at the Metro New York Section, AIChE s Seventh Annual Energy & Resources Conference - Thursday, May 30th, 2013 Con Edison Building, New York, NY

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Reducing Greenhouse Gas (GHG) Emissions - The Path Forward in the Near Term to Meet Global GHG Emission Reduction Goals...and Enhance U.S. Energy Security Presenta)on by Edward L. Helminski, President and Publisher of ExchangeMonitor Publica)ons & Forums, Inc. at the Metro New York Section, AIChE s Seventh Annual Energy & Resources Conference - Thursday, May 30th, 2013 Con Edison Building, New York, NY 1

Sooner or later we will have to get serious about limiting CO 2 emissions. Doing that will take "everything we've got," including a significant amount of CCS. Here, for example, is one EPRI scenario. Efficiency Solar Biomass You don't have to buy the details. The point is that virtually every scenario to decarbonize the energy system, in a cost effective way, requires CCS. TWh Existing nuclear Existing gas Existing coal Wind Hydro Source: http://mydocs.epri.com/docs/environment/electric-utilities-environmental-conference/euec_2012_hannegan_2012-01-31.pdf 2

Fossil fuels in the energy mix: the past Incremental world primary energy demand by fuel, 2001 to 2011 Source: IEA WEO 2012

Fossil fuels in the energy mix: the future Fossil fuels in the energy mix: the future Source: IEA WEO 2012 New Policies Scenario

CCS in Power For all fossil fuels, CCS must be applied by around 2030 in order to reach the de-carbonisation targets. Gas may become a low carbon technology, but without CCS, gas may be limited to a backup and balancing capacity where renewable energy supplies are variable.

CCS is essential alongside renewables A reminder GW Installed capacity with CCS Data from OECD/IEA, Energy technology Perspectives 2012 2/3 of global power from fossil fuels in 2035 Emissions reductions from: Efficiency increase Increase in Renewables Huge investments in CCS Without CCS => 40% more expensive (*) CCS alone can massively reduce CO2 emissions Also a key option for Industry (Cement, I&S, refineries, etc) (*) IEA 2 C Scenario

CCS will be a competitive low carbon solution Up to 45 cents/kwh cent /KWh - Typical cost of electricity OECD new plant construction Reference case (*) (*) Ref case CSP Tower without storage (**) Ref case CSP Tower with 4hrs storage (**) Trend 2013 New Plant construction in the next 5 years Source : Alstom analysis 2012. CCS w Post amine 2017 costs, including on shore T&S & CO 2 price (Flue Gas Recirculation for CCS Gas CC) CoE do not include externalities of Intermittent power (Back-up cost, balancing cost, grid enhancement if required) OECD includes Europe and NAM

Advancing CCS remains critically important 1. Energy-related CO 2 emissions have doubled in the past 40 years 2. Fossil fuels accounted for 85% of all incremental energy demand in the last decade WEO 2011

Advancing CCS remains critically important 3. CCS is the only option for many energy-intensive industries 4. CCS is part of a costeffective portfolio of technologies in any ambitious scenario

Advancing CCS remains critically important 5. CCS can help preserve an economic value of fossil fuel reserves WEO 2012 6. CCS can help unlock emissions already locked in

Advancing CCS remains critically important 7. Global energy supply is as carbon- intensive today as it was in 1990 IEA Energy Sector Carbon Intensity Index, ESCII

Regional Carbon Sequestration Partnerships Developing the Infrastructure for Wide Scale Deployment Big Sky Carbon Sequestra)on Partnership Plains CO2 Reduction Partnership Midwest Geological Sequestration Consortium West Coast Regional Carbon Sequestration Partnership Midwest Regional Carbon Sequestra)on Partnership Southwest Regional Partnership on Carbon Sequestration Southeast Regional Carbon Sequestration Partnership Seven Regional Partnerships - 400+ distinct organizations, 43 states, 4 Canadian Provinces

Regional Carbon Sequestration Partnerships Validating CCS through Small- and Large-Scale Injections 5 9 1 8 4 6 2 3 7 Large Scale File Projects InjecDon Ongoing Cumulative CO 2 (Million Tonnes) Projected Future Injected CO 2 Injected CO 2 2013/2014 InjecDon Scheduled

Major U.S. Demonstrations Using Existing Infrastructure, Creating New Markets FutureGen 2.0 Oxy-Combustion w/ CO 2 Capture & Storage in Saline Formation SALINE 1.3M TPY 2016 start Summit TX Advanced IGCC w/ Full Carbon Capture EOR 3M TPY 2014 start Hydrogen Energy California Advanced IGCC with Carbon Capture EOR 3M TPY 2018 start NRG W.A. Parish Generating Station Post Combustion CO 2 Capture EOR 1.4M TPY 2014 start CCPI ICCS Area 1 FutureGen 2.0 Air Products and Chemicals CO 2 Capture from Steam Methane Reformers EOR 1M TPY 2013 start Archer Daniels Midland CO 2 Capture from Ethanol Plant SALINE ~1 M TPY 2013 start Southern Company IGCC-Transport Gasifier w/carbon Capture EOR 3 M TPY 2014 start Leucadia Energy CO 2 Capture from Methanol Plant EOR 4.5 M TPY 2015 start 14

Inputs into CCS are not negligible... Money spent on CCS projects globally Government pledges for CCS support Source: BNEF Source: GCCSI R&D spending on CCS technologies by IEA countries Numbers of CCS- related patents Source: IEA Source: IEA

CCS is making progress Source: GCCSI, BNEF Projects in execute and define phases according to GCCSI criteria.

