TECHNICAL INFO 8 03_2013

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In this work the environmental impact of various insulation and foam cores have been evaluated by method of the Life Cycle Assessment (LCA). The benefits of novel polyethylene terephthalate () foams are demonstrated well, especially when the foam is made of post consumer material, r-. Furthermore, the potential of environmentally friendly foams is evaluated for green building scenarios, such as the LEED certification. Introduction The goal of this study was to evaluate existing insulation and foam cores in terms of environmental impact (carbon footprint), and compare them with the novel polyethylene terephthalate () foams. Life Cycle Assessment (LCA) is the most common tool used to evaluate how green the product is, what the real environmental impact of the said product is. Polymeric foams have always had a significant role in building and construction as insulation materials, where especially highly insulating polyurethanes (/PIR) and low cost polystyrenes (/ ) have been widely used. However, recently also the structural characteristics of certain rigid foams have been gaining more and more interest in building sector as foam cores in sandwich structures due to their light weight and relatively good mechanical properties. For core foams the requirements are often quite different from the requirements of insulation foams, the focus being shifted more to mechanical properties such as compression and shear strength, and in several applications also on fatigue and ageing, and on various impact and creep properties. Typically higher density foams are preferred due to their mechanical superiority. Depending on the foam material, the mechanical properties may be adjusted to meet the demand by adjusting the density and the cellular structure of the foam. Polyethylene Terephthalate Polyethylene Terephthalate () is considered as an engineering plastic due to its excellent mechanical and thermal properties. However due to its large demand in textile, bottle and packaging industry it has become a commodity plastic in terms of price and availability. Furthermore thanks to bottle industry, it is also the most recycled plastic material in the world and so called post consumer material (r-) is available globally with annual capacity of 5 million tons (EU 1 million).

novel technologies enable upgrading of the post consumer material to the level of virgin material. As is known for its extremely good barrier properties, it is also by nature an excellent insulation material and provides good protection against moisture born damage and condensation. Core Material PIR Balsa - PolyEthylene Terephthalate: REACH compliant ROHS compliant No EU listed & banned hazardous substances No heavy metals No carcinogens & mutagenes No phtalates, no formaldehyde residues No CFC s Recyclable Good aging properties: no molding, no rotting, no wetting No fibers Excellent fatique is thermoplastic by nature, and therefore easy to be processed again and again. Even though is sensitive to multiple processing cycles, the most Recyclability +++ + -- --- --- Aging ++ - -- + - Thermal Conductivity +++ ++ +++ ++ + Foaming of to relatively low densities (<300 kg/m 3 ) is very novel in foaming industry, but developments in polymer upgrading and extruder technology have enabled production of low density (down to 60 kg/m 3 ) foams with very fine cellular structure. These foams have mechanical properties at least comparable to existing core and insulation foams, but also provide a unique feature by being fully recyclable and furthermore may be made fully out of post-consumer material. This work will evaluate by means of Life Cycle Assessment the environmental benefits of using foams in sandwich structures.

Life Cycle Assessment Life Cycle Assessment (LCA) is a method where the whole life cycle of the product is evaluated. In order for the assessment to be complete, a wide range of data is required, from manufacturing of raw materials to final waste scenario, and from transport of raw materials and finished goods to travel of individual employees and heating of office buildings. Several commercial software and databases exist for this purpose, and in this study SimaPro 7.2 was used with EcoIndicator 95 v2.1. The LCA of foam is based on actual data from Armacell Benelux from 2011 and for other foams data has been collected from publications and databases. A typical referred result from LCA is the carbon footprint (the amount of CO 2 emission) produced per unit of the product in evaluation. In this case the carbon footprint of different foams has been compared and the results are shown below in kilograms of CO 2 per one kilogram of foam produced. Here the 100% () correspond to 3,23 kg CO 2 emission. r- SAN The light green indicates the amount of CO 2 produced per 1 kg of foam made of virgin resin and the dark green the CO 2 produced for foam made of post-consumer material. The results indicate that foam has a low carbon footprint in comparison. Similar comparison has been done in respect to total energy consumed and total solid waste produced during the whole life cycle of various plastic foams. The 100% correspond to 71 MJ per produced kilo. r- SAN Greenhouse effect (kg CO 2 /kg product) 0% 50% 100% 150% 200% Energy consumption (MJ/kg product) 0% 50% 100% 150% 200%

Green building directives & LCA Here the 100% correspond to 0,03 kg waste per produced kilo. r- SAN Solid waste (kg/kg product) 0% 500% 1000% 1500% 2000% Again foams exhibit very good environmental characteristics, using less energy in production and producing significantly less waste than comparative materials. In case the foam is used for applications where insulation properties are crucial, the LCA values become very attractive, as the product actually saves the environment after being installed. In such scenario the better the thermal conductivity, the better the results will be. Green building (also known as green construction or sustainable building) refers to a structure and process that is environmentally responsible and resource-efficient throughout a life cycle of a building: from building site to design, construction, operation, maintenance, renovation and demolition. Achieving a green building typically requires close cooperation of the design team, architects, engineers, and the client at all project stages. Several national and international green building directives have been introduced recently, and the American LEED is most widely used of them. LEED (Leadership in Energy and Environmental Design) provides third-party verification of green buildings. It addresses the entire lifecycle of a building by focusing on 6 crucial criteria: site location, water use, energy performance, materials and resources, indoor quality, and innovation & design. LEED projects have been successfully established in 135 countries and international projects make up more than 50% of the total LEED registered square footage. Several national directives, such as QSAS for Qatar are almost identical to LEED.

Typically for any commercial buildings and neighborhoods, in order to earn LEED certification, a project must satisfy all LEED prerequisites and earn a minimum 40 points on a 110-point LEED rating system scale: 40 = minimum for certification 50 = silver certificate 60 = gold certificate 80 = platinum certificate 40 50 60 80 In respect to environmentally friendly core and insulation foams, such as foams, the following LEED criteria may be positively influenced: improved insulation efficiency (max. 19 points of 35) use of resource and recycled material (max. 7 points of 13) potential in innovation & design (max. 4 points of 5) LCA data (max. 7 points) This makes total potential of 37 points out of Below diagram depicts the value of LEED certification. Office rental prices throughout USA were reviewed and it was shown that LEED certified buildings are considered more valuable than non- LEED certified buildings. 100. Summary The environmental impact of novel polyethylene terephthalate () foam has been analyzed by means of Life Cycle Assessment (LCA) and compared with traditional core and insulation foams. The results indicate that in all relevant categories the foam outperforms existing materials. The impact on LEED certification remains to be defined, but it is not expected to be insignificant.

Status : Technical Info 8 - March 2013 Armacell provides this information as a technical service. To the extent the information is derived from sources other than Armacell, Armacell is substantially, if not wholly, relying upon the other source(s) to provide accurate information. Information provided as a result of Armacell s own technical analysis and testing is accurate to the extent of our knowledge and ability, using effective standardized methods and procedures. Each user of these products, or information, should perform their own tests to determine the safety, fitness and suitability of the products, or combination of products, for any foreseeable purposes, applications and uses by the user and by any third party to which the user may convey the products. Since Armacell cannot control the end of this product, Armacell does not guarantee that the user will obtain the same results as published in this document. The data and information is provided as technical service, and the data and information are subject to change without notice.