Comprehensive Monitoring of Salt Water Intrusion and Submarine Groundwater Discharge in Coastal Ecosystems

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Comprehensive Monitoring of Salt Water Intrusion and Submarine Groundwater Discharge in Coastal Ecosystems Teng-fong Wong, Department of Geosciences Stony Brook University, Stony Brook, NY 11794-2100 U.S.A. (Teng-fong.Wong@stonybrook.edu) Collaborators: Ronald J Paulsen, Jonathan Wanlass (Suffolk County Department of Health Services), Christopher F Smith (Cornell Cooperative Extension), Daniel O Rourke (CDM), Bart Chadwick, Jon Groves (SPAWAR Systems Center) UN/CSD-16 2008-05-16 Comprehensive Monitoring of Salt Water Intrusion and Submarine Groundwater Discharge in Coastal Ecosystems Dynamic coupling of salt water intrusion and submarine groundwater discharge in coastal ecosystems. An ultrasonic seepage meter for quantitative characterization of submarine groundwater discharge. Integration of geophysical, geochemical and hydrological techniques for monitoring saltwater intrusion and submarine groundwater discharge: Eutrophication and algal blooms, Forge River, Moriches Bay, NY. Organic contaminant migration, Davisville, RI. UN/CSD-16 2008-05-16 1

Salt Water Intrusion and Submarine Groundwater Discharge More than 50% of the world s population live in coastal areas, corresponding to only ~4% of Earth s total land area. Nearly half of the world s major cities (pop. >500,000) are located within 50 km of the coast, and almost all the major mega-cities are at the coast or its vicinity. Coastal ecosystems are among the most productive, yet threatened, ecosystems in the world. The impact of their degradation often extends a long distance from the coast. The quantity and quality of groundwater in these areas are related to the dynamic interplay of salt water intrusion and submarine groundwater discharge (SGD). Salt Water Intrusion The problem of saltwater intrusion was recognized as early as the 19 th century, thus predating many other types of drinking-water contamination issues. Because saltwater has high concentrations of total dissolved solids and certain inorganic constituents, it is unfit for human consumption and many other anthropogenic uses. The encroachment of saline water into freshwater aquifers most often is caused by over-pumping from coastal wells. Saltwater intrusion is a particularly acute problem in an island setting. Cape Cod (LeBlanc et al., 1986) 2

Global Climate Change, Sea Level Rise and Saltwater Intrusion (IPCC, 2007) Projected sea-level rise due to climate change is several mm/yr over the next century. This has serious consequences for people living in coastal areas through the effects of flooding, coastal erosion and saltwater intrusion. Ghyben-Herzberg principle (based on hydrostatic equilibrium): sea-level rise of 2.5 mm thinning of the fresh water wedge by ~10 cm. Conceptual Model of Saltwater Intrusion (Cooper, 1964) Saltwater circulates from the sea to the transition zone. Induced by mixing processes at the transition zone, saltwater then flows back to the sea. 3

Geochemical Signature of The Spatial Distribution of Saltwater Encroachment Spatial distribution of chloride concentration from measurements on water samples extracted from numerous wells (Biscayne aquifer, FL). Dynamic Interplay of Saltwater Intrusion and Submarine Groundwater Discharge SGD is driven by hydraulic gradient in the coastal aquifer Oceanic forces can induce tidal pumping and waves Mixing of the two can significantly impact the fluid chemistry of the ecosystem Buddemeier (1996) 4

Quantity and Quality of Groundwater in Coastal Ecosystems The encroachment of saline water into a coastal aquifer is modulated by submarine groundwater discharge. Coastal ecosystems undergo degradation from anthropogenic causes, including population growth and urbanization, pollution (untreated human waste, toxic waste), eutrophication (enhanced nutrient loading from agriculatural run-off, sewage and burning of fossil fuels). Unlike surface discharge, there is a paucity of data on the magnitude of SGD and its role as a source of dissolved solids, nutrients and contaminants. International Comparative Study of SGD (SCOR-LOICZ WG112) Collection bag Heat pulse meter Ultrasonic seepage meter Radon measurement 5

Ultrasonic Seepage Meter (US Patents 6,874,371 and 7,107,859) Flow Inlet Flow Outlet Sound waves are continuously generated by piezoelectric transducers in both up- and down-stream directions. Differential travel time of the waves is proportional to the flow velocity. Both positive and negative discharge can be resolved down to 0.1 cm/day. Integral Transducer VF flow L Integral Transducer Submarine Groundwater Discharge: West Neck Bay, Shelter Island, Long Island 6

SGD Data from West Neck Bay, Shelter Island, LI 3 2 1 Submarine Groundwater Discharge: Flux and its emporal evolution during tidal cycles Specific Discharge (cm/d) 200 150 100 50 specific discharge tidal stage 0 0 06.22.99 06.24.99 06.25.99 06.27.99 Date 160 120 80 40 Tidal Stage (cm above MSL) Magnitude of SGD flux comparable to that of surface discharge. Negative correlation between tidal loading and SGD. Resolution of seepage meter down to 0.1 μm/s (0.086 cm/day). Continuous measurement over a duration of >1 month. Paulsen, Smith, O Rourke & Wong (2001) 7

