Innovation Technology Outlook of Advanced Biofuels

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Innovation Technology Outlook of Advanced Biofuels production and deployment in the next three decades Shunichi NAKADA IITC-IRENA Ecuador, November 2015

Contents 1. Why advanced Biofuel? 2. Framework of IRENA Innovation Technology Outlook of Advanced Biofuels 3. Status of deployment 4. Supply potential of advanced biofuel 5. Technology development status 6. R&D opportunities 7. Conclusion 2

1. Why advanced biofuel? 3

RE Penetration is the lowest in transport sector Energy consumption in three endues sector (2013) 13% 3% 37% Liquid biofuel will be the only option in transport sector for coming decade or two 4

Billion litres/year Liquid biofuel can grow up to 15% by 2030, technically 4000.0 3500.0 3000.0 2500.0 2000.0 1500.0 1000.0 500.0 0.0 2010 2020 2025 2030 2035 2040 North America South America Europe Africa Asia Oceania Biofuel (REmap) There is a potential to increase RE share in transport sector to 10 15% by 2030, from current 3%. Yet, significant investment, market development required. Advanced biofuel account for only 1% of current liquid biofuel 5

Quarterly investments [USD bln/yr] Global Investments in Biofuels is very low and even decreasing 12 10 1st gen 2nd gen 4Q running average 8 6 4 2 0 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 Source: BNEF 6

Stalling investment for liquid biofuel, Why? Stagnant investment due to unclear policy support in longer term which reflects public concern including, Impact of land use change GHG emission Loss of biodiversity Competitive use of natural resource - land and water - Food security Resource depletion: forest, water Social impact Land grabbing Equal benefit sharing Advanced biofuel have a potential to overcome above issues still technology development and investment is needed 7

8 2. IRENA Innovation Technology Outlook of Advanced Biofuels

Objectives This study provides a global technology outlook for advanced biofuels from 2015 to 2045, specifically liquid transport fuels. Overview of market potential Comparative assessment of pathways Technology gaps and opportunities for R&D Non-technical gaps and opportunities for deployment Innovation prospects on promising production pathways Commercialisation strategies Report coming up in 2015 9

3. Status of deployment 10

There are significant opportunity for advanced biofuel Road transport: Aviation: 6% advanced biofuel by 2020 (IATA) Fleet: US Navy, 50% of energy from non-conventional by 2020, special focus on drop in biofuel Nov. 2015, DuPont opened world largest cellulosic ethanol plant with over 100 mil. litter cellulosic ethanol production, which 500 local farmers provide feedstock, create 85 full time job, and over 150 seasonal job 11

Deployment: Advanced Biofuel Market Potential 12

Market of advanced biofuel is growing, yet far more growth is required Current Installed/planed capacity of Advanced Biofuel (2015) Projection REmap 2030 37% of total biofuel production 42% annual growth WEO 2035 18% of total biofuel production 22% annual growth OFIC 2030 12% of total biofuel production 31% annual growth 13

14 4. Supply potential of advanced biofuel

What is Advanced Biofuel? Type of feedstock Food crop / non-food crop GHG emission reduction Lifecycle GHG saving >50% (US-RFS) Technology maturity Matured / R&D status Product quality Similar properties to gasoline, diesel, jet fuel and bunker fuel, either neat or blended in high proportions 15

How much biomass can be available for advanced biofuel? Overall potential 133 (EJ/year) in 2030 Solid waste, 13 Overall potential 224 (EJ/year) in 2050 Solid waste, 13 Energy crop (non-food), 48 crop residue, 59 Energy crop (non-food), 107 crop residue, 76 Forest residues, 13 Forest residues, 28 16

Comparison of Adv. Biofuel Feedstock - Cost and Supply potential for 2030 Supply cost (USD/GJ) 4.0 3.6 3.2 2.8 Feedstock supply potential and cost 2.4 2.0 1.6 1.2 Forest residue Solid waste Crop residues Energy crop (non-food) 0.8 0.4 13EJ 13EJ 59EJ 48EJ Supply potential (EJ) 17

