Design Details of a 600 MW Graz Cycle Thermal Power Plant for CO 2

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Institute for Thermal Turbomaschinery and Machine Dynamics Graz University of Technology Erzherzog-Johann-University Design Details of a 600 MW Graz Cycle Thermal Power Plant for CO 2 Capture Presentation at the ASME Turbo Expo 2008 Berlin, Germany, June 9-13, 2008 Herbert Jericha, Wolfgang Sanz, Emil Göttlich and Fritz Neumayer Institute for Thermal Turbomachinery and Machine Dynamics Graz University of Technology Austria

Background - I Worldwide ever rising emissions of greenhouse gases to atmosphere -> global warming and environmental change Kyoto Protocol demands the reduction of greenhouse gases, mainly CO2 In EU: strong pressure on utilities and companies to reduce CO2 emissions Carbon capture and storage (CCS) as short and mid term solution CCS can be done for natural gas and coal

Background - II (CCS Technologies) Post-combustion: CO2-Capture from exhaust gas (chemical absorbtion, membranes, ) Pre-combustion: Decarbonization of fossil fuel to produce pure hydrogen for power cycle (e.g. steam reforming of methane, ) Oxy-fuel power generation: Internal combustion with pure oxygen and CO2/H2O as working fluid enabling CO2 separation by condensation Which technology has the best chances to dominate future power generation?

Oxy-Fuel Cycles Oxy-fuel cycles with internal combustion with pure oxygen are a very promising technology (Global Gas Turbine News 10/2005) + CO2 can be easily separated by condensation from working fluid consisting of CO2 and H2O, no need for very penalizing scrubbing + Very low NOx generation, NOx is not emitted + Flexibility regarding fuel: high CO2 content natural gas, syngas from coal, biomass or refinery res. gasification - New equipment required - Additional high costs of oxygen production + These new cycles show higher efficiencies than current air-based combined cycles (Graz Cycle, Matiant cycle, Water cycle,...)

Objective In 2003 design details for a 75 MW unit were presented at the ASME IGTI conference in Atlanta Power output raise to 400 MW was presented at ASME IGTI conference 2006 in Barcelona and at CIMAC conference 2007 in Vienna In continuation of these works a raise of power output to 600 MW is presented here and important design details are discussed. In order to achieve this goal combustor pressure and turbine inlet temperature are increased to values well acceptable in standard gas turbine development Additional pre-compressor stage allows to use the same compressors as for 400 MW

Cycle Scheme for 600 MW net output O2 50 bar Fuel (methane) 554 C C0 C1 Combustor C2 HPT 1500 C steam HTT C P 180 bar 557 C HRSG 1bar 572 C Cycle Fluid 79 % H2O 21 % CO2 Deaerator 172 C 0.75 bar LPST 0.021 bar H2O Condenser HTT HPT Cycle Fluid High Temperature Turbine High Pressure Steam Turbine 177 C C3 C4 CO2 LPST Low Pressure Steam Turbine C0,C1,C2 C3,C4 HRSG Cycle Fluid Compressors Cycle Fluid Compressors Heat Recovery Steam Generator 1.27 bar 1.95 bar Cycle fluid condensate

Graz Cycle Power Balance 400 MW 600 MW 400 MW 600 MW HTT power [MW] 617.9 908 Net shaft power [MW] w/o mechanical losses 504.7 746 HPT power [MW] 49.9 62 Total heat input Q zu [MW] 758.6 1100 LPST power [MW] 71.6 101 Thermal cycle efficiency [%] Total turbine power P T 739.4 1071 Electrical power output [MW] [MW] incl. mechanical, electrical & auxiliary loss C0 power [MW] - 8.8 Net electrical cycle efficiency [%] C1 power [MW] 131.1 178 O 2 generation & compression P O2 [MW] C2 power [MW] 82.6 108 Efficiency considering O 2 supply [%] 66.52 67.6 490.7 724.6 64.68 65.71 74.7 109 54.83 55.83 C3+C4 power [MW] 15.5 23 CO 2 compression to 100 13.0 18.6 bar P CO2 [MW] Pump power [MW] 5.5 7.2 Net power output [MW] 403.0 597 Total compression power P C [MW] 234.7 325 Net efficiency [%] 53.12 54.14