Spatial and Temporal Heterogeneities of Submarine Groundwater Discharge Channels 1 and 2 were located at site 1 of West Neck Bay at a lateral distance of 2 m. Negative SGD (reverse flow) was measured by channel 2 during high tide. Spatial complexity of the coupling between SGD and saltwater intrusion may persist down to m-scale. Paulsen, O Rourke, Smith & Wong (2004) Submarine Groundwater Discharge: Temporal evolution during tidal cycles in West Neck Bay The maximum, mean and minimum SGD as functions of tidal stage at site 3 of West Neck Bay. Data acquired continuously over a 282-hr period underscore the temporal complexity of SGD. Paulsen, O Rourke, Smith & Wong (2004) 8

Investigation of SGD by Integrating Geoelectric, Geochemical and Hydrologic Measurements Electrical conductivity provides a sensitive proxy for salinity of groundwater. Continuous electrical resistivity profiling can map out the spatial distribution of saltwater intrusion and SGD. Continuous seepage measurement and fluid sampling for geochemical characterization provide detailed characterization in hot spots of interest. Forge River, Long Island: A case study of eutrophication and algal bloom 9

Forge River: Submarine Groundwater Discharge and Algal Bloom Forge River is a 5-km stretch of water that juts into the South Shore of Long Island off Moriches Bay. Nitrogen from herbicides and pesticides used on lawns, as well as nitrogen and bacteria leaching from septic systems, simply flow into the bay. Overgrowth of seaweed and decomposition of the algal blooms consume virtually all the oxygen in the water and the resultant anoxia suffocates most shellfish and crabs. Groundwater Discharge and Nitrate Concentration in Unsewered Areas Along Forge River GW GW 10

Spatial Distribution of SGD Mapped by Geoelectrical Profiling Electrical conductivity provides a sensitive proxy for salinity of groundwater. High electrical resistivity fresh water flux associated with SGD. AGI SuperSting probe in a transect line across the Forge River. Continuous measurements over a tidal cycle conducted on October 18, 2007. High and low tides were at 12:17 and 18:47. 11:50 High Tide 12:17 12:31 13:18 14:08 11

14:52 15:39 16:15 17:06 Low Tide 18:47 UltraSeep: Integrated Measurement of seepage, electrical conductivity and fluid chemistry Teflon Sample Bag Funnel 12

UltraSeep: Integrated Measurement of seepage, electrical conductivity and fluid chemistry Top Flange Side 1 Side 2 Flow meter Water Sampler Batt. Logger Controller Funnel Ultrasonic Flowmeter: Specific discharge or recharge in the range of 0.1-150 cm/d Water Sampler: Programmable collection by time or flow condition at 0.2-20 ml/min via 6-port selector valve into precleaned teflon bags Electrical Conductivity: 0-70 ± 0.001 ms/cm Temperature: -5-35 ±0.001 C An Integrated Survey of Contaminant Migration: Davisville, Rhode Island A plume of volatile organic compounds (VOC) associated with historical release has been migrating toward Narragansett Bay and Allen Harbor. Multiple potential pathways toward Allen Harbor were inferred from hydrologic data. An integrated survey was conducted in 2004 to map out and characterize the discharge of the organic contaminants. 13

An Integrated Survey of Contaminant Migration: Davisville, Rhode Island 3 2 1 Electrical Conductivity survey identified three groundwater discharge zones: 1. Northern shore of Harbor. 2. Harbor end of Harbor. 3. Inner Harbor. An Integrated Survey of Contaminant Migration: Davisville, Rhode Island 3 2 1 Ultrasonic Seepage Meter: +ve and ve SGD were observed at EC4-1, reflecting relatively strong influence of tidal loading. 14

An Integrated Survey of Contaminant Migration Using UltraSeep UltraSeep Data on Fluid Chemistry: 3 2 1 Significant amount of VOC was found along northern shore of Entrance Channel. No VOCs were detected in the two other discharge zones. An Integrated Survey of Contaminant Migration: Davisville, Rhode Island A plume of volatile organic compounds (VOC) associated with historical release has been migrating toward Narragansett Bay and Allen Harbor. Three discharge zones in the vicinity of Allen Harbor were identified. Organic contaminants from the source have migrated along a path that converges toward only one of these three zones. 15

Comprehensive Monitoring of Salt Water Intrusion and Submarine Groundwater Discharge in Coastal Ecosystems Coastal ecosystems are among the most productive, yet threatened, ecosystems. The impact of their degradation often extends a long distance from the coast, covering most of the mega-cities and densely populated areas of the world. The quantity and quality of water in these areas are intimately related to the dynamic coupling between salt water intrusion and SGD. Water quality in these ecosystems should be assessed in a total resource context, integrating technological developments in multiple disciplines (geophysics, biogeochemistry and hydrology). Use of the best available scientific data from comprehensive monitoring will improve management and policy responses of coastal ecosystem, which is vital to the livelihood and economic income of a large number of people now living in coastal zones. UN/CSD-16 2008-05-16 16