18 5. Technology development status and prospects

Advanced biofuels pathways Will be replaced by simpler figure Feedstock Conversion Intermediate Upgrading Finished biofuel Micro-algae Extraction and purification Lipids Trans-esterification FAME biodiesel Tall oil pitch Hydro-treatment HVO diesel, jet Agricultural residues Pre-treatment & hydrolysis C5 & C6 sugars Aerobic fermentation Macro-algae Yeast/bacteria fermentation Butanol Palm oil mill effluent Solid biogenic residues & waste Aqueous phase reforming Ethanol Crude glycerine Pyrolysis Pyrolysis oil Hydro-treatment & refining Diesel, jet, gasoline Forest residues Non-food energy crops Diesel, jet, gasoline Black & brown liquor Gasification Syngas FT catalysis & hydro-cracking Mixed/higher alcohols Other catalysis & refining Methanol Syngas fermentation Principal pathway for each feedstock shown by bolder lines. Feedstocks are colour-coded by finished biofuel type 19

Pathways: Technology readiness L 1-3 4 5 6 7 8 9 Research Pilot Demonstration Research Pilot Demonstration Ready Commercial for commercialisation Lignocellulosic LC butanol buthanol Lignocellulosic LC ethanol ethanol Acetone-Butanol-Ethanol fermentation process ABE Gas ification + Mixed alcohols Syngas fermentation Commercialisation -Major Challenge- Aerobic fermentation Pyrolysis oil + Upgrading Fatty acid Ga s ification + Fischer-Tropsch FAME methyl ester Hydrotreated Vegetable HVO Oil Aqueous phase reforming Gasif + Methanol (us ing glycerol) Source: Preliminary findings from IRENA Advanced Biofuels Technology Outlook (work-in-progress) 20

Conversion efficiency 70 65 Conversion Efficiency in MJ fuel /MJ feedstock, dry 60 55 50 45 40 35 30 2015 2030 2045 2015 2030 2045 2015 2030 2045 2015 2030 2045 2015 2030 2045 2015 2030 2045 2015 2030 2045 Biomass to liquids: gasification + FT Fast Pyrorysis + Upgrading Gasification + Methanol-to- Gasoline Diesel / Gasoline substitutes Aqueous Phase Reforming Gasification + Mixed Alchol Synthesis Gasification + Syngas fermentation Alcohols Hydrolysis + Fermentation-to- Ethanol Thermochemical pathway have higher efficiency theoretically, including pyrolysis and Gasification. (For hydrorysis + fermentation, co-products energy use outside the process is not included) 21

2015 2030 2045 2015 2030 2045 2015 2030 2045 2015 2030 2045 2015 2030 2045 2015 2030 2045 2015 2030 2045 Biodiesel Corn EtOH Diesel Gasoline Cost reduction Production costs in USD 2014 /GJ fuel 140 120 100 80 60 40 20 0 Biomass to liquids: gasification + FT Fast Pyrorysis + Upgrading Gasification + Methanol-to- Gasoline Aqueous Phase Reforming Gasification + Mixed Alchol Synthesis Gasification + Syngas fermentation Hydrolysis + Fermentation-to- Ethanol Diesel / Gasoline substitutes Alcohols Reference (2015) 1G Fossil Lower capital investment make Gasification + MtG and Gasification + MAS most competitive. High conversion efficiency of Gasification + MtG also contribute cost reduction Conventional biofuel is almost at the same level with cheapest advanced biofuel. It still in the middle to higher range of fossil fuel 22

2015 2030 2045 2015 2030 2045 2015 2030 2045 2015 2030 2045 2015 2030 2045 2015 2030 2045 2015 2030 2045 Biodiesel Corn EtOH Environmental performance Greenhouse gas emissions in g CO2-eq /MJ fuel 60 50 40 30 20 35 % Reduction 50% Reduction 60 % Reduction 10 0 Biomass to liquids: gasification + FT Fast Pyrorysis + Upgrading Gasification + Methanol-to- Gasoline Aqueous Phase Reforming Gasification + Mixed Alchol Synthesis Gasification + Syngas fermentation Hydrolysis + Fermentation-to- Ethanol Diesel / Gasoline substitutes Alcohols Reference (2015) 1G In terms of GHG emission reduction, all advanced biofuel show significantly higher performance mainly due to the difference in feedstock. It is also energy self-sufficient in conversion process using by-product as a heat source 23

