxy purchased two vapor recovery units in August 2004 for capturing vapors from two separate tank batteries at their Wasson facility. Each battery produces approximately 450 MCFD of tank vapors, which Oxy needed to gather and compress into a 45 45 psig sales line. Due to the low discharge pressure, Oxy selected rotary vane compressor packages capable of moving 500 MCFD. In order to minimize maintenance,, Oxy selected electric drive units (75 horsepower electric motors on each unit).

Oxy Wasson Tank Battery 1 (CDU 1)

Oxy Wasson Tank Battery 2 CDU2

Industry Experience: Oxy Oxy Purchase Cost Installation Cost Installed Cost Gas Volume (mcfd) Value @ $6 / mcf Annual Revenue (with NO btu adjustment and no liquid sales) Monthly Incr. Revenue Payout (in Months) $92,500 $92,500 $9,500 $9,500 $102,000 450 $2,700 $985,500 $102,000 $82,125 1.24 $82,125 $185,000 $185,000 $19,000 $19,000 $164,250 $204,000 $204,000 900 $5,400 $1,971,000 $164,250 1.24

This is one of 3 Vapor Recovery Units that will be used to capture 25 Million cubic feet of gas in Angola for the Chevron Cabinda project commissions in 2008.

Angola Installed November 2007 2007 Angola Chevron Cabinda Flare Reduction Project - 25 MMCFD MMCFD

Project Overview Chevron Cabinda Project (Angola) This project was the Chevron s s largest flare reduction project in 2007 Angola Cabinda Hy-Bon Vapor Recovery Units are scheduled to be commissioned in Fall 2008. The 25 MMCFD of flare and vent gas recovered has the same greenhouse gas effect of removing 812,000 cars from the road or planting 1.1 million acre of trees

PDVSa Project Overview - PDVSa This flare in Venezuela was causing a variety of health and environmental concerns. Billions of cubic feet f of methane are vented and flared from oilfield ield separators and storage s tanks in almost every producing country.

PDVSa Project Overview - PDVSa This dual flooded screw package for PDVSA is designed for volumes to 5.0 MMSCFD; moving tank vapors from 0 to 200 psig in Eastern Venezuela.

PDVSa Project Overview - PDVSa At this location, three of our compressor packages were set in tandem to move 15 MMSCFD of 2500-2600 BTU tank vapors.

Project Overview PDVSa Gas Anaco (Venezuela) (Venezuela) Vapor recovery units currently capture over 75 million cubic feet of previously vented and flared gas across 7 facilities Gas Anaco project, begun in 2006, targets over one billion cubic feet of gas across eastern Venezuela Conversion of much of the power and transportation infrastructure to natural gas is underway

Dacion Eni Dacion Eni installed vapor recovery systems in their Dacion East and West facilities in Venezuela, each designed to move 1.4 MMSCFD of gas at pressures to 230 psig. Eni Oil & Gas Dacion Field, Venezuela 2004

Project Overview Eni Dacion (Venezuela) (Venezuela) Dacion Vapor recovery units were installed to capture up to 1.4 MMCFD per site White paper was written shortly after installation on the economic success of the project A highly valuable 70 API gravity condensate was recovered from the gas stream and used to blend with the primary low API gravity oil production at an approximate daily rate of 100 to 150 barrels of condensate per unit.

M2M Project Update Update Oxy Colombia Colombia

Initial project will be capturing approximately 350 mcfd of vent gas from the Caricare oil storage and production facility. Purpose of the project will be incremental capture of natural gas liquids from this gas stream. Two additional sites are planned following successful installation of the first project. Subsequent project to utilize flare gas is also being evaluated by Oxy Colombia.

Oxy Colombia April 2008

Oxy Colombia April 2008

Oxy Colombia April 2008

Other Emission Sources Sources Gas can also be captured from separators and other field equipment. This unit is capturing natural gas off several separators for sale down a high pressure line.

or

Other Emission Sources Sources This unit captures a 98% CO2 gas stream in a field outside Snyder, Texas. Flooded screw compressor for volumes to 1.5 MMSCFD. The CO2 is captured and re- injected into the formation, dramatically reducing operating costs.

REDUCTION CASINGHEAD PRESSURE REDUCTION In the effort e to wrench additional dollars from existing production, more and more producers are turning to the use of low horsepower compression to enhance production from mature wells.

Relieving Back Pressure Pressure BEFORE COMPRESSION AFTER COMPRESSION

y

Casinghead gas is usually piped 30 to 90 feet from the wellhead and quietly vented to atmosphere Casinghead gas is vented in almost every oil producing country

Multiple Casinghead Pressure Reduction Case Studies and 2 published articles available at www.hy-bon.com bon.com

In Conclusion Hydrocarbon Spills in the Air Shareholder Lost Product Truly Unique Opportunity

www.hy-bon.com HY-BON ENGINEERING COMPANY, INC. INC. Setting a New Standard!! Standard!!