Arrangement of Main Turbo Shaft - 725 MW Main gas turbine components on two shafts for 600 MW net output Compression shaft of 8500 rpm: cycle compressors C0, C1 and C2, driven by first part of HTT, the compressor turbine HTTC Power shaft of 3000/3600 rpm: power turbine HTTP as second part of HTT drives the generator Four-flow LPST at the opposite side of the generator Shafts on same spring foundation Intercooler between C1 and C2 on fixed foundation connected to HRSG Side View Vertical Section Intercooler to HRSG Spring Supported Foundation HTTC HTTP 4-Flow 3-stage LPST Generator C0+C1 From HRSG C2 High-Speed Shaft: 8500 rpm Low-Speed Shaft: 3000 rpm From Condenser/Evaporator

Main Turbo Shaft Main gas turbine components on two shafts for 600 MW net output Higher power obtained by design improvements (higher compression ratio, higher peak temperature) to Generator C0 5100 rpm C1 8500 rpm C2+HTTC 8500 rpm HTTP 3000 rpm Single stage transonic turbine drives compressor shaft (C0, C1 and C2) Power turbine HTTP 5 subsonic stages at 50 Hz 4 subsonic stages at 60 Hz

C0 and C1 compressor details Pre-arranged loading compressor C0 serves for higher mass flow to combustion chamber keeping volume flow to C1 equal to previous layout Speed change allows to keep tip Mach number at 1.3 Cycle fluid from HRSG Cycle fluid to intercooler C0 bearings Coupling to C2 and HTTC C2 C0 compressor (5100 rpm) driven via planetary gear C1 compressor (8500 rpm)

Steam Cooling Details of HTTC and C2 HTTC and C2 on common shaft with a disk of constant stress Disk is cooled on both sides with cooling steam of 300 C Cooling steam on right-hand-side: balancing of axial thrust C2 rotor: cooling to avoid creep Steam Injection for Improvement of Meridional Flow Profile Cooling steam

Combustion Chamber a) c) b) Stoichiometric combustion of fossil fuel and O2 at 50 bar Combustor exit temperature: 1500 C Oxidizer is not cooling medium, thus risk of incomplete combustion. So fuel and O2 inflow have to be kept in close contact in steam-driven burner vortex In inner cylindrical shell fuel and O2 combustion takes place partly cooled by inner steam vortex flow Outer cylindrical shell conducts cycle fluid in counterrotating vortex to locally defined vortex break-down Annular flame casing with 6 quadruples of burner tubes Cooling of annular flame cage by recompressed working fluid serving for proper mixing and guiding to first nozzles

Transonic Stage Steam Cooling Cooling steam entry through hollow nozzles Collection in inner annular chamber Jet in partly tangential direction to provide optimal inflow into blade root Radial outflow of cooling steam through fir-tree root into hollow blade in innovative cooling system (ICS) Exit of under-expanded transonic steam flow covering whole blade surface by a coherent layer of steam ICS cooling slits High-reaction high-flowefficiency blade channel

3D cooling arrangement of HTTC stage (previous work) Cooling slits Steam chambers Blade with ICS steam cooling as proposed for 75 MW Graz Cycle presented at ASME Turbo Expo Atlanta 2003

Stress of C2-HTTC shaft Analytic solutions for three-dimensional stress Rotor cooled to 300 C σ R,a = 120MPa σ t,a =230 MPa σ t,0 =448MPa σ t,a = σ ax = σ t,0 = σ R,0 230MPa 82MPa 300 C σ R,0 =448MPa σ=540 MPa h=0.45m h Rotationally symmetric stress distribution

Conclusions Graz Cycle is an oxy-fuel power cycle of highest efficiency for CO2 retention Raise of system power from 400 MW to 600 MW is presented This was made possible by a 50 bar combustion chamber with 1500 C peak temperature, increasing plant efficiency to 54.1 % Additional stage ahead of C1 working fluid compressor allows to maintain the inlet volume flow, so that the same design of the C1 and C2 compressors can be used for the 400 and 600 MW plant. Detailed deliberations on cooling, material selection, stresses and combustion chamber design are given We hope that our work will help industry to achieve a successful result in manufacture and operation in the short time limits indicated by European ZEP initiative and the warnings of Princeton University (National Geographic, Sept. 2007)