Pathways comparison Efficiency Cost GHG emission % USD/GJ gco2/mj Biomass to liquids: gasification + FT 48 35 3 Fast Pyrorysis + Upgrading 59 45 18 Gasification + Methanol-to-Gasoline 57 24 5 Aqueous Phase Reforming 42 75 25 Gasification + Mixed Alchol Synthesis 47 32 6 Gasification + Syngas fermentation 54 37 3 Hydrolysis + Fermentation-to-Ethanol 45 35 9 Numbers represent projection for 2030 Color indicates: best worst 24

6. R&D Opportunities 25

Innovation impact: Preliminary results Gasification and syngas cleaning: (Quality control of syngas, adaptation to diverse feedstock) Energy integration: 15% savings on production costs for FT Greater feedstock tolerance: Fischer-Tropsch synthesis: (Quality control of syngas, scale down of FT system) Modular micro channel reactor: 8% gain in efficiency and 10% saving in CAPEX Co processing of FT waxes: 15% savings in CAPEX Fast pyrolysis and upgrading: (Oil yield improvement, quality control of pyrolysis oil) Hydro deoxygenation upgrading, pyrolysis oil co-feeding in existing infrastructure, co-cracking of pyrolysis oil: 10-30 % fuel cost reduction Pre-treatment and hydrolysis: (Separation of lignin/celluloce, cost and sensitivity of enzyme) Optimization and dosage requirements: 10% of current enzyme costs (by 2050) Fermentation to ethanol and upgrading: (Energy intensive distillation process) Membrane separation/osmosis or induce phase separation techniques: 50% energy savings compare to distillation Control systems for plant optimization: 37-42% efficiency increase One processing step for pretreatment, hydrolysis and fermentation: 80% reduction in production costs Fermentation to butanol and upgrading: (Fermentation inhibitor) Acid recovery: 15% yield gain Aqueous phase reforming: (Low yield of liquid hydrocarbon, short lifetime of catalyst) Hydro treating catalyst development: Increase efficiency from 25% to 55% 26

Advanced Biofuels Commercialisation TRL Barriers Intervention Mandate or subsidy Lack of market and high costs Public procurement High credit risks Loan guarantee 8 Lack interest in lending, limited knowledge of market demand Loan softening programme 6/7 4/5 <4 Insufficient loans for projects, lack of long-term lending capacity Commercial expansion, financial restrictions, market integration Technology proving, testing and evaluation of claims Lack of technology proving, investor and public apprehension Investment risk in new technologies Financing gap during project development Risk of investing in start-ups Protecting IP ownership Lack of funding for research Lack of funding for innovation organisations Project loan facility Brokered partnership Demonstration (research and evaluation) Demonstration project (High profile) Project investment insurance Public/private co-financed debt Soft loan programmes Investment tax incentives IP protection - Legal frameworks and assistance with protection Research framework Grants 27

7. Conclusion 28

Conclusions and recommendation Advanced biofuel advantages supply potential energy security environmental impact food security Number of commercial scale project are on the way R&D Opportunities for deployment in the next 3 decades 1. Lignocellulosic fermentation is closest to full commercialization, with complemented by butanol fermentation in the longer term 2. Gasification can be a main source of different tech. pathway, which still require improvement in energy efficiency and syngas cleaning 3. Among different upgrading, syngas fermentation may achieve earlier commercialization. FT attracts high interest. the key is system downsizing 4. Fast pyrolysis + upgrading are still in the early stage, however cost reduction opportunity can be seen in upgrading Current obstacles - High production cost because of early development stage - Uncertainty in policy framework to prioritize advanced biofuel causes - Slow investments in the sector 29

Conclusions and recommendation Technical and non-technical factors needed: Support policy framework to cover four key area: technology research and development, company development, market formulation and integrated policies (energy, transport, agriculture, environment, ) developed in close collaboration/coordination with all relevant stakeholder, primarily industry research and project developers IRENA will support the sector through Networking stakeholders from different sector, region Providing key information to support member countries Guiding countries for policy development, project guidance 30

Thank You snakada@irena.org www.irena.org 31