Print date: 01-Nov-2007 Material Safety Data Sheet According to EC Directive 1907/2006 Revision Number: 0 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING Identification of the substance or preparation MSDS Ref. No.: 012011 Product name: Product code: CEL 32501 GIFAP Code: EC emulsifiable concentrate Use of the Substance/Preparation Recommended use: Insecticide. Company/Undertaking The Scotts Company (UK) Ltd, Salisbury House, Weyside Park, Catteshall Lane, Identification Godalming, Surrey, GU7 1XE, United Kingdom Emergency telephone number: ++44 (0) 1865 407333 Classification 2. HAZARDS IDENTIFICATION The product is non-dangerous in accordance with Directive 1999/45/EC Most important hazards None 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical nature of the preparation Components CAS-No Weight % EC-No. Classification Refined rapeseed oil 8002-13-9 > 25% 232-299-0 NE Emulsogen T No CAS no. 10-25% USA231 R52/53 Xn: R65 Oxynex LM no CAS No < 1% USA258 C;R34 R22 R43 Page 1 of 6
NE = Non-Established For the full text of the R phrases mentioned in this Section, see Section 16 4. FIRST AID MEASURES General advice: Ingestion: Inhalation: Skin contact: Health injuries are not known or expected under normal use. Rinse mouth. If symptoms persist, call a physician. Move to fresh air. If symptoms persist, call a physician. Wash off immediately with soap and plenty of water. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 10 minutes. If symptoms persist, call a physician. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media: Carbon dioxide (CO2). Powder. Water spray jet. alcohol-resistant foam. Unsuitable extinguishing media: High volume water jet Special exposure hazards arising from the substance or preparation itself, its combustion products, or released gases: carbon oxides. Special protective equipment for firefighters: In the event of fire, wear self-contained breathing apparatus. Specific methods: Collect contaminated fire extinguishing water separately. This must not be discharged into drains. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Avoid contact with skin and eyes. Contaminated surfaces will be extremely slippery. Environmental precautions: Prevent product from entering drains. Do not contaminate water. Methods for cleaning up: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Take up mechanically and collect in suitable container for disposal. 7. HANDLING AND STORAGE Handling: Technical measures/precautions: Safe handling advice: Keep away from sources of ignition - no smoking. Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Wash hands and exposed skin after use / handling. Page 2 of 6
Storage: Technical measures/storage conditions: Incompatible products: Specific use(s): Store in original container. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of reach of children. None known None. VCI (Germany) 10 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures to reduce exposure: No special technical protective measures required. Occupational exposure controls Personal protective equipment Respiratory protection: Not required if properly ventilated.. Hand protection: Eye/face protection Skin and body protection: Hygiene measures Exposure limit values Environmental exposure controls Protective gloves. Avoid contact with eyes. If splashes are likely to occur, wear:. Safety glasses. Wear normal, light working clothing. Wash hands before stopping and immediately after handling. There are no Occupational Exposure Limits available. 9. PHYSICAL AND CHEMICAL PROPERTIES General Information Physical State: Appearance: Color: Odor: Liquid Oily yellowish characteristic Important Health Safety and Environmental Information Flash point: > 100 ( C) Density: 0,924 g/cm³ (20C) Solubility: Emulsifiable Explosive properties: Doesn't present explosion hazard Flammability (solid, gas): The product is not self inflammable Other information ph: 5.3 Page 3 of 6
10. STABILITY AND REACTIVITY Stability: Conditions to avoid: Materials to avoid: Hazardous decomposition products: Stable under recommended storage conditions. To avoid thermal decomposition, do not overheat.. Strong oxidising agents. Carbon oxides 11. TOXICOLOGICAL INFORMATION Component information Product information LC50/inhalation/4h/rat = Local effects Skin effects: Eye effects: Inhalation: Ingestion: Sensitization: > 5 mg/l No sensitization. 12. ECOLOGICAL INFORMATION Product information LC50/96h/rainbow trout = 310 mg/l. LC50/24h/daphnia = 700 mg/l. EC50/72h/algae = 42 mg/l. Component information Additional ecological information: Do not treat near to a watering place 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods: Do not contaminate ponds, waterways or ditches with chemical or used container. Do not empty into drains. This material and its container must be disposed of in a safe way.. Page 4 of 6
Contaminated packaging: Do not re-use container for any other purpose and dispose of safely.. Dispose of in accordance with local regulations and national regulations. 14. TRANSPORT INFORMATION Product information Physical State: Liquid ADR/RID UN-No: Not classified for transport IATA UN-No: Not classified for transport IMO / IMDG UN-No: Not classified for transport 15. REGULATORY INFORMATION Indication of danger: This product does not have to be classified according to the EU regulations. To avoid risks to man and the environment, comply with the instructions for use. S -phrase(s) S 2 - Keep out of the reach of children. S13 - Keep away from food, drink and animal feedingstuffs. S29 - Do not empty into drains. S35 - This material and its container must be disposed of in a safe way. S20/21 - When using, do not eat, drink or smoke. Wash hands and exposed skin after use / handling. Do not contaminate water with the product or its container. This material and it's container must be disposed of in a safe way. ICPE (FR): Classified installation : article 1155 Registration number UK/Eire This product does not need to be registered for use in the UK. PCS No.: 92338 Text of R Phrases mentioned in Section 2 None 16. OTHER INFORMATION Page 5 of 6
16. OTHER INFORMATION Reason for revision: *** Indicates changes since the last revision. This version replaces all previous versions Prepared by: Regulatory Affairs Department. This information contained herein is, to the best of Scott's knowledge and belief, accurate and reliable as of the date of preparation of this document. However, no warranty or guarantee, express or implied, is made as to the accuracy or reliability, and Scotts shall not be liable for any loss or damage arising out of the use thereof. No authorization is given or implied to use any patented invention without a license. In addition, Scotts shall not be liable for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices or from any hazards inherent in the nature of the product End of Safety Data Sheet Page 6 of 6