By 2050: 120Gt of CO 2 safely stored 2020: Several dozen large- scale projects in coal and gas power and 1 st phase industry 2030: > 2000Mt CO 2 stored pa; CCS roudnely used in power and industry; ready for deployment in 2 nd phase industry 2050: > 7000Mt CO 2 stored pa; CCS rou)nely used in all applicable power and industry

Total investment in CCS: 3.6 trillion USD 2013-2020: USD 100 bn 2020-2050: USD 3,5 trn Economic benefit: if CCS removed from porzolio, investment cost in the power sector increases by 40% undl 2050 Addi)onal investment requirements to reach 2DS scenario goals 0 10 20 30 40 Trillion USD CCS Other low- carbon technology Note: investment needs in other low- carbon energies are equally significant

But, developing CCS will take time and money We expect learning curves to look like this: Ed Rubin and his colleagues argue they will more likely look like this: SO 2 NO X We need to get started now building CCS at commercial scale. Rubin et al, IIJGGC, 2007 19

CCSI: Accelerating Technology Development Iden)fy promising concepts Reduce the )me for design & troubleshoo)ng Quan)fy the technical risk, to enable reaching larger scales, earlier Stabilize the cost during commercial deployment Na)onal Labs Academia Industry 20

Advanced CO2 Capture Program Leveraging an integrated development approach MIXED-MATRIX COMPOSITES CRYOGENIC/ MEMBRANE AAIL nano-layers CHEMICAL/PHASE CHANGE SOLVENTS Similar CO2 Capacity Conventional Solvent (selexol) Changes in process conditions results in CO2-release Novel solvent H2O 22

The Capture Technology is Ready Belchatow Power Plant.. The Market is not!

Capture Technologies Capture Technologies Chemical Looping Amine Based Capture Membrane Separation Systems Ionic Liquid-Based Systems Ammonia Based Capture Systems Oxycombustion Capture Utilizing Solvents/ Sorbents Adsorption Based Processes Systems Utilizing Enzymes and Ultrasonics Coal-fired Plant Solid Waste as a Sorbent

Conclusions From ALSTOM S Tom Stringer CCS Generation 1 Technologies are ready for large-scale Technology development is on track to support a large CCS market deployment into the 2020 s Grant money is not enough Right market support needed some good examples are emerging CO2 utilization can also stimulate CCS projects; Fossil-fuel power w/ccs can remain a major factor of future low-carbon energy mix : Competitive with other forms of low-carbon power; Reliable and flexible ; Complementary to renewables and nuclear.

Specific support is needed to stimulate commercial CCS market development Before reaching full commercial status, the technology first needs to be demonstrated at large-scale in real commercial conditions, A transport and storage infrastructure also needs to be developed; Today, Power systems are not yet decarbonized : CCS extra cost to be compensated; Similar to renewables, CCS needs an adapted market framework for final demonstration and early deployment; Government programs allowed several large-scale projects in NAM However the first tranche of the European funding program NER-300 did not select any CCS project.

Example of a Supporting Market Framework The UK Carbon Capture and Storage (CCS) has the potential to be one of the most cost effective technologies for decarbonisation of the UK s power and industrial sectors, as well as those of economies worldwide CCS Roadmap Department for Energy and Climate Change The UK has developed a CCS roadmap and planned a series of measures to support CCS deployment : A CCS commercialization program - 1 Billion GBD funding support Electricity Market Reform including a CfD (Contract for Difference) for clean energy producers Support to R&D programs dedicated to CCS.

What is CO 2 EOR & How Much Does It Recover? Secure CO 2 Supply Transport via Pipeline Inject into Oilfield EOR Delivers Almost as Much Production as Primary or Secondary Recovery (1) Tertiary Recovery Remaining (CO 2 EOR) Oil ~17% Secondary Recovery (waterfloods) ~18% Primary Recovery ~20% 28

CO 2 utilization Captured CO 2 for EOR or Chemical Production Industrial flue gas with CO 2 : Power Steel mill Cement factory Refinery Methanol plant, Ethanol plant Fertilizer plant etc CO 2 capture unit Underground permanent Storage CO 2 -EOR Urea Methanol Carbonates Food industry Classic CCS (Saline Aquifers or depleted Oil & Gas fields) CO 2 -EOR : huge potential in the USA CCU Chemical usage Current prospects in Fertilizer and carbonates CCU (especially EOR) can stimulate CCS/CCU through valuation of CO 2

For More InformaDon Anthony Cugini 412-386-6023 or 304-285-4684 anthony.cugini@netl.doe.gov Office of Fossil Energy www.fe.doe.gov NETL www.netl.doe.gov Na)onal Energy Technology Laboratory @NETL_News 30

Interested in Capture? http://www.carbonsq.com/ CarbonCaptureTechnologies.htm